Late‐Stage Heteroarylation of Hetero(aryl)sulfonium Salts Activated by α‐Amino Alkyl Radicals

Redox reactions of small organic molecules using ball milling and piezoelectric materials

(2020) Koji Kubota et al.   SCIENCE

Aminoalkyl radicals as halogen-atom transfer agents for activation of alkyl and aryl halides

(2020) Timothée Constantin et al.   SCIENCE

Metal-free photoredox-catalysed formal C–H/C–H coupling of arenes enabled by interrupted Pummerer activation

(2020) Miles H. Aukland et al.   Nature Catalysis

Synthetic Applications of Sulfonium Salts

(2020) Manuel Alcarazo et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Site-Selective C–H Functionalization–Sulfination Sequence to Access Aryl Sulfonamides

(2020) Eva Maria Alvarez et al.   ORGANIC LETTERS

Germylation of Arenes via Pd(I) Dimer Enabled Sulfonium Salt Functionalization

(2020) Aymane Selmani et al.   ORGANIC LETTERS

Cine-Substitutions at Five-Membered Hetarenes Enabled by Sulfonium Salts

(2020) Florian Berger et al.   ORGANIC LETTERS

Photoinduced Copper-Catalyzed Site-Selective C(sp2)–C(sp) Cross-Coupling via Aryl Sulfonium Salts

(2020) Lei Liang et al.   ORGANIC LETTERS

Site-selective and versatile aromatic C−H functionalization by thianthrenation

(2019) Florian Berger et al.   NATURE

C–N Cross-Couplings for Site-Selective Late-Stage Diversification via Aryl Sulfonium Salts

(2019) Pascal S. Engl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aryl Sulfonium Salts for Site-Selective Late-Stage Trifluoromethylation

(2019) Fei Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective C−H Oxygenation via Aryl Sulfonium Salts

(2019) Ruocheng Sang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox catalysis with aryl sulfonium salts enables site-selective late-stage fluorination

(2019) Jiakun Li et al.   Nature Chemistry

Site-Selective Late-Stage Aromatic [18 F]Fluorination via Aryl Sulfonium Salts

(2019) Peng Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thirty Years of (TMS)3SiH: A Milestone in Radical-Based Synthetic Chemistry

(2018) Chryssostomos Chatgilialoglu et al.   CHEMICAL REVIEWS

A radical approach to the copper oxidative addition problem: Trifluoromethylation of bromoarenes

(2018) Chip Le et al.   SCIENCE

Upconversion of reductants

(2018) Mikhail A. Syroeshkin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ring-Closing Synthesis of Dibenzothiophene Sulfonium Salts and Their Use as Leaving Groups for Aromatic 18F-Fluorination

(2018) Thibault Gendron et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Radical Borylation of Alkyl and Aryl Iodides

(2018) Ying Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterocyclic Allylsulfones as Latent Heteroaryl Nucleophiles in Palladium-Catalyzed Cross-Coupling Reactions

(2018) Tim Markovic et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Simple and Efficient Generation of Aryl Radicals from Aryl Triflates: Synthesis of Aryl Boronates and Aryl Iodides at Room Temperature

(2017) Wenbo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Borylation of Aryl Sulfoniums with Diborons

(2017) Hiroko Minami et al.   ACS Catalysis

Visible Light Mediated Photoredox Catalytic Arylation Reactions

(2016) Indrajit Ghosh et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct Arylation of N-Heteroarenes with Aryldiazonium Salts by Photoredox Catalysis in Water

(2014) Dong Xue et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Syntheses of Menisporphine and Daurioxoisoporphine C Enabled by Photoredox-Catalyzed Direct C–H Arylation of Isoquinoline with Aryldiazonium Salt

(2014) Jing Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Reduction of aryl halides by consecutive visible light-induced electron transfer processes

(2014) I. Ghosh et al.   SCIENCE

A Dual-Catalysis Approach to Enantioselective [2 + 2] Photocycloadditions Using Visible Light

(2014) J. Du et al.   SCIENCE

Visible-Light Photocatalytic Reduction of Sulfonium Salts as a Source of Aryl Radicals

(2013) Simon Donck et al.   ADVANCED SYNTHESIS & CATALYSIS

Single-Operation Deracemization of 3H-Indolines and Tetrahydroquinolines Enabled by Phase Separation

(2013) Aaron D. Lackner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Active participation of amine-derived radicals in photoredox catalysis as exemplified by a reductive cyclization

(2013) Hossein Ismaili et al.   Catalysis Science & Technology

Metal-Free, Visible Light-Induced Borylation of Aryldiazonium Salts: A Simple and Green Synthetic Route to Arylboronates

(2012) Jian Yu et al.   ADVANCED SYNTHESIS & CATALYSIS

Metal-Free, Visible-Light-Mediated Direct C–H Arylation of Heteroarenes with Aryl Diazonium Salts

(2012) Durga Prasad Hari et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reduction potentials of para-substituted nitrobenzenes-an infrared, nuclear magnetic resonance, and density functional theory study

(2011) Annemarie Kuhn et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Practical Iron-Catalyzed Allylations of Aryl Grignard Reagents

(2010) Matthias Mayer et al.   ADVANCED SYNTHESIS & CATALYSIS

tert-Butoxide-Mediated Arylation of Benzene with Aryl Halides in the Presence of a Catalytic 1,10-Phenanthroline Derivative

(2010) Eiji Shirakawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C−H Arylation of Electron-Deficient Heterocycles with Arylboronic Acids

(2010) Ian B. Seiple et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY