Production of Csp3-Csp3Bonds through Palladium-Catalyzed Tsuji-Trost-Type Reactions of (Hetero)Benzylic Substrates

Dual Catalytic Decarboxylative Allylations of α-Amino Acids and Their Divergent Mechanisms

(2015) Simon B. Lang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Enantioselective Decarboxylative Allylations of a Mixture of Allyl Carbonates and Allyl Esters: Total Synthesis of (−)- and (+)-Folicanthine

(2015) Santanu Ghosh et al.   CHEMISTRY-A EUROPEAN JOURNAL

A general Pd-catalyzed α- and γ-benzylation of aldehydes for the formation of quaternary centers

(2015) Ivan Franzoni et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones

(2015) Robert A. Craig et al.   ORGANIC LETTERS

Enantioselective Synthesis of Homoallylic Azides and Nitriles via Palladium-Catalyzed Decarboxylative Allylation

(2015) Maria Victoria Vita et al.   ORGANIC LETTERS

Dawn of organopalladium chemistry in the early 1960s and a retrospective overview of the research on palladium-catalyzed reactions

(2015) Jiro Tsuji   TETRAHEDRON

Metal catalyzed allylic alkylation: its development in the Trost laboratories

(2015) Barry M. Trost   TETRAHEDRON

Structure and Reactivity of Late Transition Metal η3-Benzyl Complexes

(2014) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Retro-Claisen benzylation: direct use of benzyl alcohols in Pd-catalyzed couplings with nitriles

(2014) Tapan Maji et al.   CHEMICAL COMMUNICATIONS

Cyclization of η3-Benzylpalladium Intermediates Derived from Carbene Insertion

(2014) Eugene S. Gutman et al.   ORGANIC LETTERS

Diastereodivergent Processes in Palladium-Catalyzed Allylic Alkylation

(2013) Maria Teresa Oliveira et al.   ChemCatChem

Palladium-Catalyzed Asymmetric Benzylation of Azlactones

(2013) Barry M. Trost et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Decarboxylative Allylation and Benzylation of N-Alloc and N-Cbz Indoles

(2013) Thomas D. Montgomery et al.   ORGANIC LETTERS

DFT Studies on the Palladium-Catalyzed Dearomatization Reaction between Chloromethylnaphthalene and the Cyclic Amine Morpholine

(2013) Hujun Xie et al.   ORGANOMETALLICS

Benzyl Cation Stabilized by Metal Complexation. Relative Stability of Coordinated Methylene Arenium, π-Benzylic, and σ-Benzylic Structures

(2013) Elena Poverenov et al.   ORGANOMETALLICS

Palladium-Catalyzed Selective CH Benzylation towards Functionalized Azoles with a Quaternary Carbon Center

(2012) Pan Xie et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Amination of Chloromethylnaphthalene and Chloromethylanthracene Derivatives with Various Amines

(2012) Sheng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Benzylic Phosphates as Electrophiles in the Palladium-Catalyzed Asymmetric Benzylation of Azlactones

(2012) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Substitution and Cross-Coupling of Benzylic Fluorides

(2012) George Blessley et al.   ORGANIC LETTERS

η3-Furfuryl and η3-Thienyl Complexes of Palladium and Platinum of Relevance to the Functionalization of Biomass-Derived Furans

(2012) Yang Shi et al.   ORGANOMETALLICS

Decarboxylative benzylation and arylation of nitriles

(2011) Antonio Recio et al.   CHEMICAL COMMUNICATIONS

Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions

(2011) Jimmie D. Weaver et al.   CHEMICAL REVIEWS

Usage of the Carboxylate Leaving Group in Transition-metal-catalyzed Cross-coupling and Related Reactions

(2011) Ryoichi Kuwano   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

Palladium-Catalyzed C3-Benzylation of Indoles

(2011) Ye Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via η3-Benzylpalladium Intermediates: A New Strategy for Catalytic Dearomatization

(2011) Bo Peng et al.   ORGANIC LETTERS

Intramolecular SN′-Type Aromatic Substitution of Benzylic Carbonates at their Para-Position

(2011) Satoshi Ueno et al.   ORGANIC LETTERS

Highly Chemo- and Stereoselective Palladium-Catalyzed Transfer Semihydrogenation of Internal Alkynes Affordingcis-Alkenes

(2010) Jie Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhenium Hydride/Boron Lewis Acid Cocatalysis of Alkene Hydrogenations: Activities Comparable to Those of Precious Metal Systems

(2010) Yanfeng Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative Benzylations of Alkynes and Ketones

(2010) Robert R. P. Torregrosa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Asymmetric Benzylation of 3-Aryl Oxindoles

(2010) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 3,3-Disubstituted Oxindoles by Palladium-Catalyzed Tandem Reaction of 2-(Alkynyl)aryl Isocyanates with Benzylic Alcohols

(2010) Takeharu Toyoshima et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct Benzylation of Azoles with Benzyl Carbonates

(2010) Tomoya Mukai et al.   ORGANIC LETTERS

The η3-Furfuryl Ligand: Plausible Catalytic Intermediates and Heterocyclic η3-Benzyl Analogues with Superior Binding Ability

(2010) Rian D. Dewhurst et al.   ORGANOMETALLICS

Enantiodivergence in alkylation of 1-(6-methoxynaphth-2-yl)ethyl acetate by potassium dimethyl malonate catalyzed by chiral palladium-DUPHOS complex

(2010) Martine Assié et al.   TETRAHEDRON-ASYMMETRY

Synthesis of Stereodefined 3-Alkylideneoxindoles by Palladium-catalyzed Reactions of 2-(Alkynyl)aryl Isocyanates with Thiols and Alcohols

(2009) Tomoya Miura et al.   CHEMISTRY LETTERS

Palladium-Catalyzed Decarboxylative Benzylation of Diphenylglycinate Imines

(2009) Wendy H. Fields et al.   ORGANIC LETTERS

Catalytic Transformations of Benzylic Carboxylates and Carbonates

(2009) Ryoichi Kuwano   SYNTHESIS-STUTTGART

N,N-Dimethylformamide: much more than a solvent

(2009) Jacques Muzart   TETRAHEDRON

Activation and functionalization of benzylic derivatives by palladium catalysts

(2007) Benoît Liégault et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of benzylpalladium complexes through C–O bond cleavage of benzylic carboxylates: Development of a novel palladium-catalyzed benzylation of olefins

(2007) Hirohisa Narahashi et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY