Regiodivergent and Stereoselective Hydrosilylation of 1,3-Disubstituted Allenes

Highly efficient regioselective hydrosilylation of allenes using a [(3IP)Pd(allyl)]OTf catalyst; first example of allene hydrosilylation with phenyl- and diphenylsilane

(2015) Hosein Tafazolian et al.   CHEMICAL COMMUNICATIONS

Regiocontrol in Catalytic Reductive Couplings through Alterations of Silane Rate Dependence

(2015) Evan P. Jackson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzedtrans-Selective Hydrostannation of Alkynes

(2014) Stephan M. Rummelt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unlocking theN2 Selectivity of Benzotriazoles: Regiodivergent and Highly Selective Coupling of Benzotriazoles with Allenes

(2014) Kun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atom-Economic, Regiodivergent, and Stereoselective Coupling of Imidazole Derivatives with Terminal Allenes

(2014) Kun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanisms and Origins of Switchable Regioselectivity of Palladium- and Nickel-Catalyzed Allene Hydrosilylation with N-Heterocyclic Carbene Ligands: A Theoretical Study

(2014) Hujun Xie et al.   JOURNAL OF ORGANIC CHEMISTRY

Rational Design of a Second Generation Catalyst for Preparation of Allylsilanes Using the Silyl-Heck Reaction

(2014) Jesse R. McAtee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dimer Involvement and Origin of Crossover in Nickel-Catalyzed Aldehyde–Alkyne Reductive Couplings

(2014) M. Taylor Haynes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Regiodivergent Silacarboxylation of Allenes with Carbon Dioxide and a Silylborane

(2014) Yosuke Tani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Allene Hydroarylation via One-Pot Allene Hydrosilylation/Pd-Catalyzed Cross-Coupling

(2014) Zachary D. Miller et al.   ORGANIC LETTERS

The first example of nickel-catalyzed silyl-Heck reactions: direct activation of silyl triflates without iodide additives

(2014) Jesse R. McAtee et al.   TETRAHEDRON

Atrans-Selective Hydroboration of Internal Alkynes

(2013) Basker Sundararaju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Allene Hydrosilylation Catalyzed by N-Heterocyclic Carbene Complexes of Nickel and Palladium

(2013) Zachary D. Miller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of Vinyl Silyl Ethers and Disiloxanes via the Silyl-Heck Reaction of Silyl Ditriflates

(2013) Sara E. S. Martin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Functional-Group-Tolerant Catalytictrans Hydrogenation of Alkynes

(2012) Karin Radkowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of Allyl and Vinyl Silanes by the Palladium-Catalyzed Silylation of Terminal Olefins: A Silyl-Heck Reaction

(2012) Jesse R. McAtee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Platinum-Catalyzed Hydrosilylations of Internal Alkynes: Harnessing Substituent Effects to Achieve High Regioselectivity

(2012) Douglas A. Rooke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper(I)-Catalyzed Regio- and Chemoselective Single and Double Addition of Nucleophilic Silicon to Propargylic Chlorides and Phosphates

(2012) Chinmoy K. Hazra et al.   ORGANIC LETTERS

Silicon-based cross-coupling reaction: an environmentally benign version

(2011) Yoshiaki Nakao et al.   CHEMICAL SOCIETY REVIEWS

Ligand Steric Contours To Understand the Effects ofN-Heterocyclic Carbene Ligands on the Reversal of Regioselectivity in Ni-Catalyzed Reductive Couplings of Alkynes and Aldehydes

(2011) Peng Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Directing Group-Controlled Hydrosilylation: Regioselective Functionalization of Alkyne

(2011) Yuuya Kawasaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ladder Polyether Synthesis via Epoxide-Opening Cascades Directed by a Disappearing Trimethylsilyl Group

(2010) Timothy P. Heffron et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereoselective Syntheses of Trisubstituted Olefins via Platinum Catalysis: α-Silylenones with Geometrical Complementarity

(2010) Douglas A. Rooke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A General Strategy for Regiocontrol in Nickel-Catalyzed Reductive Couplings of Aldehydes and Alkynes

(2010) Hasnain A. Malik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Strategy for the Synthesis of Well-Defined Iron Catalysts and Application to Regioselective Diene Hydrosilylation

(2010) Jessica Y. Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unusual regiodivergence in metal-catalysed intramolecular cyclisation of γ-allenols

(2009) Jannine L. Arbour et al.   CHEMICAL COMMUNICATIONS

Pd-Catalyzed Synthesis of Allylic Silanes from Allylic Ethers

(2009) Ralph Moser et al.   ORGANIC LETTERS

Highly β-(E)-Selective Hydrosilylation of Terminal and Internal Alkynes Catalyzed by a (IPr)Pt(diene) Complex

(2008) Guillaume Berthon-Gelloz et al.   JOURNAL OF ORGANIC CHEMISTRY

A Mechanism for the Palladium-Catalyzed Regioselective Silaboration of Allene: A Theoretical Study

(2008) Yoko Abe et al.   ORGANOMETALLICS