Copper(I)-Catalyzed Regioselective Addition of Nucleophilic Silicon Across Terminal and Internal Carbon-Carbon Triple Bonds

Copper(II)-Catalyzed Silylation of Activated Alkynes in Water: Diastereodivergent Access toE- orZ-β-Silyl-α,β-Unsaturated Carbonyl and Carboxyl Compounds

(2014) Joseph A. Calderone et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Silylcupration of Conjugated Alkynes in Water at Room Temperature

(2014) Roscoe T. H. Linstadt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Addition of Silicon Nucleophiles to Aldimines Using a Preformed NHC-Copper(I) Complex as the Catalyst

(2014) Alexander Hensel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of multi-substituted vinylsilanes via copper(i)-catalyzed hydrosilylation reactions of allenes and propiolate derivatives with silylboronates

(2014) Yun-He Xu et al.   CHEMICAL COMMUNICATIONS

CuI/Pd0Cooperative Dual Catalysis: Tunable Stereoselective Construction of Tetra-Substituted Alkenes

(2014) Sébastien Vercruysse et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Enantioselective Silylation of N-Sulfonylimines: Asymmetric Synthesis of α-Amino Acids from CO2 via Stereospecific Carboxylation of α-Amino Silanes

(2014) Tsuyoshi Mita et al.   ORGANIC LETTERS

Asymmetric Synthesis of α-Chiral Allylic Silanes by Enantioconvergent γ-Selective Copper(I)-Catalyzed Allylic Silylation

(2013) Lukas B. Delvos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Addition of Nucleophilic Silicon to Aldehydes

(2013) Virginie Cirriez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC–Cu(i) catalysed asymmetric conjugate silyl transfer to unsaturated lactones: application in kinetic resolution

(2013) Vittorio Pace et al.   CHEMICAL COMMUNICATIONS

ExceptionallyE- and β-Selective NHC-Cu-Catalyzed Proto-Silyl Additions to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes

(2013) Fanke Meng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regio- and Diastereoselective Copper(I)-Catalyzed Allylic Substitution of δ-Hydroxy Allylic Chlorides by a Silicon Nucleophile

(2013) Chinmoy K. Hazra et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of α-Tri- and α-Tetrasubstituted Allylsilanes by Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Silylboronates

(2013) Momotaro Takeda et al.   JOURNAL OF ORGANIC CHEMISTRY

Cu(I)–NHC Catalyzed Asymmetric Silyl Transfer to Unsaturated Lactams and Amides

(2013) Vittorio Pace et al.   ORGANIC LETTERS

Platinum-Catalyzed Hydrosilylations of Internal Alkynes: Harnessing Substituent Effects to Achieve High Regioselectivity

(2012) Douglas A. Rooke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Regio- and Stereoselective Hydrosilylation of Electron-Deficient Alkynes

(2012) Yuto Sumida et al.   ORGANIC LETTERS

NHC–Cu-Catalyzed Silyl Conjugate Additions to Acyclic and Cyclic Dienones and Dienoates. Efficient Site-, Diastereo- and Enantioselective Synthesis of Carbonyl-Containing Allylsilanes

(2012) Kang-sang Lee et al.   ORGANOMETALLICS

(E)- and (Z)-β-Borylallylsilanes by Alkyne Silaboration Followed by Regio- and Stereoselective Double-Bond Migration

(2011) Toshimichi Ohmura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed 1,2-Addition of Nucleophilic Silicon to Aldehydes: Mechanistic Insight and Catalytic Systems

(2011) Christian Kleeberg et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Highly Regioselective Silylcupration of Terminal Alkynes to Form α-Vinylsilanes

(2011) Peng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Directing Group-Controlled Hydrosilylation: Regioselective Functionalization of Alkyne

(2011) Yuuya Kawasaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of the Si−B Linkage: Copper-Catalyzed Addition of Nucleophilic Silicon to Imines

(2011) Devendra J. Vyas et al.   ORGANIC LETTERS

Copper-Catalyzed SiB Bond Activation in Branched-Selective Allylic Substitution of Linear Allylic Chlorides

(2010) Devendra J. Vyas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Syntheses of Trisubstituted Olefins via Platinum Catalysis: α-Silylenones with Geometrical Complementarity

(2010) Douglas A. Rooke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes

(2010) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination

(2010) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

SmI2-Mediated Radical Cyclizations Directed by a C−Si Bond

(2010) Hassan Y. Harb et al.   ORGANIC LETTERS

Silylboranes as New Tools in Organic Synthesis

(2009) Toshimichi Ohmura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Silicon- and Tin-Based Cuprates: Now Catalytic in Copper!

(2009) Andreas Weickgenannt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes

(2008) Toshimichi Ohmura et al.   CHEMICAL COMMUNICATIONS

Highly β-(E)-Selective Hydrosilylation of Terminal and Internal Alkynes Catalyzed by a (IPr)Pt(diene) Complex

(2008) Guillaume Berthon-Gelloz et al.   JOURNAL OF ORGANIC CHEMISTRY