Backbone-Modified C2-Symmetrical Chiral Bisphosphine TMS-QuinoxP*: Asymmetric Borylation of Racemic Allyl Electrophiles

Enantioconvergent Synthesis of Tertiary Cyclic Allylboronates Using (Guanidine)copper Complex-Catalyzed Allylic Borylation

(2019) Choon Hong Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Computational Ligand Descriptors for Catalyst Design

(2019) Derek J. Durand et al.   CHEMICAL REVIEWS

Ni-Catalyzed Asymmetric Hydrogenation of N-Sulfonyl Imines

(2019) Bowen Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper(I)-Catalyzed Enantioconvergent Borylation of Racemic Benzyl Chlorides Enabled by Quadrant-by-Quadrant Structure Modification of Chiral Bisphosphine Ligands

(2019) Hiroaki Iwamoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thorpe-Ingold Effect in Branch-Selective Alkylation of Unactivated Aryl Fluorides

(2018) Matthew J. O'Neill et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Computational design of high-performance ligand for enantioselective Markovnikov hydroboration of aliphatic terminal alkenes

(2018) Hiroaki Iwamoto et al.   Nature Communications

Pd(OAc)2-catalyzed asymmetric hydrogenation of sterically hindered N-tosylimines

(2018) Jianzhong Chen et al.   Nature Communications

Mechanistic Studies on a Cu-Catalyzed Asymmetric Allylic Alkylation with Cyclic Racemic Starting Materials

(2017) Emeline Rideau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand–Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins

(2017) Gang Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Asymmetric Hydroboration/Cyclization of 1,6-Enynes with Pinacolborane

(2017) Songjie Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Well-Defined Chiral Gold(III) Complex Catalyzed Direct Enantioconvergent Kinetic Resolution of 1,5-Enynes

(2017) Patrick T. Bohan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Elusive Phosphine Copper(I) Boryl Complexes: Synthesis, Structures, and Reactivity

(2017) Corinna Borner et al.   ORGANOMETALLICS

Enantioselective palladium-catalyzed diboration of 1,1-disubstituted allenes

(2017) Jiawang Liu et al.   Chemical Science

Enantioconvergent catalysis

(2016) Justin T Mohr et al.   Beilstein Journal of Organic Chemistry

Searching for Practically Useful P-Chirogenic Phosphine Ligands

(2016) Tsuneo Imamoto   CHEMICAL RECORD

Applications and stereoselective syntheses of P-chirogenic phosphorus compounds

(2016) Mathieu Dutartre et al.   CHEMICAL SOCIETY REVIEWS

Recent Advances in the Preparation and Application of Allylboron Species in Organic Synthesis

(2016) Colin Diner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Temperature-Controlled Bidirectional Enantioselectivity in a Dynamic Catalyst for Asymmetric Hydrogenation

(2015) Golo Storch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

London Dispersion in Molecular Chemistry-Reconsidering Steric Effects

(2015) J. Philipp Wagner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Hemiaminals via Pd-Catalyzed C–N Coupling with Chiral Bisphosphine Mono-oxides

(2015) Hongming Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Temperature-Dependent Direct Enantioconvergent Silylation of a Racemic Cyclic Allylic Phosphate by Copper(I)-Catalyzed Allylic Substitution

(2015) Martin Oestreich et al.   SYNTHESIS-STUTTGART

Functionalization of Quinoxalines by Using TMP Bases: Preparation of Tetracyclic Heterocycles with High Photoluminescene Quantum Yields

(2014) Julia Nafe et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper(I)-Catalyzed Enantioselective Synthesis of α-Chiral Linear or Carbocyclic (E)-(γ-Alkoxyallyl)boronates

(2014) Eiji Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt Precursors for High-Throughput Discovery of Base Metal Asymmetric Alkene Hydrogenation Catalysts

(2013) M. R. Friedfeld et al.   SCIENCE

Three-Hindered Quadrant Phosphine Ligands with an Aromatic Ring Backbone for the Rhodium-Catalyzed Asymmetric Hydrogenation of Functionalized Alkenes

(2012) Zhenfeng Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Identification of a Valuable Kinetic Process in Copper-Catalyzed Asymmetric Allylic Alkylation

(2011) Jean-Baptiste Langlois et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoconvergent Synthesis of Chiral Allylboronates from anE/ZMixture of Allylic Aryl Ethers Using a 6-NHC−Cu(I) Catalyst

(2011) Jin Kyoon Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rigid P-Chiral Phosphine Ligands with tert-Butylmethylphosphino Groups for Rhodium-Catalyzed Asymmetric Hydrogenation of Functionalized Alkenes

(2011) Tsuneo Imamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic identification and improvement of a direct enantioconvergent transformation in copper-catalyzed asymmetric allylic alkylation

(2011) Jean-Baptiste Langlois et al.   Chemical Science

Enantioselective Nitroso Aldol Reaction Catalyzed by QuinoxP*·Silver(I) Complex and Tin Methoxide

(2010) Akira Yanagisawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution Reactions

(2010) Aikomari Guzman-Martinez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct enantio-convergent transformation of racemic substrates without racemization or symmetrization

(2010) Hajime Ito et al.   Nature Chemistry

Rhodium-Catalyzed Highly Enantioselective Direct Intermolecular Hydroacylation of 1,1-Disubstituted Alkenes with Unfunctionalized Aldehydes

(2009) Yu Shibata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

α-Hydroxyalkyl Heterocycles via Chiral Allylic Boronates: Pd-Catalyzed Borylation Leading to a Formal Enantioselective Isomerization of Allylic Ether and Amine

(2009) Stéphanie Lessard et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Optically Active Boron-Silicon Bifunctional Cyclopropane Derivatives through Enantioselective Copper(I)-Catalyzed Reaction of Allylic Carbonates with a Diboron Derivative

(2008) Hajime Ito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION