Cooperative Aliphatic PNP Amido Pincer Ligands - Versatile Building Blocks for Coordination Chemistry and Catalysis

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition metal catalysed dehydrogenation of amine-borane fuel blends

(2011) Sib Sankar Mal et al.   CHEMICAL COMMUNICATIONS

Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes

(2011) Jongwook Choi et al.   CHEMICAL REVIEWS

PNP pincer osmium polyhydrides for catalytic dehydrogenation of primary alcohols

(2011) Marcello Bertoli et al.   DALTON TRANSACTIONS

Cooperative Double Deprotonation of Bis(2-picolyl)amine Leading to Unexpected Bimetallic Mixed Valence (M–I, MI) Rhodium and Iridium Complexes

(2011) Cristina Tejel et al.   INORGANIC CHEMISTRY

Manifestations of Noninnocent Ligand Behavior

(2011) Wolfgang Kaim   INORGANIC CHEMISTRY

Low-Valent Ene–Amido Iron Complexes for the Asymmetric Transfer Hydrogenation of Acetophenone without Base

(2011) Paraskevi O. Lagaditis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Secondary Coordination Sphere Interactions Facilitate the Insertion Step in an Iridium(III) CO2Reduction Catalyst

(2011) Timothy J. Schmeier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ammonia formation by metal–ligand cooperative hydrogenolysis of a nitrido ligand

(2011) Bjorn Askevold et al.   Nature Chemistry

Open-Shell Organometallic [MII(dbcot(bislutidylamine)]2+Complexes (M = Rh, Ir): Unexpected Base-Assisted Reduction of the Metal Instead of Amine Ligand Deprotonation

(2011) Wojciech I. Dzik et al.   ORGANOMETALLICS

Osmium and Ruthenium Catalysts for Dehydrogenation of Alcohols

(2011) Marcello Bertoli et al.   ORGANOMETALLICS

Synthesis, Structure, and Reactivity of an Iron(V) Nitride

(2011) J. J. Scepaniak et al.   SCIENCE

Amination of Aliphatic Alcohols and Diols with an Iridium Pincer Catalyst

(2010) Natalia Andrushko et al.   ChemCatChem

Amine− and Phosphine−Borane Adducts: New Interest in Old Molecules

(2010) Anne Staubitz et al.   CHEMICAL REVIEWS

Ammonia-Borane and Related Compounds as Dihydrogen Sources

(2010) Anne Staubitz et al.   CHEMICAL REVIEWS

Redox and Lewis Acid Reactivity of Unsaturated OsII

(2010) Nikolay Tsvetkov et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Iron Complexes for the Catalytic Transfer Hydrogenation of Acetophenone: Steric and Electronic Effects Imposed by Alkyl Substituents at Phosphorus

(2010) Paraskevi O. Lagaditis et al.   INORGANIC CHEMISTRY

Ruthenium Complexes with Cooperative PNP-Pincer Amine, Amido, Imine, and Enamido Ligands: Facile Ligand Backbone Functionalization Processes

(2010) Anja Friedrich et al.   INORGANIC CHEMISTRY

Synthesis and Molecular and Electronic Structures of Reduced Bis(imino)pyridine Cobalt Dinitrogen Complexes: Ligand versus Metal Reduction

(2010) Amanda C. Bowman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Dehydrocoupling/Dehydrogenation of N-Methylamine-Borane and Ammonia-Borane: Synthesis and Characterization of High Molecular Weight Polyaminoboranes

(2010) Anne Staubitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Perspectives on How Nature Employs the Principles of Organometallic Chemistry in Dihydrogen Activation in Hydrogenases†

(2010) John C. Gordon et al.   ORGANOMETALLICS

Synthesis and Reactivity of an Iridium(I) Acetonyl PNP Complex. Experimental and Computational Study of Metal−Ligand Cooperation in H−H and C−H Bond Activation via Reversible Ligand Dearomatization

(2010) Leonid Schwartsburd et al.   ORGANOMETALLICS

Radical Ligands Confer Nobility on Base-Metal Catalysts

(2010) P. J. Chirik et al.   SCIENCE

The Give and Take of Alcohol Activation

(2010) A. J. A. Watson et al.   SCIENCE

Discovery of Environmentally Benign Catalytic Reactions of Alcohols Catalyzed by Pyridine-Based Pincer Ru Complexes, Based on Metal–Ligand Cooperation

(2010) David Milstein   TOPICS IN CATALYSIS

Acceptorless Dehydrogenation of Alcohols: Perspectives for Synthesis and H2Storage.

(2009) Anja Friedrich et al.   ChemCatChem

Surprising isomer preference on IrIII, favoring facile H–C(sp3) bond cleavage

(2009) Nikolai P. Tsvetkov et al.   CHEMICAL COMMUNICATIONS

Hydrogen Autotransfer in theN-Alkylation of Amines and Related Compounds using Alcohols and Amines as Electrophiles

(2009) Gabriela Guillena et al.   CHEMICAL REVIEWS

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

(2009) Graham E. Dobereiner et al.   CHEMICAL REVIEWS

Ruthenium-Catalyzed Dimethylamineborane Dehydrogenation: Stepwise Metal-Centered Dehydrocyclization

(2009) Anja Friedrich et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ligand-Centred Reactivity of Bis(picolyl)amine Iridium: Sequential Deprotonation, Oxidation and Oxygenation of a “Non-Innocent” Ligand

(2009) Cristina Tejel et al.   CHEMISTRY-A EUROPEAN JOURNAL

TERMINAL NITRIDO AND IMIDO COMPLEXES OF THE LATE TRANSITION METALS

(2009) John F. Berry   COMMENTS ON INORGANIC CHEMISTRY

Highly active iridium catalysts for the hydrogenation of ketones and aldehydes

(2009) Xuanhua Chen et al.   DALTON TRANSACTIONS

Metal–ligand cooperation in the trans addition of dihydrogen to a pincer Ir(i) complex: a DFT study

(2009) Mark A. Iron et al.   DALTON TRANSACTIONS

Ammonia Borane as a Hydrogen Carrier: Dehydrogenation and Regeneration

(2009) Nathan C. Smythe et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Palladium N(CH2CH2PiPr2)2-Dialkylamides: Synthesis, Structural Characterization, and Reactivity

(2009) Alexander N. Marziale et al.   INORGANIC CHEMISTRY

Highly Stereoselective Proton/Hydride Exchange: Assistance of Hydrogen Bonding for the Heterolytic Splitting of H2

(2009) Anja Friedrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Three-Coordinate Copper(I) Amido and Aminyl Radical Complexes

(2009) Neal P. Mankad et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Double C−H Activation of Tetrahydrofuran by an Iridium PNP Pincer Complex

(2009) Jenni Meiners et al.   ORGANOMETALLICS

Iridium Olefin Complexes Bearing Dialkylamino/amido PNP Pincer Ligands: Synthesis, Reactivity, and Solution Dynamics†

(2009) Anja Friedrich et al.   ORGANOMETALLICS

Decomposition of Methylnickel(II) Amido, Alkoxo, and Alkyl Complexes by β-Hydrogen Elimination: A Comparative Study†

(2009) Inmaculada Matas et al.   ORGANOMETALLICS

Six-, Five-, and Four-Coordinate Ruthenium(II) Hydride Complexes Supported byN-Heterocyclic Carbene Ligands: Synthesis, Characterization, Fundamental Reactivity, and Catalytic Hydrogenation of Olefins, Aldehydes, and Ketones

(2009) John P. Lee et al.   ORGANOMETALLICS

B–N compounds for chemical hydrogenstorage

(2008) Charles W. Hamilton et al.   CHEMICAL SOCIETY REVIEWS

Ligand Oxidation of a Deprotonated Bis(picolyl)amine IrI(cod) Complex

(2008) Cristina Tejel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cycloheptatrienyl, alkyl and aryl PCP-pincer complexes: Ligand backbone effects and metal reactivity

(2008) W LEIS et al.   COORDINATION CHEMISTRY REVIEWS

Transition metal catalysed reactions of alcohols using borrowing hydrogen methodology

(2008) Tracy D. Nixon et al.   DALTON TRANSACTIONS

Rhodium and Iridium Amino, Amido, and Aminyl Radical Complexes

(2008) Nicola Donati et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Unexpected selectivity in electrophilic attack on (PNP)RuN

(2008) Amy Walstrom et al.   INORGANICA CHIMICA ACTA

Oxygen-Atom Transfer from Carbon Dioxide to a Fischer Carbene at (PNP)Ir

(2008) Matthew T. Whited et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Dehydrogenation of Ammonia Boranes

(2008) Nicole Blaquiere et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural and Spectroscopic Characterization of an Electrophilic Iron Nitrido Complex

(2008) Jeremiah J. Scepaniak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural, Spectroscopic, and Theoretical Elucidation of a Redox-Active Pincer-Type Ancillary Applied in Catalysis

(2008) Debashis Adhikari et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbon–heteroatom bond formation catalysed by organometallic complexes

(2008) John F. Hartwig   NATURE

Biologically inspired oxidation catalysis

(2008) Lawrence Que et al.   NATURE

Prototropic rearrangements in cycloheptatrienyl PCP pincer iridium complexes

(2007) Angelika M. Winter et al.   DALTON TRANSACTIONS

Theoretical investigation on the mechanisms of transfer hydrogenation of ketones catalyzed by iridium complexes

(2007) Siwei Bi et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY