Reversible cyclometalation at RhI as a motif for metal–ligand bifunctional bond activation and base-free formic acid dehydrogenation

Hydrogenation of CO2 to formic acid with iridiumIII(bisMETAMORPhos)(hydride): the role of a dormant fac-IrIII(trihydride) and an active trans-IrIII(dihydride) species

(2016) S. Oldenhof et al.   Catalysis Science & Technology

CH Activation of Benzene by a Photoactivated NiII(azide): Formation of a Transient Nickel Nitrido Complex

(2015) Vincent Vreeken et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Ligand Cooperation

(2015) Julia R. Khusnutdinova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular C–H activation with an Ir-METAMORPhos piano-stool complex – multiple reaction steps at a reactive ligand

(2015) S. Oldenhof et al.   CHEMICAL COMMUNICATIONS

New avenues for ligand-mediated processes – expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands

(2015) Daniël L. J. Broere et al.   CHEMICAL SOCIETY REVIEWS

Dynamic Ligand Reactivity in a Rhodium Pincer Complex

(2015) Zhou Tang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Facile Synthesis and Versatile Reactivity of an Unusual Cyclometalated Rhodium(I) Pincer Complex

(2015) Linda S. Jongbloed et al.   CHEMISTRY-A EUROPEAN JOURNAL

Amine-Free Reversible Hydrogen Storage in Formate Salts Catalyzed by Ruthenium Pincer Complex without pH Control or Solvent Change

(2015) Jotheeswari Kothandaraman et al.   ChemSusChem

A new class of PN3-pincer ligands for metal–ligand cooperative catalysis

(2015) Huaifeng Li et al.   COORDINATION CHEMISTRY REVIEWS

Formation and Site-Selective Reactivity of a Nonsymmetric Dinuclear Iridium BisMETAMORPhos Complex

(2015) Sander Oldenhof et al.   ORGANOMETALLICS

Metal-ligand cooperation by aromatization-dearomatization as a tool in single bond activation

(2015) D. Milstein   PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES

Dehydrogenation of formic acid by Ir–bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand

(2015) Sander Oldenhof et al.   Chemical Science

Iron(II) Complexes of the Linear rac-Tetraphos-1 Ligand as Efficient Homogeneous Catalysts for Sodium Bicarbonate Hydrogenation and Formic Acid Dehydrogenation

(2015) Federica Bertini et al.   ACS Catalysis

SHELXT– Integrated space-group and crystal-structure determination

(2015) George M. Sheldrick   Acta Crystallographica A-Foundation and Advances

An Isolated Nitridyl Radical-Bridged {Rh(N.)Rh} Complex

(2014) Yann Gloaguen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Active Ligand-Induced Homolytic Bond Activation

(2014) Daniël L. J. Broere et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Efficient Reversible Hydrogenation of Carbon Dioxide to Formates Using a Ruthenium PNP-Pincer Catalyst

(2014) Georgy A. Filonenko et al.   ChemCatChem

Bond Activation and Catalysis by Ruthenium Pincer Complexes

(2014) Chidambaram Gunanathan et al.   CHEMICAL REVIEWS

Methandiide as a Non-Innocent Ligand in Carbene Complexes: From the Electronic Structure to Bond Activation Reactions and Cooperative Catalysis

(2014) Julia Becker et al.   CHEMISTRY-A EUROPEAN JOURNAL

Formic Acid Dehydrogenation with Bioinspired Iridium Complexes: A Kinetic Isotope Effect Study and Mechanistic Insight

(2014) Wan-Hui Wang et al.   ChemSusChem

Mechanistic Studies of Ammonia Borane Dehydrogenation Catalyzed by Iron Pincer Complexes

(2014) Papri Bhattacharya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Redox-Active Ligand-to-Substrate Single-Electron Transfer: Radical Reactivity with a Palladium(II) Complex

(2014) Daniël L. J. Broere et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid-Assisted Formic Acid Dehydrogenation Using a Pincer-Supported Iron Catalyst

(2014) Elizabeth A. Bielinski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aluminium–ligand cooperation promotes selective dehydrogenation of formic acid to H2 and CO2

(2014) T. W. Myers et al.   Chemical Science

The NH Functional Group in Organometallic Catalysis

(2013) Baoguo Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Free Production of H2by Dehydrogenation of Formic Acid Using An Iridium-bisMETAMORPhos Complex

(2013) Sander Oldenhof et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis, Coordination Chemistry, and Cooperative Activation of H2with Ruthenium Complexes of Proton-Responsive METAMORPhos Ligands

(2013) Frédéric G. Terrade et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

C-H Activation at a Ruthenium(II) Complex - The Key Step for a Base-Free Catalytic Transfer Hydrogenation?

(2013) Leila Taghizadeh Ghoochany et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand

(2013) Yann Gloaguen et al.   INORGANIC CHEMISTRY

Hemilabile N-Xylyl-N′-methylperimidine Carbene Iridium Complexes as Catalysts for C–H Activation and Dehydrogenative Silylation: Dual Role of N-Xylyl Moiety for ortho-C–H Bond Activation and Reductive Bond Cleavage

(2013) Gyeongshin Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Water, Ammonia, and Other Small Molecules by PCcarbeneP Nickel Pincer Complexes

(2013) Dmitry V. Gutsulyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A homogeneous transition metal complex for clean hydrogen production from methanol–water mixtures

(2013) Rafael E. Rodríguez-Lugo et al.   Nature Chemistry

Hydroxy-substituted pyridine-like N-heterocycles: versatile ligands in organometallic catalysis

(2013) Wan-Hui Wang et al.   NEW JOURNAL OF CHEMISTRY

Reductive Elimination at an Ortho-Metalated Iridium(III) Hydride Bearing a Tripodal Tetraphosphorus Ligand

(2013) Yann Gloaguen et al.   ORGANOMETALLICS

Mesoionic Complexes of Platinum(II) Derived from “Rollover” Cyclometalation: A Delicate Balance between Pt–C(sp3) and Pt–C(sp2) Bond Cleavage as a Result of Different Reaction Conditions

(2013) Luca Maidich et al.   ORGANOMETALLICS

Heterolytic Cleavage of Dihydrogen by an Iron(II) PNP Pincer Complex via Metal–Ligand Cooperation

(2013) Bernhard Bichler et al.   ORGANOMETALLICS

Metal or Nonmetal Cooperation with a Phenyl Group: Route to Catalysis? A Computational Investigation

(2013) Kamalika Ghatak et al.   ACS Catalysis

Cooperative Catalysis by Iridium Complexes with a Bipyridonate Ligand: Versatile Dehydrogenative Oxidation of Alcohols and Reversible Dehydrogenation-Hydrogenation between 2-Propanol and Acetone

(2012) Ryoko Kawahara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

6,6′-Dihydroxy terpyridine: a proton-responsive bifunctional ligand and its application in catalytic transfer hydrogenation of ketones

(2012) Cameron M. Moore et al.   CHEMICAL COMMUNICATIONS

Redox-active ligands in catalysis

(2012) Oana R. Luca et al.   CHEMICAL SOCIETY REVIEWS

N–H bond activation by palladium(ii) and copper(i) complexes featuring a reactive bidentate PN-ligand

(2012) Sandra Y. de Boer et al.   DALTON TRANSACTIONS

Towards the development of a hydrogen battery

(2012) Albert Boddien et al.   Energy & Environmental Science

Rollover Cyclometalation Pathway in Rhodium Catalysis: Dramatic NHC Effects in the C–H Bond Functionalization

(2012) Jaesung Kwak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures

(2012) Jonathan F. Hull et al.   Nature Chemistry

Selective Au–C Cleavage in (C∧N∧C)Au(III) Aryl and Alkyl Pincer Complexes

(2012) Dan A. Smith et al.   ORGANOMETALLICS

Long-range metal–ligand bifunctional catalysis: cyclometallated iridium catalysts for the mild and rapid dehydrogenation of formic acid

(2012) Jonathan H. Barnard et al.   Chemical Science

Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

(2012) Volodymyr Lyaskovskyy et al.   ACS Catalysis

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Dinuclear Copper(I) Thiolate Complexes with a Bridging Noninnocent PNP Ligand

(2011) Jarl Ivar van der Vlugt et al.   CHEMISTRY-A EUROPEAN JOURNAL

New possible mode of ligand–metal cooperation in PC(sp3)P pincer complexes

(2011) Sanaa Musa et al.   DALTON TRANSACTIONS

Pincer ligands with an all-phosphorus donor set: subtle differences between rhodium and palladium

(2011) Richard C. Bauer et al.   DALTON TRANSACTIONS

Cooperative Aliphatic PNP Amido Pincer Ligands - Versatile Building Blocks for Coordination Chemistry and Catalysis

(2011) Sven Schneider et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative Catalysis with First-Row Late Transition Metals

(2011) Jarl Ivar van der Vlugt   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

CuI click catalysis with cooperative noninnocent pyridylphosphine ligands

(2011) Sandra Y. de Boer et al.   INORGANICA CHIMICA ACTA

Mechanistic Studies on the Reversible Hydrogenation of Carbon Dioxide Catalyzed by an Ir-PNP Complex

(2011) Ryo Tanaka et al.   ORGANOMETALLICS

Tunable Hemilabile Ligands for Adaptive Transition Metal Complexes

(2011) Ronald Lindner et al.   ORGANOMETALLICS

Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst

(2011) A. Boddien et al.   SCIENCE

“Rollover” cyclometalation – early history, recent developments, mechanistic insights and application aspects

(2011) Burkhard Butschke et al.   Chemical Science

Ir-Catalysed Asymmetric Allylic Substitutions with Cyclometalated (Phosphoramidite)Ir Complexes-Resting States, Catalytically Active (π-Allyl)Ir Complexes and Computational Exploration

(2010) Jevgenij A. Raskatov et al.   CHEMISTRY-A EUROPEAN JOURNAL

The dehydrogenation of ammonia–borane catalysed by dicarbonylruthenacyclic(ii) complexes

(2010) Cédric Boulho et al.   DALTON TRANSACTIONS

Quest for metal/NH bifunctional bioinspired catalysis in a dinuclear platform

(2010) Shigeki Kuwata et al.   DALTON TRANSACTIONS

Carbon dioxide and formic acid—the couple for environmental-friendly hydrogen storage?

(2010) Stephan Enthaler et al.   Energy & Environmental Science

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Discovery of Environmentally Benign Catalytic Reactions of Alcohols Catalyzed by Pyridine-Based Pincer Ru Complexes, Based on Metal–Ligand Cooperation

(2010) David Milstein   TOPICS IN CATALYSIS

Neutral Tridentate PNP Ligands and Their Hybrid Analogues: Versatile Non-Innocent Scaffolds for Homogeneous Catalysis

(2009) Jarl Ivar van der Vlugt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

EVAL15: a diffraction data integration method based onab initiopredicted profiles

(2009) Antoine M. M. Schreurs et al.   JOURNAL OF APPLIED CRYSTALLOGRAPHY

N^N^C platinum(II) and palladium(II) cyclometallates of 6,6′-diphenyl-2,2′-bipyridine, L: Crystal and molecular structure of [Pd(L–H)Cl]

(2009) Antonio Zucca et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

A Cationic AgI(PNPtBu) Species Acting as PNP Transfer Agent: Facile Synthesis of Pd(PNPtBu)(alkyl) Complexes and Their Reactivity Compared to PCPtBuAnalogues

(2009) Jarl Ivar van der Vlugt et al.   ORGANOMETALLICS

Modularly Designed Transition Metal PNP and PCP Pincer Complexes based on Aminophosphines: Synthesis and Catalytic Applications

(2008) David Benito-Garagorri et al.   ACCOUNTS OF CHEMICAL RESEARCH

Controlled Generation of Hydrogen from Formic Acid Amine Adducts at Room Temperature and Application in H2/O2Fuel Cells

(2008) Björn Loges et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cationic and neutral NiIIcomplexes containing a non-innocent PNP ligand: formation of alkyl and thiolate species

(2008) Jarl Ivar van der Vlugt et al.   DALTON TRANSACTIONS

Selective decarbonylation by a pincer PCP-rhodium(I) complex

(2008) Kuo-Wei Huang et al.   INORGANICA CHIMICA ACTA