High Site Selectivity in Electrophilic Aromatic Substitutions: Mechanism of C–H Thianthrenation

Catalytic Transformations of Sulfonium Salts via C‐S Bond Activation

(2021) Hideki Yorimitsu   CHEMICAL RECORD

Late‐Stage Heteroarylation of Hetero(aryl)sulfonium Salts Activated by α‐Amino Alkyl Radicals

(2021) Eva Maria Alvarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective C–H alkylation of Complex Arenes by a Two-Step Aryl Thianthrenation-Reductive Alkylation Sequence

(2021) Beatrice Lansbergen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-free photoredox-catalysed formal C–H/C–H coupling of arenes enabled by interrupted Pummerer activation

(2020) Miles H. Aukland et al.   Nature Catalysis

Synthetic Applications of Sulfonium Salts

(2020) Manuel Alcarazo et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Achieving Site-Selectivity for C–H Activation Processes Based on Distance and Geometry: A Carpenter’s Approach

(2020) Guangrong Meng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective C–H Functionalization–Sulfination Sequence to Access Aryl Sulfonamides

(2020) Eva Maria Alvarez et al.   ORGANIC LETTERS

Late-Stage Diversification of Natural Products

(2020) Benke Hong et al.   ACS Central Science

Analysis of Benzenoid Substitution Patterns in Small Molecule Active Pharmaceutical Ingredients

(2020) Aleksandra Nilova et al.   JOURNAL OF MEDICINAL CHEMISTRY

Germylation of Arenes via Pd(I) Dimer Enabled Sulfonium Salt Functionalization

(2020) Aymane Selmani et al.   ORGANIC LETTERS

Late-Stage Functionalization

(2020) Jonas Börgel et al.   Chem

Site-selective and versatile aromatic C−H functionalization by thianthrenation

(2019) Florian Berger et al.   NATURE

The Interrupted Pummerer Reaction in a Sulfoxide-Catalyzed Oxidative Coupling of 2-Naphthols

(2019) Zhen He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts

(2019) Daniel Kaiser et al.   CHEMICAL REVIEWS

C–N Cross-Couplings for Site-Selective Late-Stage Diversification via Aryl Sulfonium Salts

(2019) Pascal S. Engl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective C−H Oxygenation via Aryl Sulfonium Salts

(2019) Ruocheng Sang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Stereoselective Thianthrenation of Olefins to Access Versatile Alkenyl Electrophiles

(2019) Tobias Ritter et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, Structure, and Reactivity of 5-(Aryl)dibenzothiophenium Triflates

(2019) Kevin Kafuta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox catalysis with aryl sulfonium salts enables site-selective late-stage fluorination

(2019) Jiakun Li et al.   Nature Chemistry

Para-selective borylation of monosubstituted benzenes using a transient mediator

(2019) Jie Wu et al.   Science China-Chemistry

Site-Selective Late-Stage Aromatic [18 F]Fluorination via Aryl Sulfonium Salts

(2019) Peng Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Application of arylsulfonium salts as arylation reagents

(2018) Ze-Yu Tian et al.   TETRAHEDRON LETTERS

Dual vicinal functionalisation of heterocycles via an interrupted Pummerer coupling/[3,3]-sigmatropic rearrangement cascade

(2018) Mindaugas Šiaučiulis et al.   Chemical Science

Fast and accurate prediction of the regioselectivity of electrophilic aromatic substitution reactions

(2018) Jimmy C. Kromann et al.   Chemical Science

C–S Bond Activation

(2018) Shinya Otsuka et al.   Topics in Current Chemistry

A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

(2018) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Palladium-catalysed electrophilic aromatic C–H fluorination

(2018) Kumiko Yamamoto et al.   NATURE

Divergent Late-Stage (Hetero)aryl C−H Amination by the Pyridinium Radical Cation

(2018) Won Seok Ham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Predictive Tool for Electrophilic Aromatic Substitutions Using Machine Learning

(2018) Anna Tomberg et al.   JOURNAL OF ORGANIC CHEMISTRY

Late-Stage Aromatic C–H Oxygenation

(2018) Jonas Börgel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Late-Stage Direct Arene Cyanation

(2018) Da Zhao et al.   Chem

Azulenesulfonium Salts: Accessible, Stable, and Versatile Reagents for Cross-Coupling

(2016) Paul Cowper et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−H Coupling Reactions Directed by Sulfoxides: Teaching an Old Functional Group New Tricks

(2016) Alexander P. Pulis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sterically-controlled intermolecular Friedel–Crafts acylation with twisted amides via selective N–C cleavage under mild conditions

(2016) Yongmei Liu et al.   CHEMICAL COMMUNICATIONS

Reaching the south: metal-catalyzed transformation of the aromatic para-position

(2016) Aniruddha Dey et al.   CHEMICAL COMMUNICATIONS

The medicinal chemist's toolbox for late stage functionalization of drug-like molecules

(2016) Tim Cernak et al.   CHEMICAL SOCIETY REVIEWS

Charge-transfer-directed radical substitution enables para-selective C–H functionalization

(2016) Gregory B. Boursalian et al.   Nature Chemistry

C 2-Symmetric Chiral Sulfoxide-Mediated Intermolecular Interrupted Pummerer Reaction for Enantioselective Construction of C3a-Substituted Pyrroloindolines

(2016) Kazuhiro Higuchi et al.   SYNLETT

Iridium-Catalyzed Borylation of Primary Benzylic C–H Bonds without a Directing Group: Scope, Mechanism, and Origins of Selectivity

(2015) Matthew A. Larsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H Functionalization at Sterically Congested Positions by the Platinum-Catalyzed Borylation of Arenes

(2015) Takayuki Furukawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

para-C–H Borylation of Benzene Derivatives by a Bulky Iridium Catalyst

(2015) Yutaro Saito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Distortion/Interaction Analysis Reveals the Origins of Selectivities in Iridium-Catalyzed C–H Borylation of Substituted Arenes and 5-Membered Heterocycles

(2014) Aaron G. Green et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition-Metal Complexes

(2012) Eric M. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-metal mediated carbon–sulfur bond activation and transformations

(2012) Liandi Wang et al.   CHEMICAL SOCIETY REVIEWS

Activation of remote meta-C–H bonds assisted by an end-on template

(2012) Dasheng Leow et al.   NATURE

Sulfoxide-TFAA and nucleophile combination as new reagent for aliphatic C–H functionalization at indole 2α-position

(2012) Masanori Tayu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Active thionium species mediated functionalization at the 2α-position of indole derivatives

(2011) Kazuhiro Higuchi et al.   CHEMICAL COMMUNICATIONS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Beyond the Pummerer Reaction: Recent Developments in Thionium Ion Chemistry

(2010) Laura H. S. Smith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Trifluoroacetylation in Organic Synthesis: Reagents, Developments and Applications in the Construction of Trifluoromethylated Compounds

(2010) Simon Lopez et al.   CURRENT ORGANIC SYNTHESIS

Validation of a Computational Model for Predicting the Site for Electrophilic Substitution in Aromatic Systems

(2010) Magnus Liljenberg et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

A remarkable difference in the deprotonation steps of the Friedel-Crafts acylation and alkylation reactions

(2009) Shinichi Yamabe et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Synthesis and Redox Behavior of 1-Azulenyl Sulfides and Efficient Synthesis of 1,1′-Biazulenes

(2008) Taku Shoji et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY