Pd‐Catalyzed Asymmetric Allylic Substitution Annulation Using Enolizable Ketimines as Nucleophiles: An Alternative Approach to Chiral Tetrahydroindoles

A Stereoselective Synthesis of the ACE Inhibitor Trandolapril

(2019) Hans-Günther Schmalz et al.   SYNLETT

Total Synthesis of Adunctin B

(2018) Dattatraya H. Dethe et al.   JOURNAL OF ORGANIC CHEMISTRY

Desymmetrization of meso-Dibromocycloalkenes through Copper(I)-Catalyzed Asymmetric Allylic Substitution with Organolithium Reagents

(2018) Shermin S. Goh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ir/Cu Dual Catalysis: Enantio- and Diastereodivergent Access to α,α-Disubstituted α-Amino Acids Bearing Vicinal Stereocenters

(2018) Xiaohong Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Domino Aryne Annulation via a Nucleophilic–Ene Process

(2018) Hai Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Brønsted-Acid-Promoted Rh-Catalyzed Asymmetric Hydrogenation of N-Unprotected Indoles: A Cocatalysis of Transition Metal and Anion Binding

(2018) Jialin Wen et al.   ORGANIC LETTERS

Palladium-Catalyzed [3 + 2]-C–C/N–C Bond-Forming Annulation

(2018) Yang Liu et al.   ORGANIC LETTERS

Phosphine-Catalyzed Dual Umpolung Domino Michael Reaction: Facile Synthesis of Hydroindole- and Hydrobenzofuran-2-Carboxylates

(2018) Kenta Kishi et al.   ACS Catalysis

Iridium-Catalyzed Asymmetric Allylic Substitution Reactions

(2018) Qiang Cheng et al.   CHEMICAL REVIEWS

Synthesis of 2,3-dihydro-1H-pyrroles by intramolecular cyclization of N-(3-butynyl)-sulfonamides

(2017) Min-Ching Chung et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Cooperative bimetallic catalysis in asymmetric allylic substitution

(2017) Jingke Fu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Direct Activation of β-sp3-Carbons of Saturated Carboxylic Esters as Electrophilic Carbons via Oxidative Carbene Catalysis

(2017) Bin Liu et al.   ORGANIC LETTERS

(3 + 2)-Annulation of p-Quinamine and Aryne: A Strategy To Construct the Multisubstituted Hydrocarbazoles

(2017) Dengyu Xu et al.   ORGANIC LETTERS

Enantioselective N-Heterocyclic Carbene-Catalyzed [3+3] Annulation of α,β-Unsaturated Esters with Methyl Ketoimine

(2016) Wenjing Xia et al.   ADVANCED SYNTHESIS & CATALYSIS

Metal-Free Enantioselective Oxidative Arylation of Alkenes: Hypervalent-Iodine-Promoted Oxidative C−C Bond Formation

(2016) Mio Shimogaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

DiverseN-Heterocyclic Ring Systems via Aza-Heck Cyclizations ofN-(Pentafluorobenzoyloxy)sulfonamides

(2016) Ian R. Hazelden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Allylic Alkylations with Enamine Nucleophiles

(2016) Nicholas Butt et al.   CHEMICAL RECORD

Catalytic Enantioselective Desymmetrization Reactions to All-Carbon Quaternary Stereocenters

(2016) Xing-Ping Zeng et al.   CHEMICAL REVIEWS

A Concise Total Synthesis of (−)-Mesembrine

(2016) Lu-Ning Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Hydrogenation of Unprotected Indoles Catalyzed by η6-Arene/N-Me-sulfonyldiamine–Ru(II) Complexes

(2016) Taichiro Touge et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Ir/Zn Dual Catalysis for Enantio- and Diastereodivergent α-Allylation of α-Hydroxyketones

(2016) Xiaohong Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Construction of Chiral Fused Azabicycles Using a Pd-Catalyzed Allylic Substitution Cascade and Asymmetric Desymmetrization Strategy

(2016) Qianjin An et al.   ORGANIC LETTERS

Transition metal-catalyzed allylic substitution reactions with unactivated allylic substrates

(2015) Nicholas A. Butt et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Allylic Alkylation of Simple Ketones with Allylic Alcohols and Its Mechanistic Study

(2014) Xiaohong Huo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalyzed Cyclocondensation of α,β-Unsaturated Carboxylic Acids: Enantioselective Synthesis of Pyrrolidinone and Dihydropyridinone Derivatives

(2014) Xiang-Yu Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of functionalized 2-vinyl-2,3-dihydropyrroles and 3-methylene-1,2,3,4-tetrahydropyridines by palladium-catalyzed cyclization of β-enaminocarbonyl compounds with allylic bisacetates

(2014) Masahiro Yoshida et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

The Design and Synthesis of Planar Chiral Ligands and Their Application to Asymmetric Catalysis

(2014) Wanbin Zhang et al.   SYNLETT

Recent advances of desymmetrization protocol applied in natural product total synthesis

(2014) Ming Wang et al.   TETRAHEDRON LETTERS

Catalytic Asymmetric Synthesis of Allylic Alcohols and Derivatives and their Applications in Organic Synthesis

(2013) Alexandre Lumbroso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of (2S,3aR,7aS)-Benzyl Octahydro-1H-indole-2-carboxylate

(2013) Tao Shi et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

The synthesis of chiral β-aryl-α,β-unsaturated amino alcohols via a Pd-catalyzed asymmetric allylic amination

(2013) Mao Quan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Highly Efficient Narasaka-Heck Cyclizations Mediated by P(3,5-(CF3)2C6H3)3: Facile Access to N-Heterobicyclic Scaffolds

(2012) Adele Faulkner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Construction of Pyrrolidines by Palladium-Catalyzed Asymmetric [3 + 2] Cycloaddition of Trimethylenemethane with Imines

(2012) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd- and Mo-Catalyzed Asymmetric Allylic Alkylation

(2012) Barry M. Trost   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Recent advances in enantioselective organocatalyzed anhydride desymmetrization and its application to the synthesis of valuable enantiopure compounds

(2011) María D. Díaz de Villegas et al.   CHEMICAL SOCIETY REVIEWS

C–N Bond Cleavage of Allylic Amines via Hydrogen Bond Activation with Alcohol Solvents in Pd-Catalyzed Allylic Alkylation of Carbonyl Compounds

(2011) Xiaohu Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Three Decades of  -Lactamase Inhibitors

(2010) S. M. Drawz et al.   CLINICAL MICROBIOLOGY REVIEWS

Enantioselective Construction of Highly Substituted Pyrrolidines by Palladium-Catalyzed Asymmetric [3+2] Cycloaddition of Trimethylenemethane with Ketimines

(2010) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Review of multidrug-resistant and extensively drug-resistant TB: global perspectives with a focus on sub-Saharan Africa

(2010) Giovanni Battista Migliori et al.   TROPICAL MEDICINE & INTERNATIONAL HEALTH

Catalytic asymmetric allylic alkylation employing heteroatom nucleophiles: a powerful method for C–X bond formation

(2010) Barry M. Trost et al.   Chemical Science

Enamines: efficient nucleophiles for the palladium-catalyzed asymmetric allylic alkylation

(2008) Xiaohu Zhao et al.   TETRAHEDRON

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversal in enantioselectivity for the palladium-catalyzed asymmetric allylic substitution with novel metallocene-based planar chiral diphosphine ligands

(2007) Fang Xie et al.   TETRAHEDRON LETTERS