Regioselective direct arylation of indoles on the benzenoid moiety

Diverse ortho-C(sp2)–H Functionalization of Benzaldehydes Using Transient Directing Groups

(2017) Xi-Hai Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Unified Modular Synthetic Strategy for Dictyodendrins F, H, I, and G

(2017) Sreenivas Banne et al.   ORGANIC LETTERS

Mild and selective base-free C–H arylation of heteroarenes: experiment and computation

(2017) Hannes P. L. Gemoets et al.   Chemical Science

Remote C6-Selective Ruthenium-Catalyzed C–H Alkylation of Indole Derivatives via σ-Activation

(2017) Jamie A. Leitch et al.   ACS Catalysis

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds

(2016) Joshua R. Hummel et al.   CHEMICAL REVIEWS

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Iridium(III)-Catalyzed Regioselective C7-Amination of N-Pivaloylindoles with Sulfonoazides

(2016) Lanting Xu et al.   JOURNAL OF ORGANIC CHEMISTRY

A Concise Total Synthesis of Dictyodendrins F, H, and I Using Aryl Ynol Ethers as Key Building Blocks

(2016) Wenhan Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C–H Arylation of Indoles at the C7 Position

(2016) Youqing Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Direct C6-Arylation of Indoles

(2016) Youqing Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium(iii)-catalyzed regioselective C7-sulfonamidation of indoles

(2016) Zengqiang Song et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Direct Access to 7-Aminoindoles via Iridium-Catalyzed Mild C–H Amidation of N-Pivaloylindoles with Organic Azides

(2016) Youyoung Kim et al.   ORGANIC LETTERS

Hexafluoro-2-propanol-Promoted Intermolecular Friedel–Crafts Acylation Reaction

(2016) Rakesh H. Vekariya et al.   ORGANIC LETTERS

Direct and site-selective Pd(ii)-catalyzed C-7 arylation of indolines with arylsilanes

(2016) Haiqing Luo et al.   RSC Advances

Transition Metal-Catalyzed CH Activation of Indoles

(2015) Alexander H. Sandtorv   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Regioselective C7-Functionalization of N -Pivaloylindoles

(2015) Lanting Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Concise and Scalable Strategy for the Total Synthesis of Dictyodendrin B Based on Sequential CH Functionalization

(2015) Andrew K. Pitts et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Verruculogen and Fumitremorgin A Enabled by Ligand-Controlled C–H Borylation

(2015) Yu Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Atom-Economical Transformation of Diaryliodonium Salts: Tandem C–H and N–H Arylation of Indoles

(2015) Sachin G. Modha et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd/C as a Catalyst for Completely Regioselective CH Functionalization of Thiophenes under Mild Conditions

(2014) Dan-Tam D. Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Methylation of CH Bonds Using CO2and H2

(2014) Yuehui Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Using ‘biased-privileged’ scaffolds to identify lysine methyltransferase inhibitors

(2014) Sudhir Kashyap et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Copper-Catalyzed C–H Functionalization Reactions: Efficient Synthesis of Heterocycles

(2014) Xun-Xiang Guo et al.   CHEMICAL REVIEWS

Total Synthesis of Dictyodendrins B and E, and Formal Synthesis of Dictyodendrin C

(2014) Pengyu Tao et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

C7-Derivatization of C3-Alkylindoles Including Tryptophans and Tryptamines

(2014) Richard P. Loach et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd(II)-Catalyzed meta-C–H Olefination, Arylation, and Acetoxylation of Indolines Using a U-Shaped Template

(2014) Guoqiang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Direct Denitrogenative C-3-Arylation of 1H-Indoles with Arylhydrazines using Air as the Oxidant

(2013) Yongxin Chen et al.   ADVANCED SYNTHESIS & CATALYSIS

“On Water”, Phosphine-Free Palladium-Catalyzed Room Temperature CH Arylation of Indoles

(2013) Saidul Islam et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Phenanthridine Derivatives by Microwave-Mediated Cyclization of o-Furyl(allylamino)arenes

(2013) Matthew Lovell Read et al.   JOURNAL OF ORGANIC CHEMISTRY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Facile construction of pyrrolophenanthridone skeleton via a one-pot intramolecular Heck reaction and oxidation

(2013) Wei Cong et al.   TETRAHEDRON

Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization

(2012) Sharon R. Neufeldt et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cobalt-Catalyzed Direct Arylation and Benzylation by CH/CO Cleavage with Sulfamates, Carbamates, and Phosphates

(2012) Weifeng Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed CH Oxidation/Cross-Coupling of α-Amino Carbonyl Compounds

(2012) Ji-Cheng Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed dual C–H or N–H functionalization of unfunctionalized indole derivatives with alkenes and arenes

(2012) Gianluigi Broggini et al.   Beilstein Journal of Organic Chemistry

Recent advances in transition-metal catalyzed reactions using molecular oxygen as the oxidant

(2012) Zhuangzhi Shi et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Dehydrogenative β′-Functionalization of β-Keto Esters with Indoles at Room Temperature

(2012) Mikko V. Leskinen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A C–H Borylation Approach to Suzuki–Miyaura Coupling of Typically Unstable 2–Heteroaryl and Polyfluorophenyl Boronates

(2012) Daniel W. Robbins et al.   ORGANIC LETTERS

Adding Aliphatic C-H Bond Oxidations to Synthesis

(2012) M. C. White   SCIENCE

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Update 1 of: Synthesis and Functionalization of Indoles Through Palladium-Catalyzed Reactions

(2011) Sandro Cacchi et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed CH Bond Functionalization of a Metal-Organic Framework (MOF): Mild, Selective, and Efficient

(2011) Thomas Dröge et al.   CHEMISTRY-A EUROPEAN JOURNAL

Intramolecular Oxidative C−H Coupling for Medium-Ring Synthesis

(2011) Didier G. Pintori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild and Selective Ru-Catalyzed Formylation and Fe-Catalyzed Acylation of Free (N–H) Indoles Using Anilines as the Carbonyl Source

(2011) Wenliang Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C3-Benzylation of Indoles

(2011) Ye Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Dictyodendrin A and B

(2010) Kentaro Okano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative dimerization of N-protected and free indole derivatives toward 3,3′-biindoles via Pd-catalyzed direct C–H transformations

(2010) Yang Li et al.   CHEMICAL COMMUNICATIONS

Regioselective Oxidative Arylation of Indoles BearingN-Alkyl Protecting Groups: Dual C−H Functionalization via a Concerted Metalation−Deprotonation Mechanism

(2010) Shathaverdhan Potavathri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed, Silyl-Directed Borylation of Nitrogen-Containing Heterocycles

(2010) Daniel W. Robbins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Direct Cyanation of Indoles with K4[Fe(CN)6]

(2010) Guobing Yan et al.   ORGANIC LETTERS

Transition Metal-Catalysed, Direct and Site-Selective N1-, C2- or C3-Arylation of the Indole Nucleus: 20 Years of Improvements

(2009) Lionel Joucla et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Functionalization of Indoles in a New Dimension

(2009) Marco Bandini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Chloropeptin II (Complestatin) and Chloropeptin I

(2009) Joie Garfunkle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular Decarboxylative Direct C-3 Arylation of Indoles with Benzoic Acids

(2009) Josep Cornella et al.   ORGANIC LETTERS

A Meta-Selective Copper-Catalyzed C-H Bond Arylation

(2009) R. J. Phipps et al.   SCIENCE

A formal total synthesis of the telomerase inhibitor dictyodendrin B

(2009) Shotaro Hirao et al.   TETRAHEDRON LETTERS

Palladium-Catalyzed Direct Arylation of (Hetero)Arenes with Aryl Boronic Acids

(2008) Shang-Dong Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Palladium-Catalyzed C-3 Arylation of Free (NH)-Indoles with Aryl Bromides under Ligandless Conditions

(2008) Fabio Bellina et al.   JOURNAL OF ORGANIC CHEMISTRY

Room Temperature and Phosphine Free Palladium Catalyzed Direct C-2 Arylation of Indoles

(2008) Nathalie Lebrasseur et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(II)-Catalyzed Direct and Site-Selective Arylation of Indoles Under Mild Conditions

(2008) Robert J. Phipps et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

First heterogeneously palladium-catalysed fully selective C3-arylation of free NH-indoles

(2008) Giuseppe Cusati et al.   TETRAHEDRON LETTERS