Expanding Insight into Asymmetric Palladium-Catalyzed Allylic Alkylation of N-Heterocyclic Molecules and Cyclic Ketones

PREPARATION OF (S)-tert-ButylPHOX

(2014)   ORGANIC SYNTHESES

Enantioselective Total Synthesis of the Reported Structures of (−)-9-epi-Presilphiperfolan-1-ol and (−)-Presilphiperfolan-1-ol: Structural Confirmation and Reassignment and Biosynthetic Insights

(2012) Allen Y. Hong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Reaction Mechanism of the Enantioselective Tsuji Allylation: Inner-Sphere and Outer-Sphere Pathways, Internal Rearrangements, and Asymmetric C–C Bond Formation

(2012) John A. Keith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 2-oxazolines and related N-containing heterocycles using [Et2NSF2]BF4 as a cyclodehydration agent

(2012) Marie-France Pouliot et al.   TETRAHEDRON LETTERS

Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of β-ketoesters: An Unusual Counterion Effect

(2011) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Catalytic Enantioselective Total Synthesis of (+)-Liphagal

(2011) Joshua J. Day et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ring-Contraction Strategy for the Practical, Scalable, Catalytic Asymmetric Synthesis of Versatile γ-Quaternary Acylcyclopentenes

(2011) Allen Y. Hong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions

(2011) Jimmie D. Weaver et al.   CHEMICAL REVIEWS

Enantioselective Decarboxylative Alkylation Reactions: Catalyst Development, Substrate Scope, and Mechanistic Studies

(2011) Douglas C. Behenna et al.   CHEMISTRY-A EUROPEAN JOURNAL

Design, Synthesis, and Applications of Potential Substitutes of t-Bu-Phosphinooxazoline in Pd-Catalyzed Asymmetric Transformations and Their Use for the Improvement of the Enantioselectivity in the Pd-Catalyzed Allylation Reaction of Fluorinated Allyl Enol Carbonates

(2011) Étienne Bélanger et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams

(2011) Douglas C. Behenna et al.   Nature Chemistry

Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork–Danheiser approach: preparation of mono-, bi-, and tricyclic systems

(2011) Nathan B. Bennett et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-catalyzed asymmetric alkylation in the synthesis of cyclopentanoid and cycloheptanoid core structures bearing all-carbon quaternary stereocenters

(2011) Allen Y. Hong et al.   TETRAHEDRON

Mechanistic Origin of the Stereodivergence in Decarboxylative Allylation

(2010) Kalicharan Chattopadhyay et al.   ORGANIC LETTERS

Rapid synthesis of an electron-deficient t-BuPHOX ligand: cross-coupling of aryl bromides with secondary phosphine oxides

(2010) Nolan T. McDougal et al.   TETRAHEDRON LETTERS

Unusual Allylpalladium Carboxylate Complexes: Identification of the Resting State of Catalytic Enantioselective Decarboxylative Allylic Alkylation Reactions of Ketones

(2009) Nathaniel H. Sherden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Enol Carbonates

(2009) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Use of 5,5-(Dimethyl)-i-Pr-PHOX as a Practical Equivalent tot-Bu-PHOX in Asymmetric Catalysis

(2009) Étienne Bélanger et al.   ORGANIC LETTERS

Unexpected effect of the fluorine atom on the optimal ligand-to-palladium ratio in the enantioselective Pd-catalyzed allylation reaction of fluorinated enol carbonates

(2008) Étienne Bélanger et al.   CHEMICAL COMMUNICATIONS

The total synthesis of (-)-cyanthiwigin F by means of double catalytic enantioselective alkylation

(2008) John A. Enquist Jr et al.   NATURE

Enantioselective Total Synthesis of (+)-Cassiol

(2008) Krastina V. Petrova et al.   ORGANIC LETTERS

Catalytic Enantioselective Approach to the Eudesmane Sesquiterpenoids: Total Synthesis of (+)-Carissone

(2008) Samantha R. Levine et al.   ORGANIC LETTERS

The Catalytic Asymmetric Total Synthesis of Elatol

(2007) David E. White et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY