Synthesis of a 4-Vinyltetrahydrocarbazole by Palladium-Catalyzed Asymmetric Allylic Alkylation of Indole-Containing Allylic Carbonates

An Efficient Protocol for the Palladium-Catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst

(2015) Alexander N. Marziale et al.   ADVANCED SYNTHESIS & CATALYSIS

Tsuji-Trost Type Functionalization of Allylic Substrates with Challenging Leaving Groups: Recent Developments

(2015) Raffaella Ferraccioli et al.   CURRENT ORGANIC CHEMISTRY

Brønsted Acid Catalyzed Asymmetric Diels–Alder Reactions: Stereoselective Construction of Spiro[tetrahydrocarbazole-3,3′-oxindole] Framework

(2015) Yang Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal catalyzed allylic alkylation: its development in the Trost laboratories

(2015) Barry M. Trost   TETRAHEDRON

NOBIN-based chiral phosphite-type ligands and their application in asymmetric catalysis

(2015) Konstantin N. Gavrilov et al.   TETRAHEDRON LETTERS

Design of supramolecular chiral ligands for asymmetric metal catalysis

(2015) Kohsuke Ohmatsu et al.   TETRAHEDRON LETTERS

Synthesis of γ-Lactams and γ-Lactones via Intramolecular Pd-Catalyzed Allylic Alkylations

(2014) Claire Kammerer et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed Asymmetric Allylic Dearomatization Reactions

(2014) Chun-Xiang Zhuo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Vinylogous Diels-Alder Reactions Catalyzed by a Chiral Phosphoric Acid

(2014) Xu Tian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The asymmetric Cu(ii)–indolinylmethanol complex catalyzed Diels–Alder reaction of 2-vinylindoles with β,γ-unsaturated α-ketoesters: an efficient route to functionalized tetrahydrocarbazoles

(2014) Banlai Ouyang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective synthesis of 1-vinyltetrahydroisoquinolines through palladium-catalysed intramolecular allylic amidation with chiral PhthalaPhos ligands

(2014) Luca Pignataro et al.   TETRAHEDRON-ASYMMETRY

Supramolecular control of selectivity in transition-metal catalysis through substrate preorganization

(2014) Paweł Dydio et al.   Chemical Science

The NH Functional Group in Organometallic Catalysis

(2013) Baoguo Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Supramolecular catalysis. Part 1: non-covalent interactions as a tool for building and modifying homogeneous catalysts

(2013) Matthieu Raynal et al.   CHEMICAL SOCIETY REVIEWS

Rapid Access to Spirocyclic Oxindole Alkaloids: Application of the Asymmetric Palladium-Catalyzed [3 + 2] Trimethylenemethane Cycloaddition

(2013) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective synthesis of highly functionalized tetrahydrocarbazoles through a domino Michael–Henry reaction: an easy access to four contiguous chiral centers

(2013) Pradeep Kumar Jaiswal et al.   RSC Advances

Enantioselective Synthesis of Spiro Cyclopentane-1,3′-indoles and 2,3,4,9-Tetrahydro-1H-carbazoles by Iridium-Catalyzed Allylic Dearomatization and Stereospecific Migration

(2012) Qing-Feng Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Occurrence, Biogenesis, and Synthesis of Biologically Active Carbazole Alkaloids

(2012) Arndt W. Schmidt et al.   CHEMICAL REVIEWS

A Library Approach to the Development of BenzaPhos: Highly Efficient Chiral Supramolecular Ligands for Asymmetric Hydrogenation

(2012) Luca Pignataro et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Diels–Alder Reaction of 2-Methyl-3-indolylmethanols via in Situ Generation of o-Quinodimethanes

(2012) You-Cai Xiao et al.   ORGANIC LETTERS

Multicatalytic Asymmetric Synthesis of Complex Tetrahydrocarbazoles via a Diels–Alder/Benzoin Reaction Sequence

(2012) Yankai Liu et al.   ORGANIC LETTERS

Pd2(dba)3 as a Precursor of Soluble Metal Complexes and Nanoparticles: Determination of Palladium Active Species for Catalysis and Synthesis

(2012) Sergey S. Zalesskiy et al.   ORGANOMETALLICS

Organocatalytic Multiple Cascade Reactions: A New Strategy for the Construction of Enantioenriched Tetrahydrocarbazoles

(2011) Yi-Ju Cao et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Asymmetric Hydrogenation of Olefins with PhthalaPhos, a New Class of Chiral Supramolecular Ligands

(2011) Luca Pignataro et al.   CHEMISTRY-A EUROPEAN JOURNAL

Supramolecular ligand–ligand and ligand–substrate interactions for highly selective transition metal catalysis

(2011) Stefano Carboni et al.   DALTON TRANSACTIONS

The Catalytic Asymmetric Fischer Indolization

(2011) Steffen Müller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Collective synthesis of natural products by means of organocascade catalysis

(2011) Spencer B. Jones et al.   NATURE

Enantioselective synthesis of 1-vinyltetrahydroisoquinolines via Pd-catalyzed intramolecular asymmetric allylic amination reactions

(2011) Chih-Wei Chien et al.   TETRAHEDRON

Phosphites and diamidophosphites based on mono-ethers of BINOL: a comparison of enantioselectivity in asymmetric catalytic reactions

(2011) Konstantin N. Gavrilov et al.   TETRAHEDRON

PhthalaPhos: Chiral Supramolecular Ligands for Enantioselective Rhodium-Catalyzed Hydrogenation Reactions

(2010) Luca Pignataro et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Practical and Enantioselective Approach to Tetrahydrocarbazoles by Asymmetric Organocatalysis

(2010) Xiao-Yu Zhu et al.   ChemCatChem

Creating Chemical Diversity in Indole Compounds by Merging Au and Ru Catalysis

(2010) Marco Bandini et al.   ChemCatChem

Phosphite-Containing Ligands for Asymmetric Catalysis

(2010) Piet W. N. M. van Leeuwen et al.   CHEMICAL REVIEWS

The Enantioselective, Organocatalyzed Diels-Alder Reaction of 2-Vinylindoles with α,β-Unsaturated Aldehydes: An Efficient Route to Functionalized Tetrahydrocarbazoles

(2010) Changwu Zheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Efficient Route to Functionalized Tetrahydrocarbazoles Using a Tandem Cross-Metathesis/Intramolecular-Hydroarylation Sequence

(2010) Xiao-Lei An et al.   Chemistry-An Asian Journal

Allylic alcohols: Valuable synthetic equivalents of non-activated alkenes in gold-catalyzed enantioselective alkylation of indoles

(2010) Marco Bandini et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Asymmetric Total Synthesis of Vindoline

(2010) Daisuke Kato et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Enantioselective Approach to Highly Substituted Tetrahydrocarbazoles through Hydrogen Bonding-Catalyzed Cascade Reactions

(2010) Xu-Fan Wang et al.   ORGANIC LETTERS

Catalytic asymmetric allylic alkylation employing heteroatom nucleophiles: a powerful method for C–X bond formation

(2010) Barry M. Trost et al.   Chemical Science

Enantioselective Gold-Catalyzed Allylic Alkylation of Indoles with Alcohols: An Efficient Route to Functionalized Tetrahydrocarbazoles

(2009) Marco Bandini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combination of a binaphthol-derived phosphite and a C1-symmetric phosphinamine generates heteroleptic catalysts in Rh- and Pd-mediated reactions

(2009) Luca Pignataro et al.   CHEMICAL COMMUNICATIONS

Allylation ofN-Heterocycles with Allylic Alcohols Employing Self-Assembling Palladium Phosphane Catalysts

(2008) Ippei Usui et al.   ORGANIC LETTERS

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION