Regio- and Enantioselective Monoborylation of Alkenylsilanes Catalyzed by an Electron-Donating Chiral Phosphine-Copper(I) Complex

Regio- and Enantioselective Copper(I)-Catalyzed Hydroboration of Borylalkenes: Asymmetric Synthesis of 1,1-Diborylalkanes

(2013) Xinhui Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ExceptionallyE- and β-Selective NHC-Cu-Catalyzed Proto-Silyl Additions to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes

(2013) Fanke Meng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regioselective and Stereospecific Copper-Catalyzed Aminoboration of Styrenes with Bis(pinacolato)diboron and O-Benzoyl-N,N-dialkylhydroxylamines

(2013) Naoki Matsuda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Borylative exo-Cyclization of Alkenyl Halides Containing Unactivated Double Bond

(2013) Koji Kubota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Copper(I)-Catalyzed Borylative Aldol Cyclizations of Enone Diones

(2012) Alan R. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Copper(I)-Catalyzed Boryl Substitution of Unactivated Alkyl Halides

(2012) Hajime Ito et al.   ORGANIC LETTERS

Highly Enantio- and Diastereoselective Synthesis of γ-Amino Alcohols from α,β-Unsaturated Imines through a One-Pot β-Boration/Reduction/Oxidation Sequence

(2011) Cristina Solé et al.   ADVANCED SYNTHESIS & CATALYSIS

NHC-Cu-Catalyzed Enantioselective Hydroboration of Acyclic and Exocyclic 1,1-Disubstituted Aryl Alkenes

(2011) Rosa Corberán et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic asymmetric conjugate boration of α,β-unsaturated sulfones

(2011) Abraham L. Moure et al.   CHEMICAL COMMUNICATIONS

Rigid P-Chiral Phosphine Ligands with tert-Butylmethylphosphino Groups for Rhodium-Catalyzed Asymmetric Hydrogenation of Functionalized Alkenes

(2011) Tsuneo Imamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

(2011) Jack Chang Hung Lee et al.   Nature Chemistry

Enantioselective Synthesis oftrans-Aryl- and -Heteroaryl-Substituted Cyclopropylboronates by Copper(I)-Catalyzed Reactions of Allylic Phosphates with a Diboron Derivative

(2010) Chongmin Zhong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Synthesis of Cyclobutylboronates through Copper(I)-Catalyzed Reaction of Homoallylic Sulfonates and a Diboron Derivative

(2010) Hajime Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Boron-Substituted Quaternary Carbons by NHC−Cu-Catalyzed Boronate Conjugate Additions to Unsaturated Carboxylic Esters, Ketones, or Thioesters

(2010) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Asymmetric Monoborylation of 1,3-Dienes: Synthesis of Enantioenriched Cyclic Homoallyl- and Allylboronates

(2010) Yusuke Sasaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct enantio-convergent transformation of racemic substrates without racemization or symmetrization

(2010) Hajime Ito et al.   Nature Chemistry

Highly Regio- and Enantioselective Copper-Catalyzed Hydroboration of Styrenes

(2009) Dongwan Noh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Desymmetrization of meso-2-Alkene-1,4-diol Derivatives through Copper(I)-Catalyzed Asymmetric Boryl Substitution and Stereoselective Allylation of Aldehydes

(2009) Hajime Ito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

(2009) Christian Kleeberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boryl ligands and their roles in metal-catalysed borylation reactions

(2009) Li Dang et al.   CHEMICAL COMMUNICATIONS

Pt-Catalyzed Enantioselective Diboration of Terminal Alkenes with B2(pin)2

(2009) Laura T. Kliman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Chiral Tertiary Organoboronic Esters through Conjugate Boration of β-Substituted Cyclic Enones

(2009) I-Hon Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Boron−Copper Additions to Aryl-Substituted Alkenes Promoted by NHC−Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Optically Active Boron-Silicon Bifunctional Cyclopropane Derivatives through Enantioselective Copper(I)-Catalyzed Reaction of Allylic Carbonates with a Diboron Derivative

(2008) Hajime Ito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Amide-Directed Catalytic Asymmetric Hydroboration

(2008) Sean M. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Substitution of Propargylic Carbonates with Diboron: Selective Synthesis of Multisubstituted Allenylboronates

(2008) Hajime Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols

(2008) Jake L. Stymiest et al.   NATURE

Understanding the Higher Reactivity of B2cat2versus B2pin2in Copper(I)-Catalyzed Alkene Diboration Reactions

(2008) Li Dang et al.   ORGANOMETALLICS

Asymmetric β-Boration of α,β-Unsaturated Esters with Chiral (NHC)Cu Catalysts

(2008) Vanesa Lillo et al.   ORGANOMETALLICS

Catalytic Asymmetric Boration of Acyclic α,β-Unsaturated Esters and Nitriles

(2007) Ji-Eon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION