Dynamic Ligand Reactivity in a Rhodium Pincer Complex

Nickel-Catalyzed Monoarylation of Ammonia

(2015) Andrey Borzenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Metal-Ligand Cooperative Pathway for Intermolecular Oxa-Michael Additions to Unsaturated Nitriles

(2015) Sébastien Perdriau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile Synthesis and Versatile Reactivity of an Unusual Cyclometalated Rhodium(I) Pincer Complex

(2015) Linda S. Jongbloed et al.   CHEMISTRY-A EUROPEAN JOURNAL

A new class of PN3-pincer ligands for metal–ligand cooperative catalysis

(2015) Huaifeng Li et al.   COORDINATION CHEMISTRY REVIEWS

Iron(ii) complexes featuring κ3- and κ2-bound PNP pincer ligands – the significance of sterics

(2015) Mathias Glatz et al.   DALTON TRANSACTIONS

Towards a Sustainable Synthesis of Formate Salts: Combined Catalytic Methanol Dehydrogenation and Bicarbonate Hydrogenation

(2014) Qiang Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Isolated Nitridyl Radical-Bridged {Rh(N.)Rh} Complex

(2014) Yann Gloaguen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Active Ligand-Induced Homolytic Bond Activation

(2014) Daniël L. J. Broere et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boryl-assisted hydrogenolysis of a nickel–methyl bond

(2014) Natalia Curado et al.   CHEMICAL COMMUNICATIONS

System with Potential Dual Modes of Metal-Ligand Cooperation: Highly Catalytically Active Pyridine-Based PNNH-Ru Pincer Complexes

(2014) Eran Fogler et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogen-Bond-Assisted Activation of Allylic Alcohols for Palladium-Catalyzed Coupling Reactions

(2014) Yasemin Gumrukcu et al.   ChemSusChem

Intramolecular Redox-Active Ligand-to-Substrate Single-Electron Transfer: Radical Reactivity with a Palladium(II) Complex

(2014) Daniël L. J. Broere et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of N–H Bond Cleavage of Aniline by a Dearomatized PNP-Pincer Type Phosphaalkene Complex of Iridium(I)

(2014) Yung-Hung Chang et al.   ORGANOMETALLICS

Efficient Hydrogenation of Ketones and Aldehydes Catalyzed by Well-Defined Iron(II) PNP Pincer Complexes: Evidence for an Insertion Mechanism

(2014) Nikolaus Gorgas et al.   ORGANOMETALLICS

Aluminium–ligand cooperation promotes selective dehydrogenation of formic acid to H2 and CO2

(2014) T. W. Myers et al.   Chemical Science

Lutidine-Derived Ru-CNC Hydrogenation Pincer Catalysts with Versatile Coordination Properties

(2014) Georgy A. Filonenko et al.   ACS Catalysis

A d10Ni-(H2) Adduct as an Intermediate in HH Oxidative Addition across a NiB Bond

(2013) W. Hill Harman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversible carbon–carbon bond formation between carbonyl compounds and a ruthenium pincer complex

(2013) Chelsea A. Huff et al.   CHEMICAL COMMUNICATIONS

Base-Free Production of H2by Dehydrogenation of Formic Acid Using An Iridium-bisMETAMORPhos Complex

(2013) Sander Oldenhof et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unexpected Electronic Process of H2 Activation by a New Nickel Borane Complex: Comparison with the Usual Homolytic and Heterolytic Activations

(2013) Guixiang Zeng et al.   INORGANIC CHEMISTRY

Room Temperature Rapid Functionalization of E–H Bonds (E = O, N, S) via the Metal–Ligand Cooperation Mechanism

(2013) Adam Scharf et al.   INORGANIC CHEMISTRY

Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand

(2013) Yann Gloaguen et al.   INORGANIC CHEMISTRY

Facile N–H Bond Cleavage of Ammonia by an Iridium Complex Bearing a Noninnocent PNP-Pincer Type Phosphaalkene Ligand

(2013) Yung-Hung Chang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Water, Ammonia, and Other Small Molecules by PCcarbeneP Nickel Pincer Complexes

(2013) Dmitry V. Gutsulyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Combinatorial Libraries: From Exploring Molecular Recognition to Systems Chemistry

(2013) Jianwei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aluminum–Ligand Cooperative N–H Bond Activation and an Example of Dehydrogenative Coupling

(2013) Thomas W. Myers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Nitriles by Metal Ligand Cooperation. Reversible Formation of Ketimido- and Enamido-Rhenium PNP Pincer Complexes and Relevance to Catalytic Design

(2013) Matthias Vogt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A homogeneous transition metal complex for clean hydrogen production from methanol–water mixtures

(2013) Rafael E. Rodríguez-Lugo et al.   Nature Chemistry

Catalytic transformation of alcohols to carboxylic acid salts and H2 using water as the oxygen atom source

(2013) Ekambaram Balaraman et al.   Nature Chemistry

Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts

(2013) Chi Wai Cheung et al.   ORGANIC LETTERS

Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane

(2013) Henry Fong et al.   ORGANOMETALLICS

Amine(imine)diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines

(2013) W. Zuo et al.   SCIENCE

Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis

(2013) C. Gunanathan et al.   SCIENCE

Facile Si–H bond activation and hydrosilylation catalysis mediated by a nickel–borane complex

(2013) Samantha N. MacMillan et al.   Chemical Science

The impact of Metal–Ligand Cooperation in Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium PNP Pincer

(2013) Georgy A. Filonenko et al.   ACS Catalysis

From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts

(2012) Denis Spasyuk et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Catalysis by Iridium Complexes with a Bipyridonate Ligand: Versatile Dehydrogenative Oxidation of Alcohols and Reversible Dehydrogenation-Hydrogenation between 2-Propanol and Acetone

(2012) Ryoko Kawahara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

6,6′-Dihydroxy terpyridine: a proton-responsive bifunctional ligand and its application in catalytic transfer hydrogenation of ketones

(2012) Cameron M. Moore et al.   CHEMICAL COMMUNICATIONS

Redox-active ligands in catalysis

(2012) Oana R. Luca et al.   CHEMICAL SOCIETY REVIEWS

N–H bond activation by palladium(ii) and copper(i) complexes featuring a reactive bidentate PN-ligand

(2012) Sandra Y. de Boer et al.   DALTON TRANSACTIONS

Aldehyde Binding through Reversible C–C Coupling with the Pincer Ligand upon Alcohol Dehydrogenation by a PNP–Ruthenium Catalyst

(2012) Michael Montag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Mechanism of Efficient Asymmetric Transfer Hydrogenation of Acetophenone Using an Iron(II) Complex Containing an (S,S)-Ph2PCH2CH═NCHPhCHPhN═CHCH2PPh2 Ligand: Partial Ligand Reduction Is the Key

(2012) Alexandre A. Mikhailine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible H2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis

(2012) W. Hill Harman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

MCl2(ampy)(dppf) (M = Ru, Os): Multitasking Catalysts for Carbonyl Compound/Alcohol Interconversion Reactions

(2012) Elisabetta Putignano et al.   ORGANOMETALLICS

PNS-Type Ruthenium Pincer Complexes

(2012) Moti Gargir et al.   ORGANOMETALLICS

Enhanced Reactivities toward Amines by Introducing an Imine Arm to the Pincer Ligand: Direct Coupling of Two Amines To Form an Imine Without Oxidant

(2012) Li-Peng He et al.   ORGANOMETALLICS

Spectroscopic and DFT Study of Ferraaziridine Complexes Formed in the Transfer Hydrogenation of Acetophenone Catalyzed Using trans-[Fe(CO)(NCMe)(PPh2C6H4CH═NCH2−)2-κ4P,N,N,P](BF4)2

(2012) Demyan E. Prokopchuk et al.   ORGANOMETALLICS

Role of a Noninnocent Pincer Ligand in the Activation of CO2 at (PNN)Ru(H)(CO)

(2012) Chelsea A. Huff et al.   ORGANOMETALLICS

Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

(2012) Volodymyr Lyaskovskyy et al.   ACS Catalysis

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Developing Synthetic Approaches with Non-Innocent Metalloligands: Easy Access to IrI/Pd0 and IrI/Pd0/IrI Cores

(2011) Cristina Tejel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Homogeneous catalysis using iron complexes: recent developments in selective reductions

(2011) Kathrin Junge et al.   CHEMICAL COMMUNICATIONS

Dinuclear Copper(I) Thiolate Complexes with a Bridging Noninnocent PNP Ligand

(2011) Jarl Ivar van der Vlugt et al.   CHEMISTRY-A EUROPEAN JOURNAL

β-Protic Pyrazole and N-Heterocyclic Carbene Complexes: Synthesis, Properties, and Metal-Ligand Cooperative Bifunctional Catalysis

(2011) Shigeki Kuwata et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cooperative Catalysis with First-Row Late Transition Metals

(2011) Jarl Ivar van der Vlugt   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative Double Deprotonation of Bis(2-picolyl)amine Leading to Unexpected Bimetallic Mixed Valence (M–I, MI) Rhodium and Iridium Complexes

(2011) Cristina Tejel et al.   INORGANIC CHEMISTRY

CuI click catalysis with cooperative noninnocent pyridylphosphine ligands

(2011) Sandra Y. de Boer et al.   INORGANICA CHIMICA ACTA

Synthesis of Amides from Esters and Amines with Liberation of H2under Neutral Conditions

(2011) Boopathy Gnanaprakasam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO

(2011) Ekambaram Balaraman et al.   Nature Chemistry

‘Carbene Radicals’ in CoII(por)-Catalyzed Olefin Cyclopropanation

(2010) Wojciech I. Dzik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multifunctional ligands in transition metal catalysis

(2010) Robert H. Crabtree   NEW JOURNAL OF CHEMISTRY

Simple and Versatile Catalytic System for N-Alkylation of Sulfonamides with Various Alcohols

(2010) Mingwen Zhu et al.   ORGANIC LETTERS

Structure validation in chemical crystallography

(2009) Anthony L. Spek   ACTA CRYSTALLOGRAPHICA SECTION D-BIOLOGICAL CRYSTALLOGRAPHY

Copper-Catalyzed Alkylation of Sulfonamides with Alcohols

(2009) Feng Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Neutral Tridentate PNP Ligands and Their Hybrid Analogues: Versatile Non-Innocent Scaffolds for Homogeneous Catalysis

(2009) Jarl Ivar van der Vlugt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen Autotransfer in theN-Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles

(2009) Gabriela Guillena et al.   CHEMICAL REVIEWS

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

(2009) Graham E. Dobereiner et al.   CHEMICAL REVIEWS

Asymmetric hydrogenation, transfer hydrogenation and hydrosilylation of ketones catalyzed by iron complexes

(2009) Robert H. Morris   CHEMICAL SOCIETY REVIEWS

CuIComplexes with a Noninnocent PNP Ligand: Selective Dearomatization and Electrophilic Addition Reactivity

(2009) Jarl Ivar van der Vlugt et al.   INORGANIC CHEMISTRY

Ruthenium-CatalyzedN-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

(2009) M. Haniti S. A. Hamid et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Consecutive Thermal H2and Light-Induced O2Evolution from Water Promoted by a Metal Complex

(2009) Stephan W. Kohl et al.   SCIENCE

N-Alkylation of poor nucleophilic amine and sulfonamide derivatives with alcohols by a hydrogen autotransfer process catalyzed by copper(II) acetate

(2009) Ana Martínez-Asencio et al.   TETRAHEDRON LETTERS

Modularly Designed Transition Metal PNP and PCP Pincer Complexes based on Aminophosphines: Synthesis and Catalytic Applications

(2008) David Benito-Garagorri et al.   ACCOUNTS OF CHEMICAL RESEARCH

METAMORPhos: Adaptive Supramolecular Ligands and Their Mechanistic Consequences for Asymmetric Hydrogenation

(2008) Frederic W. Patureau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Branched-Regioselective Hydroformylation with Catalytic Amounts of a Reversibly Bound Directing Group

(2008) Christian U. Grünanger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereospecific and Reversible CO Binding at Iron Pincer Complexes

(2008) David Benito-Garagorri et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperating Ligands in Catalysis

(2008) Hansjörg Grützmacher   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyzed Dehydrogenative Coupling of Primary Alcohols with Water, Methanol, or Amines

(2008) Theo Zweifel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Monoalkylation of primary amines and N-sulfinylamides

(2008) José Luis García Ruano et al.   CHEMICAL COMMUNICATIONS

Cationic and neutral NiIIcomplexes containing a non-innocent PNP ligand: formation of alkyl and thiolate species

(2008) Jarl Ivar van der Vlugt et al.   DALTON TRANSACTIONS

T-Shaped Cationic CuIComplexes with Hemilabile PNP-Type Ligands

(2008) Jarl Ivar van der Vlugt et al.   INORGANIC CHEMISTRY

Deprotonation Induced Ligand-to-Metal Electron Transfer: Synthesis of a Mixed-Valence Rh(−I,I) Dinuclear Compound and Its Reaction with Dioxygen

(2008) Cristina Tejel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY