Rhodium(III)‐Catalyzed Asymmetric [4+1] and [5+1] Annulation of Arenes and 1,3‐Enynes: A Distinct Mechanism of Allyl Formation and Allyl Functionalization

The Mechanism of Rhodium Catalyzed Allylic C–H Amination

(2020) Robert J Harris et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Reaction of α-Carbonyl Sulfoxonium Ylides and Alkenes: Synthesis of Indanones via [4 + 1] Cycloaddition

(2020) Yadagiri Kommagalla et al.   ORGANIC LETTERS

Rhodium(III)‐Catalyzed Atroposelective Synthesis of Biaryls by C−H Activation and Intermolecular Coupling with Sterically Hindered Alkynes

(2020) Fen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divergent Synthesis of Tunable Cyclopentadienyl Ligands and Their Application in Rh-Catalyzed Enantioselective Synthesis of Isoindolinone

(2020) Wen-Jun Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sulfoxonium-Ylide-Directed C–H Activation and Tandem (4 + 1) Annulation

(2020) Vinayak Hanchate et al.   ORGANIC LETTERS

Palladium-Catalyzed meta-C–H Allylation of Arenes: A Unique Combination of a Pyrimidine-Based Template and Hexafluoroisopropanol

(2020) Sukdev Bag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Designing a Planar Chiral Rhodium Indenyl Catalyst for Regio- and Enantioselective Allylic C–H Amidation

(2020) Caitlin M. B. Farr et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Enantioselective CpxRh(III)-Catalyzed C-H Functionalization / Ring-Opening Route to Chiral Cyclopentenylamines

(2019) Nicolai Cramer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemodivergent Oxidative Annulation of Benzamides and Enynes via 1,4-Rhodium Migration

(2019) Jiaqiong Sun et al.   ORGANIC LETTERS

CuH-Catalyzed Enantioselective Ketone Allylation with 1,3-Dienes: Scope, Mechanism, and Applications

(2019) Chengxi Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidatively Induced Reductive Elimination: Exploring the Scope and Catalyst Systems with Ir, Rh, and Ru Complexes

(2019) Jinwoo Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ir-Catalyzed Intermolecular Branch-Selective Allylic C–H Amidation of Unactivated Terminal Olefins

(2019) Honghui Lei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular, Branch-Selective and Redox-Neutral Cp*IrIII-Catalyzed Allylic C-H Amidation

(2019) Tobias Knecht et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Prenylation and Reverse Prenylation of Indoles with Isoprene: Regioselectivity Manipulation through Choice of Metal Hydride

(2019) Yan-Cheng Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Kinetic Resolution of Sulfur-Stereogenic Sulfoximines by Exploiting CpX RhIII -Catalyzed C−H Functionalization

(2019) Marcus Brauns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Directed meta-Selective C−H Allylation of Arenes: Unactivated Internal Olefins as Allyl Surrogates

(2019) Tapas Kumar Achar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Reductive Allylation of Ketones with 1,3-Dienes

(2019) Bin Fu et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed C-H Activation/Carbene Insertion/Lossen Rearrangement Sequence: Efficient Synthesis of Spirooxindole Pyrrolones

(2019) Huixiong Dai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,4‐Migration of Transition Metals in Organic Synthesis

(2019) Abdur Rahim et al.   CHINESE JOURNAL OF CHEMISTRY

Rhodium(III)-Catalyzed Oxidative Allylic C–H Indolylation via Nucleophilic Cyclization

(2019) Jiaqiong Sun et al.   ORGANIC LETTERS

Stereoselective β–F Elimination Enabled Redox-Neutral [4 + 1] Annulation via Rh(III)-Catalyzed C–H Activation: Access to Z-Monofluoroalkenyl Dihydrobenzo[d]isoxazole Framework

(2019) Hui Gao et al.   ORGANIC LETTERS

Rhodium-Catalyzed Enantioselective Oxidative [3+2] Annulation of Arenes and Azabicyclic Olefins through Twofold C−H Activation

(2019) Ruijie Mi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular 1,4-Carboamination of Conjugated Dienes Enabled by Cp*RhIII -Catalyzed C−H Activation

(2019) Tobias Pinkert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Alkenyl C−H Functionalization by Cpx RhIII forms 2H -Pyrrol-2-ones through [4+1]-Annulation of Acryl Amides and Allenes

(2019) Shou-Guo Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed C(sp2)–H Allylation of Biphenyl Amines with Unbiased Terminal Olefins

(2019) Alessio Baccalini et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Enantio- and Diastereoselective C−H Cyclopropylation of N-Phenoxylsulfonamides: Combined Experimental and Computational Studies

(2019) Guangfan Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Planar-Chiral Rhodium(III) Catalyst with a Sterically Demanding Cyclopentadienyl Ligand and Its Application in the Enantioselective Synthesis of Dihydroisoquinolones

(2018) Evgeniya A. Trifonova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Solvent-Dependent Asymmetric Synthesis of Alkynyl and Monofluoroalkenyl Isoindolinones by CpRhIII -Catalyzed C−H Activation

(2018) Teng Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Carbon Oxidative Annulations of 1,3-Enynes by Catalytic C−H Functionalization and 1,4-Rhodium(III) Migration

(2018) Johnathon D. Dooley et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral Carboxylic Acid Enabled Achiral Rhodium(III)-Catalyzed Enantioselective C−H Functionalization

(2018) Luqing Lin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Non-Directed Cross-Dehydrogenative (Hetero)arylation of Allylic C(sp3)-H bonds enabled by C-H activation

(2018) Andreas Lerchen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to P - and Axially Chiral Biaryl Phosphine Oxides by Enantioselective Cpx IrIII -Catalyzed C−H Arylations

(2018) Yun-Suk Jang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Allylic C-H Etherification of Internal Olefins

(2018) Taylor Nelson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

(2018) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Synthesis of Chiral-at-Sulfur 1,2-Benzothiazines by Cpx RhIII -Catalyzed C−H Functionalization of Sulfoximines

(2018) Yang Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantiodivergent Desymmetrization in the Rhodium(III)-Catalyzed Annulation of Sulfoximines with Diazo Compounds

(2018) Bingxue Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Formal C(sp3 )−H Bond Activation in the Synthesis of Bioactive Spiropyrazolone Derivatives

(2018) Houhua Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Enantioselective Coupling of Indoles and 7-Azabenzonorbornadienes by C−H Activation/Desymmetrization

(2018) Xifa Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cp*RhIII-Catalyzed Allyl–Aryl Coupling of Olefins and Arylboron Reagents Enabled by C(sp3)–H Activation

(2018) Tobias Knecht et al.   ACS Catalysis

C–F Bond Cleavage Enabled Redox-Neutral [4+1] Annulation via C–H Bond Activation

(2017) Cheng-Qiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-catalysed arylation of C–H bonds enabled by oxidatively induced reductive elimination

(2017) Kwangmin Shin et al.   Nature Chemistry

Propargyl Alcohols as One-Carbon Synthons: Redox-Neutral Rhodium(III)-Catalyzed C–H Bond Activation for the Synthesis of Isoindolinones Bearing a Quaternary Carbon

(2017) Xiaowei Wu et al.   ORGANIC LETTERS

Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reaction

(2017) Soham Maity et al.   Chemical Science

Enantioselective C–H Annulation of Indoles with Diazo Compounds through a Chiral Rh(III) Catalyst

(2017) Xiaohong Chen et al.   ACS Catalysis

Branching Out: Rhodium-Catalyzed Allylation with Alkynes and Allenes

(2016) Philipp Koschker et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Allylic C−H Oxidation of Terminal Olefins to Isochromans by Palladium(II)/Chiral Sulfoxide Catalysis

(2016) Stephen E. Ammann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Enantiotopic C−H Activation Enables Access to P -Chiral Cyclic Phosphinamides

(2016) Yang Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds

(2016) Joshua R. Hummel et al.   CHEMICAL REVIEWS

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Access to Spirocyclic Sultams by Chiral Cpx -Rhodium(III)-Catalyzed Annulations

(2016) Manh V. Pham et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aerobic Linear Allylic C–H Amination: Overcoming Benzoquinone Inhibition

(2016) Christopher C. Pattillo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Formation of All-Carbon Quaternary Centers via C–H Functionalization of Methanol: Iridium-Catalyzed Diene Hydrohydroxymethylation

(2016) Khoa D. Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Catalysis Powered by Chiral Cyclopentadienyl Ligands

(2016) Christopher G. Newton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes

(2016) Jun Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regiocontrolled Coupling of Aromatic and Vinylic Amides with α-Allenols To Form γ-Lactams via Rhodium(III)-Catalyzed C–H Activation

(2016) Zhi Zhou et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Aryl and Alkenyl C–H Bond Addition to Diverse Nitroalkenes

(2016) Tyler J. Potter et al.   ACS Catalysis

Switch to Allylic Selectivity in Cobalt-Catalyzed Dehydrogenative Heck Reactions with Unbiased Aliphatic Olefins

(2016) Soham Maity et al.   ACS Catalysis

Bidentate, Monoanionic Auxiliary-Directed Functionalization of Carbon–Hydrogen Bonds

(2015) Olafs Daugulis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

(2015) Guoyong Song et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations

(2015) Baihua Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed CH Functionalization and 1,4-Migration

(2015) David J. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Neutral Rhodium-Catalyzed CH Functionalization of ArylamineN-Oxides with Diazo Compounds: Primary C(sp3)H/C(sp2)H Activation and Oxygen-Atom Transfer

(2015) Bing Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Spiroindenes by Enol-Directed Rhodium(III)-Catalyzed CH Functionalization and Spiroannulation

(2015) Suresh Reddy Chidipudi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed [4+1] Annulation of Aromatic and Vinylic Carboxylic Acids with Allenes: An Efficient Method Towards Vinyl-Substituted Phthalides and 2-Furanones

(2015) Parthasarathy Gandeepan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp2)–H Functionalization/Annulation Reaction

(2015) Jun Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Cyclization of Arylnitrones to Indolines under External Oxidant-Free Conditions: Dual Role of Rh(III) Catalyst in the C–H Activation and Oxygen Atom Transfer

(2015) Ramesh B. Dateer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed C–H Activation of Phenacyl Ammonium Salts Assisted by an Oxidizing C–N Bond: A Combination of Experimental and Theoretical Studies

(2015) Songjie Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

RhIII-Catalyzed [4 + 1] Annulations of 2-Hydroxy- and 2-Aminobenzaldehydes with Allenes: A Simple Method toward 3-Coumaranones and 3-Indolinones

(2015) Ramajayam Kuppusamy et al.   ORGANIC LETTERS

Formal SN-Type Reactions in Rhodium(III)-Catalyzed CH Bond Activation

(2014) Nadine Kuhl et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic 1,4-Rhodium(III) Migration Enables 1,3-Enynes to Function as One-Carbon Oxidative Annulation Partners in CH Functionalizations

(2014) David J. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Isoindolones by Chiral Cyclopentadienyl-Rhodium(III)-Catalyzed CH Functionalizations

(2014) Baihua Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Arene C–H functionalisation using a removable/modifiable or a traceless directing group strategy

(2014) Fengzhi Zhang et al.   CHEMICAL SOCIETY REVIEWS

Terminal Olefins to Chromans, Isochromans, and Pyrans via Allylic C–H Oxidation

(2014) Stephen E. Ammann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Cp-Rhodium(III)-Catalyzed Asymmetric Hydroarylations of 1,1-Disubstituted Alkenes

(2013) Baihua Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Tunable Class of Chiral Cp Ligands for Enantioselective Rhodium(III)-Catalyzed C–H Allylations of Benzamides

(2013) Baihua Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst-Controlled C–O versus C–N Allylic Functionalization of Terminal Olefins

(2013) Iulia I. Strambeanu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Coupling of Benzamides and Donor/Acceptor Diazo Compounds To Form γ-Lactams via Rh(III)-Catalyzed C–H Activation

(2013) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(iii)-catalyzed C–H activation/[4 + 3] cycloaddition of benzamides and vinylcarbenoids: facile synthesis of azepinones

(2013) Sunliang Cui et al.   Chemical Science

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C-H Activation

(2012) T. K. Hyster et al.   SCIENCE

Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization

(2012) B. Ye et al.   SCIENCE

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Diastereo- and Enantioselective Ruthenium-Catalyzed Hydrohydroxyalkylation of 2-Silyl-butadienes: Carbonylsyn-Crotylation from the Alcohol Oxidation Level

(2011) Jason R. Zbieg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution

(2010) John F. Hartwig et al.   ACCOUNTS OF CHEMICAL RESEARCH

Iridium-Catalyzed Hydrohydroxyalkylation of Butadiene: Carbonyl Crotylation

(2010) Jason R. Zbieg et al.   ADVANCED SYNTHESIS & CATALYSIS

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Allylic C−H Acetoxylation with a 4,5-Diazafluorenone-Ligated Palladium Catalyst: A Ligand-Based Strategy To Achieve Aerobic Catalytic Turnover

(2010) Alison N. Campbell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidatively Induced Reductive Elimination from (tBu2bpy)Pd(Me)2: Palladium(IV) Intermediates in a One-Electron Oxidation Reaction

(2009) Michael P. Lanci et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Chiral Lewis Acid Strategy for Enantioselective Allylic CH Oxidation

(2008) Dustin J. Covell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed C−C Bond Forming Transfer Hydrogenation: Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Employing Acyclic 1,3-Dienes as Surrogates to Preformed Allyl Metal Reagents

(2008) Fumitoshi Shibahara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intra/Intermolecular Direct Allylic Alkylation via Pd(II)-Catalyzed Allylic C−H Activation

(2008) Song Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed C−C Coupling via Transfer Hydrogenation:  Carbonyl Addition from the Alcohol or Aldehyde Oxidation Level Employing 1,3-Cyclohexadiene

(2008) John F. Bower et al.   ORGANIC LETTERS

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION