Practical Synthesis of Chiral Allylboronates by Asymmetric 1,1‐Difunctionalization of Terminal Alkenes

Modular and Facile Access to Chiral α-Aryl Phosphates via Dual Nickel- and Photoredox-Catalyzed Reductive Cross-Coupling

(2022) Hepan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition‐Metal‐Catalyzed Synthesis of Chiral Allylboronates

(2021) Wenbo Ming et al.   CHINESE JOURNAL OF CHEMISTRY

Backbone-Modified C2-Symmetrical Chiral Bisphosphine TMS-QuinoxP*: Asymmetric Borylation of Racemic Allyl Electrophiles

(2021) Hiroaki Iwamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition Metal (Ni, Cu, Pd)-Catalyzed Alkene Dicarbofunctionalization Reactions

(2021) Laura M. Wickham et al.   ACCOUNTS OF CHEMICAL RESEARCH

Regio- and Stereoselective Synthesis of Multi-Alkylated Allylic Boronates through Three-Component Coupling Reactions between Allenes, Alkyl Halides, and a Diboron Reagent

(2021) Yu Ozawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni/Photoredox-Catalyzed Enantioselective Cross-Electrophile Coupling of Styrene Oxides with Aryl Iodides

(2021) Sii Hong Lau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and Stereoselective Alkylboration of Endocyclic Olefins Enabled by Nickel Catalysis

(2021) Chao Ding et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Chiral N-Heterocyclic Allylboronates via the Enantioselective Borylative Dearomatization of Pyrroles

(2020) Keiichi Hayama et al.   ORGANIC LETTERS

Recent Advances in Nickel-Catalyzed Three-Component Difunctionalization of Unactivated Alkenes

(2020) Hai-Yong Tu et al.   SYNTHESIS-STUTTGART

On the Nature of C(sp3)–C(sp2) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides

(2020) Mingbin Yuan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Role of Electron-Deficient Olefin Ligands in a Ni-Catalyzed Aziridine Cross-Coupling To Generate Quaternary Carbons

(2020) Jesús G. Estrada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Chemodivergent 1,1-Difunctionalization of Unactivated α-Olefins with Alkynyl Electrophiles and B2pin2

(2020) Yangyang Li et al.   ACS Catalysis

Nickel‐Catalyzed Dicarbofunctionalization of Alkenes †

(2020) Yun‐Cheng Luo et al.   CHINESE JOURNAL OF CHEMISTRY

Nickel-Catalyzed Dicarbofunctionalization of Alkenes

(2020) Xiaoxu Qi et al.   ACS Catalysis

Regio‐ and Enantioselective Ni‐Catalyzed Formal Hydroalkylation, Hydrobenzylation and Hydropropargylation of Acrylamides to α‐Tertiary Amides

(2020) Wei Shu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in nickel-catalyzed reductive hydroalkylation and hydroarylation of electronically unbiased alkenes

(2020) Xiao-Xu Wang et al.   Science China-Chemistry

Catalyst-controlled enantioselective 1,1-arylboration of unactivated olefins

(2020) Wang Wang et al.   Nature Catalysis

Organocatalytic Synthesis of α-Trifluoromethyl Allylboronic Acids by Enantioselective 1,2-Borotropic Migration

(2020) Sybrand J. T. Jonker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

General Method for Enantioselective Three-Component Carboarylation of Alkenes Enabled by Visible-Light Dual Photoredox/Nickel Catalysis

(2020) Lei Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioconvergent Synthesis of Tertiary Cyclic Allylboronates Using (Guanidine)copper Complex-Catalyzed Allylic Borylation

(2019) Choon Hong Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Migratory Arylboration of Unactivated Alkenes Enabled by Nickel Catalysis

(2019) Wang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed 1,1-Alkylboration of Electronically Unbiased Terminal Alkenes

(2019) Yangyang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Synthesis of Allylic Boronates Bearing a Trisubstituted Alkenyl Fluoride and Related Derivatives

(2019) Sota Akiyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Investigation of Enantioconvergent Kumada Reactions of Racemic α-Bromoketones Catalyzed by a Nickel/Bis(oxazoline) Complex

(2019) Haolin Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

α-Branched amines by catalytic 1,1-addition of C–H bonds and aminating agents to terminal alkenes

(2019) Soham Maity et al.   Nature Catalysis

Photochemical Asymmetric Nickel-Catalyzed Acyl Cross-Coupling

(2019) Eugenio Gandolfo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Difunctionalization of Alkenes Involving Metal Migration

(2019) Yuqiang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Copper(I)-Catalyzed Enantioselective γ-Boryl Substitution of Trifluoromethyl-Substituted Alkenes: Synthesis of Enantioenriched γ,γ-gem -Difluoroallylboronates

(2018) Ryoto Kojima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Defluoroborylation of 1-(Trifluoromethyl)Alkenes

(2018) Pan Gao et al.   Chem

Catalyst-Controlled 1,2- and 1,1-Arylboration of α-Alkyl Alkenyl Arenes

(2018) Allison M. Bergmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper(I)-Catalyzed Enantioselective 1,6-Borylation of α,β,γ,δ-Unsaturated Phosphonates

(2018) Hyesu Lee et al.   ORGANIC LETTERS

Enantioselective Conjunctive Cross-Coupling of Bis(alkenyl)borates: A General Synthesis of Chiral Allylboron Reagents

(2017) Emma K. Edelstein et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formal nucleophilic borylation and borylative cyclization of organic halides

(2017) K. Kubota et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective palladium-catalyzed diboration of 1,1-disubstituted allenes

(2017) Jiawang Liu et al.   Chemical Science

Enantioselective Palladium-Catalyzed Oxidative β,β-Fluoroarylation of α,β-Unsaturated Carbonyl Derivatives

(2016) Javier Miró et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Accessing Both Retention and Inversion Pathways in Stereospecific, Nickel-Catalyzed Miyaura Borylations of Allylic Pivalates

(2016) Qi Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in the Preparation and Application of Allylboron Species in Organic Synthesis

(2016) Colin Diner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development and Analysis of a Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Acrylates Enabled by Chiral Anion Phase Transfer

(2016) Eiji Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Optimization and multigram scalability of a catalytic enantioselective borylative migration for the synthesis of functionalized chiral piperidines

(2016) You-Ri Kim et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Modular, Catalytic Enantioselective Construction of Quaternary Carbon Stereocenters by Sequential Cross-Coupling Reactions

(2016) Bowman Potter et al.   ORGANIC LETTERS

Copper-Catalyzed Asymmetric Borylative Ring Opening of Diazabicycles

(2016) Hyesu Lee et al.   ACS Catalysis

Palladium-Catalyzed Enantioselective 1,1-Fluoroarylation of Aminoalkenes

(2015) Ying He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron-Deficient Olefin Ligands Enable Generation of Quaternary Carbons by Ni-Catalyzed Cross-Coupling

(2015) Chung-Yang (Dennis) Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective 1,1-Arylborylation of Alkenes: Merging Chiral Anion Phase Transfer with Pd Catalysis

(2015) Hosea M. Nelson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Allylboronates and Allylic Alcohols by Copper-Catalyzed 1,6-Boration

(2014) Yunfei Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of (+)-Discodermolide by Catalytic Stereoselective Borylation Reactions

(2014) Zhiyong Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Diastereoselective and Enantiospecific Allylation of Ketones and Imines Using Borinic Esters: Contiguous Quaternary Stereogenic Centers

(2014) Jack L.-Y. Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nonracemic Allylic Boronates through Enantiotopic-Group-Selective Cross-Coupling of Geminal Bis(boronates) and Vinyl Halides

(2014) Bowman Potter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Enantioselective Synthesis of α-Chiral Linear or Carbocyclic (E)-(γ-Alkoxyallyl)boronates

(2014) Eiji Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concise Synthesis and Antimalarial Activity of All Four Mefloquine Stereoisomers Using a Highly Enantioselective Catalytic Borylative Alkene Isomerization

(2013) Jinyue Ding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterogeneous and homogeneous chiral Cu(ii) catalysis in water: enantioselective boron conjugate additions to dienones and dienoesters

(2013) Taku Kitanosono et al.   CHEMICAL COMMUNICATIONS

Selection of boron reagents for Suzuki–Miyaura coupling

(2013) Alastair J. J. Lennox et al.   CHEMICAL SOCIETY REVIEWS

A Catalytic Enantioselective Tandem Allylation Strategy for Rapid Terpene Construction: Application to the Synthesis of Pumilaside Aglycon

(2013) Grace E. Ferris et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Allylboration of vic-Tricarbonyl Compounds: Total Synthesis of (+)-Awajanomycin

(2011) Malte Wohlfahrt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Boron-Based Synthesis of the Natural Product (+)-trans-Dihydrolycoricidine

(2011) Sarah L. Poe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modular Monodentate Oxaphospholane Ligands: Utility in Highly Efficient and Enantioselective 1,4-Diboration of 1,3-Dienes

(2011) Christopher H. Schuster et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective 1,2-Diboration of 1,3-Dienes: Versatile Reagents for Stereoselective Allylation

(2011) Laura T. Kliman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoconvergent Synthesis of Chiral Allylboronates from anE/ZMixture of Allylic Aryl Ethers Using a 6-NHC−Cu(I) Catalyst

(2011) Jin Kyoon Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

(2011) Jack Chang Hung Lee et al.   Nature Chemistry

Total Synthesis of (±)- and (−)-Actinophyllic Acid

(2010) Connor L. Martin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Asymmetric Monoborylation of 1,3-Dienes: Synthesis of Enantioenriched Cyclic Homoallyl- and Allylboronates

(2010) Yusuke Sasaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Application of the Lithiation−Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry

(2010) Martin Althaus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution Reactions

(2010) Aikomari Guzman-Martinez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct enantio-convergent transformation of racemic substrates without racemization or symmetrization

(2010) Hajime Ito et al.   Nature Chemistry

Asymmetric 1,4-Dihydroxylation of 1,3-Dienes by Catalytic Enantioselective Diboration

(2009) Heather E. Burks et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Palmerolide A via Organoboron Methodology

(2009) Marlin Penner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

α-Hydroxyalkyl Heterocycles via Chiral Allylic Boronates: Pd-Catalyzed Borylation Leading to a Formal Enantioselective Isomerization of Allylic Ether and Amine

(2009) Stéphanie Lessard et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY