Cobalt-Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity

Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes

(2016) Daisuke Noda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oligoarginine peptides slow strand annealing and assist non-enzymatic RNA replication

(2016) Tony Z. Jia et al.   Nature Chemistry

A (Borylmethyl)silane Bearing Three Hydrolyzable Groups on Silicon: Synthesis via Iridium-Catalyzed C(sp3)–H Borylation and Conversion to Functionalized Siloxanes

(2016) Toshimichi Ohmura et al.   ORGANOMETALLICS

(N-Heterocyclic Carbene)2-Pd(0)-Catalyzed Silaboration of Internal and Terminal Alkynes: Scope and Mechanistic Studies

(2016) Melvyn B. Ansell et al.   ACS Catalysis

Synthesis of 1,1-diboronate esters by cobalt-catalyzed sequential hydroboration of terminal alkynes

(2016) Ziqing Zuo et al.   Organic Chemistry Frontiers

Corrigendum: Crowdsourcing Natural Products Discovery to Access Uncharted Dimensions of Fungal Metabolite Diversity

(2015) Lin Du et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations–Hydroboration

(2015) Lei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism, reactivity, and selectivity of the iridium-catalyzed C(sp3)–H borylation of chlorosilanes

(2015) Genping Huang et al.   Chemical Science

Cobalt Complex-Catalyzed Hydrosilylation of Alkenes and Alkynes

(2015) Jian Sun et al.   ACS Catalysis

Iron-Catalysed Chemo-, Regio-, and Stereoselective Hydrosilylation of Alkenes and Alkynes using a Bench-Stable Iron(II) Pre-Catalyst

(2014) Mark D. Greenhalgh et al.   ADVANCED SYNTHESIS & CATALYSIS

A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane

(2014) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalysed Hydrofunctionalisation of Alkenes and Alkynes

(2014) Mark D. Greenhalgh et al.   ChemCatChem

Highly Regioselective Hydrosilylation of Unsymmetric Alkynes Using a Phenylthio Directing Group

(2014) Kuan-Hsun Huang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes

(2014) Lei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis(imino)pyridine Cobalt-Catalyzed Dehydrogenative Silylation of Alkenes: Scope, Mechanism, and Origins of Selective Allylsilane Formation

(2014) Crisita Carmen Hojilla Atienza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes

(2014) Zhenbo Mo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes

(2014) Jianhui Chen et al.   Organic Chemistry Frontiers

Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane

(2013) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anchoring of Silyl Donors on a N-Heterocyclic Carbene through the Cobalt-Mediated Silylation of Benzylic CH Bonds

(2013) Zhenbo Mo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Borole Formation by 1,1-Carboboration

(2013) Fang Ge et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphinite-Iminopyridine Iron Catalysts for Chemoselective Alkene Hydrosilylation

(2013) Dongjie Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formal Carbon Insertion of N-Tosylhydrazone into B–B and B–Si Bonds: gem-Diborylation and gem-Silylborylation of sp3 Carbon

(2013) Huan Li et al.   ORGANIC LETTERS

Functionalization of Tetraorganosilanes and Permethyloligosilanes at a Methyl Group on Silicon via Iridium-Catalyzed C(sp3)–H Borylation

(2013) Toshimichi Ohmura et al.   ORGANOMETALLICS

Aryl–aryl interactions as directing motifs in the stereodivergent iron-catalyzed hydrosilylation of internal alkynes

(2012) Christian Belger et al.   CHEMICAL COMMUNICATIONS

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)–H Borylation of Methylchlorosilanes

(2012) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

General and Practical One-Pot Synthesis of Dihydrobenzosiloles from Styrenes

(2012) Alexey Kuznetsov et al.   ORGANIC LETTERS

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

(2012) A. M. Tondreau et al.   SCIENCE

Copper-Catalyzed Highly Regioselective Silylcupration of Terminal Alkynes to Form α-Vinylsilanes

(2011) Peng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Tertiary and Quaternary Allyl- and Crotylsilanes via the Borylation of Lithiated Carbamates

(2011) Varinder K. Aggarwal et al.   ORGANIC LETTERS

Iridium-Catalyzed AreneOrtho-Silylation by Formal Hydroxyl-Directed C−H Activation

(2010) Eric M. Simmons et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Synthesis of Cyclobutylboronates through Copper(I)-Catalyzed Reaction of Homoallylic Sulfonates and a Diboron Derivative

(2010) Hajime Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silylboranes as New Tools in Organic Synthesis

(2009) Toshimichi Ohmura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Remarkable access to fluoroalkylated trisubstituted alkenes via highly stereoselective cobalt-catalyzed hydrosilylation reaction of fluoroalkylated alkynes

(2009) Tsutomu Konno et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Optically Active Boron-Silicon Bifunctional Cyclopropane Derivatives through Enantioselective Copper(I)-Catalyzed Reaction of Allylic Carbonates with a Diboron Derivative

(2008) Hajime Ito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION