Cobalt-Catalyzed Diborylation of 1,1-disubstituted Vinylarenes: A Practical Route to Branched gem -Bis(boryl)alkanes

Benzyltriboronates: Building Blocks for Diastereoselective Carbon–Carbon Bond Formation

(2017) W. Neil Palmer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–O Functionalization of α-Oxyboronates: A Deoxygenative gem-Diborylation and gem-Silylborylation of Aldehydes and Ketones

(2017) Lu Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Asymmetric Hydroboration/Cyclization of 1,6-Enynes with Pinacolborane

(2017) Songjie Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed 1,1-Diboration of Terminal Alkynes: Scope, Mechanism, and Synthetic Applications

(2017) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of Alkenes with Tertiary Silanes

(2017) Yang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Tandem Bis-Electrophile Couplings of Diborylmethane

(2017) Stephanie A. Murray et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Free Homologative Cross-Coupling of Aldehydes and Ketones with Geminal Bis(boron) Compounds

(2017) Thomas C. Stephens et al.   ORGANIC LETTERS

Chemo- and Stereoselective Crotylation of Aldehydes and Cyclic Aldimines with Allylic gem-Diboronate Ester

(2017) Jinyoung Park et al.   ORGANIC LETTERS

Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes

(2017) Lei Li et al.   Nature Communications

Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes

(2017) Chao Wang et al.   Nature Communications

Stereoselective Synthesis of Trisubstituted Alkenes via Cobalt-Catalyzed Double Dehydrogenative Borylations of 1-Alkenes

(2017) Huanan Wen et al.   ACS Catalysis

Cobalt-Catalyzed Ligand-Controlled Regioselective Hydroboration/Cyclization of 1,6-Enynes

(2017) Tuo Xi et al.   ACS Catalysis

Insights into a Chemoselective Cobalt Catalyst for the Hydroboration of Alkenes and Nitriles

(2017) Abdulrahman D. Ibrahim et al.   ACS Catalysis

Co6H8(PiPr3)6: A Cobalt Octahedron with Face-Capping Hydrides

(2016) Yasuhiro Ohki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio- and Diastereoselective 1,2-Additions to α-Ketoesters with Diborylmethane and Substituted 1,1-Diborylalkanes

(2016) Stephanie A. Murray et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Regioselective Alkylation of Pyridine N -Oxides Using 1,1-Diborylalkanes as Alkylating Reagents

(2016) Woohyun Jo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed cross-coupling reactions of epoxides with gem-diborylmethane: access to γ-hydroxyl boronic esters

(2016) Ahmed Ebrahim-Alkhalil et al.   CHEMICAL COMMUNICATIONS

Cobalt-Catalyzed Benzylic Borylation: Enabling Polyborylation and Functionalization of Remote, Unactivated C(sp3)–H Bonds

(2016) W. Neil Palmer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modular, Catalytic Enantioselective Construction of Quaternary Carbon Stereocenters by Sequential Cross-Coupling Reactions

(2016) Bowman Potter et al.   ORGANIC LETTERS

Copper-Catalyzed Diastereoselective Addition of Diborylmethane to N-tert-Butanesulfinyl Aldimines: Synthesis of β-Aminoboronates

(2016) Jinyoung Park et al.   ORGANIC LETTERS

Cobalt-Catalyzed Regiodivergent Hydrosilylation of Vinylarenes and Aliphatic Alkenes: Ligand- and Silane-Dependent Regioselectivities

(2016) Chao Wang et al.   ACS Catalysis

Dual-Stereocontrol Asymmetric Cobalt-Catalyzed Hydroboration of Sterically Hindered Styrenes

(2016) Heyi Zhang et al.   ACS Catalysis

Synthesis of 1,1-diboronate esters by cobalt-catalyzed sequential hydroboration of terminal alkynes

(2016) Ziqing Zuo et al.   Organic Chemistry Frontiers

Rhodium-Catalyzed Dehydrogenative Borylation of Aliphatic Terminal Alkenes with Pinacolborane

(2015) Masao Morimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver(I)-Catalyzed Diastereoselective Synthesis ofanti-1,2-Hydroxyboronates

(2015) Matthew V. Joannou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Branched Alkylboronates by Copper-Catalyzed Allylic Substitution Reactions of Allylic Chlorides with 1,1-Diborylalkanes

(2015) Junghoon Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction Optimization, Scalability, and Mechanistic Insight on the Catalytic Enantioselective Desymmetrization of 1,1-Diborylalkanes via Suzuki-Miyaura Cross-Coupling

(2015) Ho-Yan Sun et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd(0)-Catalyzed Cross-Coupling of 1,1-Diboronates with 2,2′-Dibromobiphenyls: Synthesis of 9H-Fluorenes

(2015) Shuai Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations–Hydroboration

(2015) Lei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio- and Diastereoselective Synthesis of 1,2-Hydroxyboronates through Cu-Catalyzed Additions of Alkylboronates to Aldehydes

(2015) Matthew V. Joannou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt Catalyzed Z-Selective Hydroboration of Terminal Alkynes and Elucidation of the Origin of Selectivity

(2015) Jennifer V. Obligacion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Vinyl Boronates from Aldehydes by a Practical Boron–Wittig Reaction

(2015) John R. Coombs et al.   ORGANIC LETTERS

Palladium(0)-Catalyzed Cross-Coupling of 1,1-Diboronates with Vinyl Bromides and 1,1-Dibromoalkenes

(2014) Huan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane

(2014) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Synthesis of 1,1-Diborylalkanes through Regioselective Dihydroboration of Terminal Alkynes

(2014) Sumin Lee et al.   Chemistry-An Asian Journal

Nonracemic Allylic Boronates through Enantiotopic-Group-Selective Cross-Coupling of Geminal Bis(boronates) and Vinyl Halides

(2014) Bowman Potter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates

(2014) Chunrui Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple Access to Elusive α-Boryl Carbanions and Their Alkylation: An Umpolung Construction for Organic Synthesis

(2014) Kai Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes

(2014) Lei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed/Promoted Cross-coupling of gem-Diborylalkanes with Nonactivated Primary Alkyl Halides: An Alternative Route to Alkylboronic Esters

(2014) Zhen-Qi Zhang et al.   ORGANIC LETTERS

High-Activity Cobalt Catalysts for Alkene Hydroboration with Electronically Responsive Terpyridine and α-Diimine Ligands

(2014) W. Neil Palmer et al.   ACS Catalysis

Regio- and Enantioselective Copper(I)-Catalyzed Hydroboration of Borylalkenes: Asymmetric Synthesis of 1,1-Diborylalkanes

(2013) Xinhui Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bis(imino)pyridine Cobalt-Catalyzed Alkene Isomerization–Hydroboration: A Strategy for Remote Hydrofunctionalization with Terminal Selectivity

(2013) Jennifer V. Obligacion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-catalyzed diborylation of benzylic C–H bonds directed by a hydrosilyl group: synthesis of 1,1-benzyldiboronate esters

(2013) Seung Hwan Cho et al.   Chemical Science

Cross Coupling between sp3-Carbon and sp3-Carbon Using a Diborylmethane Derivative at Room Temperature

(2012) Kohei Endo et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient Synthesis of Diborylalkenes from Alkenes and Diboron by a New PSiP-Pincer Palladium-Catalyzed Dehydrogenative Borylation

(2011) Jun Takaya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

(2011) Jack Chang Hung Lee et al.   Nature Chemistry

Chemoselective Suzuki Coupling of Diborylmethane for Facile Synthesis of Benzylboronates

(2011) Kohei Endo et al.   ORGANIC LETTERS

Chemoselective and Regiospecific Suzuki Coupling on a Multisubstituted sp3-Carbon in 1,1-Diborylalkanes at Room Temperature

(2010) Kohei Endo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of cis-β-Methyl- and Phenyl-Substituted Alkenylboronates by Platinum-Catalyzed Dehydrogenative Borylation

(2009) Toshimichi Ohmura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 1,1-Organodiboronates via Rh(I)Cl-Catalyzed Sequential Regioselective Hydroboration of 1-Alkynes

(2009) Kohei Endo et al.   SYNLETT

Metal-Catalyzed Reactions of Organoboronic Acids and Esters

(2008) Norio Miyaura   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN