Facile Synthesis and Versatile Reactivity of an Unusual Cyclometalated Rhodium(I) Pincer Complex

The Missing Entry in the Agostic–Anagostic Series: Rh(I)–η1-C Interactions in P(CH)P Pincer Complexes

(2015) Christine Lepetit et al.   INORGANIC CHEMISTRY

Dehydrogenation of formic acid by Ir–bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand

(2015) Sander Oldenhof et al.   Chemical Science

An Isolated Nitridyl Radical-Bridged {Rh(N.)Rh} Complex

(2014) Yann Gloaguen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Active Ligand-Induced Homolytic Bond Activation

(2014) Daniël L. J. Broere et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly selective directed arylation reactions via back-to-back dehydrogenative C–H borylation/arylation reactions

(2014) Eric C. Keske et al.   CHEMICAL COMMUNICATIONS

Methandiide as a Non-Innocent Ligand in Carbene Complexes: From the Electronic Structure to Bond Activation Reactions and Cooperative Catalysis

(2014) Julia Becker et al.   CHEMISTRY-A EUROPEAN JOURNAL

System with Potential Dual Modes of Metal-Ligand Cooperation: Highly Catalytically Active Pyridine-Based PNNH-Ru Pincer Complexes

(2014) Eran Fogler et al.   CHEMISTRY-A EUROPEAN JOURNAL

Intramolecular Redox-Active Ligand-to-Substrate Single-Electron Transfer: Radical Reactivity with a Palladium(II) Complex

(2014) Daniël L. J. Broere et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Theoretical Study on Iridacycle and Rhodacycle Formation via C–H Activation of Phenyl Imines

(2014) Jing Li et al.   ORGANOMETALLICS

Well-Defined BisMETAMORPhos PdI–PdI Complex: Synthesis, Structural Characterization, and Reactivity

(2014) Sander Oldenhof et al.   ORGANOMETALLICS

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Bio-Inspired Catalytic Imine Reduction by Rhodium Complexes with Tethered Hantzsch Pyridinium Groups: Evidence for Direct Hydride Transfer from Dihydropyridine to Metal-Activated Substrate

(2013) Alex McSkimming et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversible Dihydrogen Activation in Cationic Rare-Earth-Metal Polyhydride Complexes

(2013) Waldemar Fegler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The NH Functional Group in Organometallic Catalysis

(2013) Baoguo Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

(2013) Guy Rouquet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Free Production of H2by Dehydrogenation of Formic Acid Using An Iridium-bisMETAMORPhos Complex

(2013) Sander Oldenhof et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stepwise Metal-Ligand Cooperation by a Reversible Aromatization/Deconjugation Sequence in Ruthenium Complexes with a Tetradentate Phenanthroline-Based Ligand

(2013) Robert Langer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ligand-Metal Cooperating PC(sp3)P Pincer Complexes as Catalysts in Olefin Hydroformylation

(2013) Sanaa Musa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis, Coordination Chemistry, and Cooperative Activation of H2with Ruthenium Complexes of Proton-Responsive METAMORPhos Ligands

(2013) Frédéric G. Terrade et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

C-H Activation at a Ruthenium(II) Complex - The Key Step for a Base-Free Catalytic Transfer Hydrogenation?

(2013) Leila Taghizadeh Ghoochany et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand

(2013) Yann Gloaguen et al.   INORGANIC CHEMISTRY

Facile N–H Bond Cleavage of Ammonia by an Iridium Complex Bearing a Noninnocent PNP-Pincer Type Phosphaalkene Ligand

(2013) Yung-Hung Chang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Study of the Oxidative Coupling of Styrene with 2-Phenylpyridine Derivatives Catalyzed by Cationic Rhodium(III) via C–H Activation

(2013) Mikaël Brasse et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hemilabile N-Xylyl-N′-methylperimidine Carbene Iridium Complexes as Catalysts for C–H Activation and Dehydrogenative Silylation: Dual Role of N-Xylyl Moiety for ortho-C–H Bond Activation and Reductive Bond Cleavage

(2013) Gyeongshin Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Efficient Rh/O2 Catalytic System for Oxidative C–H Activation/Annulation: Evidence for Rh(I) to Rh(III) Oxidation by Molecular Oxygen

(2013) Guoying Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Water, Ammonia, and Other Small Molecules by PCcarbeneP Nickel Pincer Complexes

(2013) Dmitry V. Gutsulyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aluminum–Ligand Cooperative N–H Bond Activation and an Example of Dehydrogenative Coupling

(2013) Thomas W. Myers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxy-substituted pyridine-like N-heterocycles: versatile ligands in organometallic catalysis

(2013) Wan-Hui Wang et al.   NEW JOURNAL OF CHEMISTRY

Reductive Elimination at an Ortho-Metalated Iridium(III) Hydride Bearing a Tripodal Tetraphosphorus Ligand

(2013) Yann Gloaguen et al.   ORGANOMETALLICS

Mesoionic Complexes of Platinum(II) Derived from “Rollover” Cyclometalation: A Delicate Balance between Pt–C(sp3) and Pt–C(sp2) Bond Cleavage as a Result of Different Reaction Conditions

(2013) Luca Maidich et al.   ORGANOMETALLICS

Amine(imine)diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines

(2013) W. Zuo et al.   SCIENCE

Metal or Nonmetal Cooperation with a Phenyl Group: Route to Catalysis? A Computational Investigation

(2013) Kamalika Ghatak et al.   ACS Catalysis

From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts

(2012) Denis Spasyuk et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Catalysis by Iridium Complexes with a Bipyridonate Ligand: Versatile Dehydrogenative Oxidation of Alcohols and Reversible Dehydrogenation-Hydrogenation between 2-Propanol and Acetone

(2012) Ryoko Kawahara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

6,6′-Dihydroxy terpyridine: a proton-responsive bifunctional ligand and its application in catalytic transfer hydrogenation of ketones

(2012) Cameron M. Moore et al.   CHEMICAL COMMUNICATIONS

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

N–H bond activation by palladium(ii) and copper(i) complexes featuring a reactive bidentate PN-ligand

(2012) Sandra Y. de Boer et al.   DALTON TRANSACTIONS

Rollover Cyclometalation Pathway in Rhodium Catalysis: Dramatic NHC Effects in the C–H Bond Functionalization

(2012) Jaesung Kwak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible H2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis

(2012) W. Hill Harman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Electrochemistry, and Reactivity of New Iridium(III) and Rhodium(III) Hydrides

(2012) Yue Hu et al.   ORGANOMETALLICS

N–H Activation by Rh(I) via Metal–Ligand Cooperation

(2012) Moran Feller et al.   ORGANOMETALLICS

Selective Au–C Cleavage in (C∧N∧C)Au(III) Aryl and Alkyl Pincer Complexes

(2012) Dan A. Smith et al.   ORGANOMETALLICS

Coordination Versatility of sp3-Hybridized Pincer Ligands toward Ligand–Metal Cooperative Catalysis

(2012) Dmitri Gelman et al.   ACS Catalysis

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Developing Synthetic Approaches with Non-Innocent Metalloligands: Easy Access to IrI/Pd0 and IrI/Pd0/IrI Cores

(2011) Cristina Tejel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Dinuclear Copper(I) Thiolate Complexes with a Bridging Noninnocent PNP Ligand

(2011) Jarl Ivar van der Vlugt et al.   CHEMISTRY-A EUROPEAN JOURNAL

β-Protic Pyrazole and N-Heterocyclic Carbene Complexes: Synthesis, Properties, and Metal-Ligand Cooperative Bifunctional Catalysis

(2011) Shigeki Kuwata et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Ligand Cooperation in the Catalytic Dehydrogenative Coupling (DHC) of Polyalcohols to Carboxylic Acid Derivatives

(2011) Mónica Trincado et al.   CHEMISTRY-A EUROPEAN JOURNAL

New possible mode of ligand–metal cooperation in PC(sp3)P pincer complexes

(2011) Sanaa Musa et al.   DALTON TRANSACTIONS

Pincer ligands with an all-phosphorus donor set: subtle differences between rhodium and palladium

(2011) Richard C. Bauer et al.   DALTON TRANSACTIONS

Cooperative Aliphatic PNP Amido Pincer Ligands - Versatile Building Blocks for Coordination Chemistry and Catalysis

(2011) Sven Schneider et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative Catalysis with First-Row Late Transition Metals

(2011) Jarl Ivar van der Vlugt   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative Double Deprotonation of Bis(2-picolyl)amine Leading to Unexpected Bimetallic Mixed Valence (M–I, MI) Rhodium and Iridium Complexes

(2011) Cristina Tejel et al.   INORGANIC CHEMISTRY

CuI click catalysis with cooperative noninnocent pyridylphosphine ligands

(2011) Sandra Y. de Boer et al.   INORGANICA CHIMICA ACTA

A Dearomatized Anionic PNP Pincer Rhodium Complex: C–H and H–H Bond Activation by Metal–Ligand Cooperation and Inhibition by Dinitrogen

(2011) Leonid Schwartsburd et al.   ORGANOMETALLICS

Tunable Hemilabile Ligands for Adaptive Transition Metal Complexes

(2011) Ronald Lindner et al.   ORGANOMETALLICS

“Rollover” cyclometalation – early history, recent developments, mechanistic insights and application aspects

(2011) Burkhard Butschke et al.   Chemical Science

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Ir-Catalysed Asymmetric Allylic Substitutions with Cyclometalated (Phosphoramidite)Ir Complexes-Resting States, Catalytically Active (π-Allyl)Ir Complexes and Computational Exploration

(2010) Jevgenij A. Raskatov et al.   CHEMISTRY-A EUROPEAN JOURNAL

The dehydrogenation of ammonia–borane catalysed by dicarbonylruthenacyclic(ii) complexes

(2010) Cédric Boulho et al.   DALTON TRANSACTIONS

A General and Highly Efficient Method for the Construction of Aryl-Substituted N-Heteroarenes

(2010) Chun Liu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of the tris-cyclometalated complex fac-[Rh(ptpy)3] and X-ray crystal structure of [Rh(acac)(ptpy)2]

(2010) Hans-Christian Böttcher et al.   INORGANIC CHEMISTRY COMMUNICATIONS

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Agostic bonds in cyclometalation

(2010) Iwao Omae   JOURNAL OF ORGANOMETALLIC CHEMISTRY

“Long-Range” Metal−Ligand Cooperation in H2Activation and Ammonia-Promoted Hydride Transfer with a Ruthenium−Acridine Pincer Complex

(2010) Chidambaram Gunanathan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structure validation in chemical crystallography

(2009) Anthony L. Spek   ACTA CRYSTALLOGRAPHICA SECTION D-BIOLOGICAL CRYSTALLOGRAPHY

Neutral Tridentate PNP Ligands and Their Hybrid Analogues: Versatile Non-Innocent Scaffolds for Homogeneous Catalysis

(2009) Jarl Ivar van der Vlugt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends

(2009) Martin Albrecht   CHEMICAL REVIEWS

Computational and synthetic studies on the cyclometallation reaction of dimethylbenzylamine with [IrCl2Cp*]2: role of the chelating base

(2009) Youcef Boutadla et al.   DALTON TRANSACTIONS

Metalloligands: Rhodium(III) Cyclometallated Compounds Containing Multitopological Binucleating Ligands

(2009) Santo Lanza et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

EVAL15: a diffraction data integration method based onab initiopredicted profiles

(2009) Antoine M. M. Schreurs et al.   JOURNAL OF APPLIED CRYSTALLOGRAPHY

N^N^C platinum(II) and palladium(II) cyclometallates of 6,6′-diphenyl-2,2′-bipyridine, L: Crystal and molecular structure of [Pd(L–H)Cl]

(2009) Antonio Zucca et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Rhodium(0) Metalloradicals in Binuclear C−H Activation

(2009) Florian F. Puschmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Characterization of agostic interactions in theory and computation

(2008) Matthias Lein   COORDINATION CHEMISTRY REVIEWS

Selective decarbonylation by a pincer PCP-rhodium(I) complex

(2008) Kuo-Wei Huang et al.   INORGANICA CHIMICA ACTA

C−H Bond Activation by Rhodium(I) Phenoxide and Acetate Complexes: Mechanism of H−D Exchange between Arenes and Water

(2008) Susan Kloek Hanson et al.   ORGANOMETALLICS

Structure and Reactivity of Rhodium(I) Complexes Based on Electron-Withdrawing Pyrrolyl-PCP-Pincer Ligands

(2008) Elizaveta Kossoy et al.   ORGANOMETALLICS

Mechanistic Study of Acetate-Assisted C−H Activation of 2-Substituted Pyridines with [MCl2Cp*]2(M = Rh, Ir) and [RuCl2(p-cymene)]2

(2008) Youcef Boutadla et al.   ORGANOMETALLICS