Cooperative bimetallic catalysis in asymmetric allylic substitution

Stereoselective and Site-Specific Allylic Alkylation of Amino Acids and Small Peptides via a Pd/Cu Dual Catalysis

(2017) Xiaohong Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergence in Asymmetric Catalysis

(2017) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ir/Zn Dual Catalysis: Enantioselective and Diastereodivergent α-Allylation of Unprotected α-Hydroxy Indanones

(2017) Rui He et al.   ORGANIC LETTERS

Bimetallic catalysis for C–C and C–X coupling reactions

(2017) Dominic R. Pye et al.   Chemical Science

Catalytic SN 2′- and Enantioselective Allylic Substitution with a Diborylmethane Reagent and Application in Synthesis

(2016) Ying Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decarboxylative [4+2] Cycloaddition by Synergistic Palladium and Organocatalysis

(2016) Lars A. Leth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Allylic Alkylations with Enamine Nucleophiles

(2016) Nicholas Butt et al.   CHEMICAL RECORD

Combinations of Aminocatalysts and Metal Catalysts: A Powerful Cooperative Approach in Selective Organic Synthesis

(2016) Samson Afewerki et al.   CHEMICAL REVIEWS

Nucleophilic and Electrophilic Activation of Non-Heteroaromatic Amides in Atom-Economical Asymmetric Catalysis

(2016) Naoya Kumagai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Rhodium-Catalyzed Allylic Alkylation of Prochiral α,α-Disubstituted Aldehyde Enolates for the Construction of Acyclic Quaternary Stereogenic Centers

(2016) Timothy B. Wright et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Ir/Zn Dual Catalysis for Enantio- and Diastereodivergent α-Allylation of α-Hydroxyketones

(2016) Xiaohong Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Allylic C–H Alkylation of Terminal Olefins with Pyrazol-5-ones Enabled by Cooperative Catalysis of Palladium Complex and Brønsted Acid

(2016) Hua-Chen Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Uniting C1-Ammonium Enolates and Transition Metal Electrophiles via Cooperative Catalysis: The Direct Asymmetric α-Allylation of Aryl Acetic Acid Esters

(2016) Kevin J. Schwarz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis

(2016) Xingyu Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed SN2′-Selective Allylic Substitution Reaction of gem-Diborylalkanes

(2016) Zhen-Qi Zhang et al.   ORGANIC LETTERS

Combining Ru-Catalyzed C–H Functionalization with Pd-Catalyzed Asymmetric Allylic Alkylation: Synthesis of 3-Allyl-3-aryl Oxindole Derivatives from Aryl α-Diazoamides

(2016) Kosuke Yamamoto et al.   ORGANIC LETTERS

Silver-Assisted, Iridium-Catalyzed Allylation of Bis[(pinacolato)boryl]methane Allows the Synthesis of Enantioenriched Homoallylic Organoboronic Esters

(2016) Miao Zhan et al.   ACS Catalysis

Chiral Primary Amine/Palladium Dual Catalysis for Asymmetric Allylic Alkylation of β-Ketocarbonyl Compounds with Allylic Alcohols

(2015) Han Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Enantioselective 1,6-Boration ofpara-Quinone Methides and Efficient Transformation ofgem-Diarylmethine Boronates to Triarylmethanes

(2015) Yazhou Lou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereodivergent Dual Catalytic α-Allylation of Protected α-Amino- and α-Hydroxyacetaldehydes

(2015) Tobias Sandmeier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Branched Alkylboronates by Copper-Catalyzed Allylic Substitution Reactions of Allylic Chlorides with 1,1-Diborylalkanes

(2015) Junghoon Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances of Catalytic Asymmetric 1,3-Dipolar Cycloadditions

(2015) Takuya Hashimoto et al.   CHEMICAL REVIEWS

Transition metal-catalyzed allylic substitution reactions with unactivated allylic substrates

(2015) Nicholas A. Butt et al.   CHEMICAL SOCIETY REVIEWS

A Cu/Pd Cooperative Catalysis for Enantioselective Allylboration of Alkenes

(2015) Tao Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Asymmetric Mannich-Type Reaction of α- and β-Fluorinated Amides

(2015) Lennart Brewitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Rhodium-Catalyzed Allylic Substitution with a Nitrile Anion: Construction of Acyclic Quaternary Carbon Stereogenic Centers

(2015) Ben W. H. Turnbull et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective cooperative catalysis

(2015) Suleman M. Inamdar et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper(I)-Catalyzed Asymmetric Pinacolboryl Addition of N-Boc-imines Using a Chiral Sulfoxide–Phosphine Ligand

(2015) Ding Wang et al.   ORGANIC LETTERS

Catalytic Enantioselective 1,3-Dipolar Cycloadditions of Azomethine Ylides for Biology-Oriented Synthesis

(2014) Rishikesh Narayan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Organocatalysis Combined with Metal Catalysis: Concept, Proof of Concept, and Beyond

(2014) Dian-Feng Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Allylic Alkylation of Simple Ketones with Allylic Alcohols and Its Mechanistic Study

(2014) Xiaohong Huo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Counteranion Strategy for Asymmetric Oxidative C(sp3)H/C(sp3)H Coupling: Enantioselective α-Allylation of Aldehydes with Terminal Alkenes

(2014) Pu-Sheng Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic–cooperative combination of enamine catalysis with transition metal catalysis

(2014) Yongming Deng et al.   CHEMICAL COMMUNICATIONS

Versatile CuI/Pd0Dual Catalysis for the Synthesis of Quaternary α-Allylated Carbonyl Compounds: Development, Mechanistic Investigations and Scope

(2014) Fady Nahra et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric Reactions by Metal and Chiral Phosphoric Acid Sequential Catalysis

(2014) Ze-Peng Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Generation of α-CF3 Enolate: Direct Catalytic Asymmetric Mannich-Type Reaction of α-CF3 Amide

(2014) Liang Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent α-Allylation of Linear Aldehydes with Dual Iridium and Amine Catalysis

(2014) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Brønsted Acid Accelerated Pd-Catalyzed Direct Asymmetric Allylic Alkylation of Azlactones with Simple Allylic Alcohols: A Practical Access to Quaternary Allylic Amino Acid Derivatives

(2014) Hui Zhou et al.   ORGANIC LETTERS

Hydrogen-Bond-Activated Palladium-Catalyzed Allylic Alkylation via Allylic Alkyl Ethers: Challenging Leaving Groups

(2014) Xiaohong Huo et al.   ORGANIC LETTERS

Dual Catalysis Becomes Diastereodivergent

(2013) Maria Teresa Oliveira et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper/Palladium-Catalyzed 1,4 Reduction and Asymmetric Allylic Alkylation of α,β-Unsaturated Ketones: Enantioselective Dual Catalysis

(2013) Fady Nahra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

P,N ligands in asymmetric catalysis

(2013) Michael P. Carroll et al.   CHEMICAL SOCIETY REVIEWS

Pd-Catalyzed Asymmetric Allylic Alkylation of Pyrazol-5-ones with Allylic Alcohols: The Role of the Chiral Phosphoric Acid in C–O Bond Cleavage and Stereocontrol

(2013) Zhong-Lin Tao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spiroketal-Based Diphosphine Ligands in Pd-Catalyzed Asymmetric Allylic Amination of Morita–Baylis–Hillman Adducts: Exceptionally High Efficiency and New Mechanism

(2013) Xiaoming Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Twist on Cooperative Catalysis

(2013) C. S. Schindler et al.   SCIENCE

Enantio- and Diastereodivergent Dual Catalysis:  -Allylation of Branched Aldehydes

(2013) S. Krautwald et al.   SCIENCE

Synergistic catalysis: A powerful synthetic strategy for new reaction development

(2012) Anna E. Allen et al.   Chemical Science

Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of β-ketoesters: An Unusual Counterion Effect

(2011) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ring-Contraction Strategy for the Practical, Scalable, Catalytic Asymmetric Synthesis of Versatile γ-Quaternary Acylcyclopentenes

(2011) Allen Y. Hong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions

(2011) Jimmie D. Weaver et al.   CHEMICAL REVIEWS

Enantioselective Decarboxylative Alkylation Reactions: Catalyst Development, Substrate Scope, and Mechanistic Studies

(2011) Douglas C. Behenna et al.   CHEMISTRY-A EUROPEAN JOURNAL

C–N Bond Cleavage of Allylic Amines via Hydrogen Bond Activation with Alcohol Solvents in Pd-Catalyzed Allylic Alkylation of Carbonyl Compounds

(2011) Xiaohu Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bifunctional organo/metal cooperative catalysis with cinchona alkaloid scaffolds

(2011) Linus Stegbauer et al.   Chemical Science

When Organocatalysis Meets Transition-Metal Catalysis

(2010) Cheng Zhong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A Highly Efficient Palladium/Copper Cocatalytic System for Direct Arylation of Heteroarenes: An Unexpected Effect of Cu(Xantphos)I

(2010) Jinkun Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient palladium-catalyzed asymmetric allylic alkylation of ketones and aldehydes

(2010) Xiaohu Zhao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Biaryl Phosphites: New Efficient Adaptative Ligands for Pd-Catalyzed Asymmetric Allylic Substitution Reactions

(2009) Montserrat Diéguez et al.   ACCOUNTS OF CHEMICAL RESEARCH

Combining transition metal catalysis and organocatalysis: a broad new concept for catalysis

(2009) Zhihui Shao et al.   CHEMICAL SOCIETY REVIEWS

The Allyl Intermediate in Regioselective and Enantioselective Iridium-Catalyzed Asymmetric Allylic Substitution Reactions

(2009) Sherzod T. Madrahimov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Enol Carbonates

(2009) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Palladium- and Proline-Catalyzed Allylic Alkylation of Enolizable Ketones and Aldehydes with Allylic Alcohols

(2009) Ippei Usui et al.   ORGANIC LETTERS

Enantioselective Copper-Catalyzed 1,3-Dipolar Cycloadditions

(2008) Levi M. Stanley et al.   CHEMICAL REVIEWS

Enamines: efficient nucleophiles for the palladium-catalyzed asymmetric allylic alkylation

(2008) Xiaohu Zhao et al.   TETRAHEDRON

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION