Highly Diastereoselective and Enantiospecific Allylation of Ketones and Imines Using Borinic Esters: Contiguous Quaternary Stereogenic Centers

All-Carbon Quaternary Stereogenic Centers in Acyclic Systems through the Creation of Several C–C Bonds per Chemical Step

(2014) Ilan Marek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective allylboration of imines and indoles under mild conditions. An in situ E/Z isomerization of imines by allylboroxines

(2014) Rauful Alam et al.   Chemical Science

Axial Preferences in Allylation Reactions via the Zimmerman–Traxler Transition State

(2013) Tom Mejuch et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cu-Catalyzed Chemoselective Preparation of 2-(Pinacolato)boron-Substituted Allylcopper Complexes and their In Situ Site-, Diastereo-, and Enantioselective Additions to Aldehydes and Ketones

(2013) Fanke Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereoselective Allylation of Carbonyl Compounds and Imines: Application to the Synthesis of Natural Products

(2013) Miguel Yus et al.   CHEMICAL REVIEWS

The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis

(2013) Allen Y. Hong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A Catalytic Enantioselective Tandem Allylation Strategy for Rapid Terpene Construction: Application to the Synthesis of Pumilaside Aglycon

(2013) Grace E. Ferris et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Diastereo- and Enantioselective Allylboration of Aldehydes using α-Substituted Allyl/Crotyl Pinacol Boronic Esters via in Situ Generated Borinic Esters

(2013) Jack L.-Y. Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple organic molecules as catalysts for enantioselective synthesis of amines and alcohols

(2013) Daniel L. Silverio et al.   NATURE

Selective Formation of Adjacent Stereocenters by Allylboration of Ketones under Mild Neutral Conditions

(2013) Rauful Alam et al.   ORGANIC LETTERS

Enantioselective Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines with Allylboron Reagents

(2012) Yunfei Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Diastereoselective Construction of Acyclic Systems with Two Adjacent Quaternary Stereocenters by Allylation of Ketones

(2012) Takeshi Takeda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Stereoselective Allylation and Crotylation of Indoles at C2 Through the Use of Potassium Organotrifluoroborate Salts

(2012) Farhad Nowrouzi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Synthesis and Isolation of Functionalized Allylboronic Acids: Selective, Direct Allylboration of Ketones

(2012) Mihai Raducan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Synthesis of B-Allyl and B-Allenyldiisopinocampheylborane Reagents Using Allyl or Propargyl Halides and Indium Metal Under Barbier-Type Conditions

(2012) Lacie C. Hirayama et al.   JOURNAL OF ORGANIC CHEMISTRY

Use of alkyl 2,4,6-triisopropylbenzoates in the asymmetric homologation of challenging boronic esters

(2011) Robin Larouche-Gauthier et al.   CHEMICAL COMMUNICATIONS

Enantioselective synthesis of all-carbon quaternary stereogenic centers in acyclic systems

(2011) Jaya Prakash Das et al.   CHEMICAL COMMUNICATIONS

Catalytic Enantioselective Formation of C−C Bonds by Addition to Imines and Hydrazones: A Ten-Year Update

(2011) Shu̅ Kobayashi et al.   CHEMICAL REVIEWS

Enantioselective Synthesis of Homoallylic Amines through Reactions of (Pinacolato)allylborons with Aryl-, Heteroaryl-, Alkyl-, or Alkene-Substituted Aldimines Catalyzed by ChiralC1-Symmetric NHC−Cu Complexes

(2011) Erika M. Vieira et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Syntheses of (+)-Sertraline and (+)-Indatraline Using Lithiation/Borylation–Protodeboronation Methodology

(2011) Stefan Roesner et al.   ORGANIC LETTERS

Identification of Modular Chiral Bisphosphines Effective for Cu(I)-Catalyzed Asymmetric Allylation and Propargylation of Ketones

(2010) Shi-Liang Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Diastereoselective Preparation of Homoallylic Alcohols Containing Two Contiguous Quaternary Stereocenters in Acyclic Systems from Simple Terminal Alkynes

(2010) Bishnu Dutta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild and General Zinc-Alkoxide-Catalyzed Allylations of Ketones with Allyl Pinacol Boronates

(2010) Keith R. Fandrick et al.   ORGANIC LETTERS

Allyl Transfer to Aldehydes and Ketones by Brønsted Acid Activation of Allyl and Crotyl 1,3,2-Dioxazaborolidines

(2010) Maureen K. Reilly et al.   ORGANIC LETTERS

The Mechanism and an Improved Asymmetric Allylboration of Ketones Catalyzed by Chiral Biphenols

(2009) David S. Barnett et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diene-Ligated Iridium Catalyst for Allylation Reactions of Ketones and Imines

(2009) Timothy J. Barker et al.   ORGANIC LETTERS

Allylation and Crotylation of Ketones and Aldehydes Using Potassium Organotrifluoroborate Salts under Lewis Acid and Montmorillonite K10 Catalyzed Conditions

(2009) Farhad Nowrouzi et al.   ORGANIC LETTERS

Organozinc Generation via the Titanium-Catalyzed Activation of Alkyl Halides

(2009) Lauren M. Fleury et al.   ORGANIC LETTERS

Catalytic Use of Indium(0) for Carbon−Carbon Bond Transformations in Water: General Catalytic Allylations of Ketones with Allylboronates

(2008) Uwe Schneider et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zn-Catalyzed Asymmetric Allylation for the Synthesis of Optically Active Allylglycine Derivatives. Regio- and Stereoselective Formal α-Addition of Allylboronates to Hydrazono Esters

(2008) Mari Fujita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Borabicyclo[3.3.2]decanes and the Stereoselective Asymmetric Synthesis of 1,3-Diol Stereotriads from 1,3-Diborylpropenes

(2008) Ana Z. González et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Diastereoselective Addition of Cinnamylzinc Derivatives to α-Chiral Carbonyl Compounds

(2007) Guillaume Dunet et al.   ORGANIC LETTERS