1,4‐Migration of Transition Metals in Organic Synthesis

Asymmetric Alkenylation of Enones and Imines Enabled by Highly Efficient Aryl to Vinyl 1,4-Rhodium Migration

(2019) Shu-Sheng Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Synthesis of Silicon-Bridged 1,2-Dialkenylbenzenes via 1,4-Rhodium Migration

(2019) Takuya Miwa et al.   ORGANIC LETTERS

Chemodivergent Oxidative Annulation of Benzamides and Enynes via 1,4-Rhodium Migration

(2019) Jiaqiong Sun et al.   ORGANIC LETTERS

1,4-Palladium Shift/C(sp3)–H Activation Strategy for the Remote Construction of Five-Membered Rings

(2019) Ronan Rocaboy et al.   ORGANIC LETTERS

Construction of Quaternary Stereocenters by Palladium-Catalyzed Carbopalladation-Initiated Cascade Reactions

(2018) Yuanyuan Ping et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Stereoselective Synthesis of 1,3-Dienes through an Aryl to Vinyl 1,4-Palladium Migration/Heck Sequence

(2018) Tian-Jiao Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,4-Iron Migration for Expedient Allene Annulations through Iron-Catalyzed C−H/N−H/C−O/C−H Functionalizations

(2018) Jiayu Mo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Carbon Oxidative Annulations of 1,3-Enynes by Catalytic C−H Functionalization and 1,4-Rhodium(III) Migration

(2018) Johnathon D. Dooley et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Substituted Naphthalenes by 1,4-Palladium Migration Involved Annulation with Internal Alkynes

(2018) Dong Wei et al.   CHINESE JOURNAL OF CHEMISTRY

Efficient Access to cis-Hydrobenzo[b]oxepines: Rhodium(I)-Catalyzed Cyclization of Cyclohexadienone-Tethered o-Tolyl-Substituted Alkynes

(2018) Wei-Wei Liao et al.   SYNLETT

Rhodium-Catalyzed Arylzincation of Alkynes: Ligand Control of 1,4-Migration Selectivity

(2018) Jialin Ming et al.   ORGANIC LETTERS

Addition of arylstannanes to alkynes giving ortho-alkenylarylstannanes catalysed cooperatively by a rhodium complex and zinc chloride

(2018) Jialin Ming et al.   Chemical Science

Synthesis of β,β-Disubstituted Indanones via the Pd-Catalyzed Tandem Conjugate Addition/Cyclization Reaction of Arylboronic Acids with α,β-Unsaturated Esters

(2017) Ang Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Phenanthrene Synthesis by Palladium-Catalyzed Benzannulation with o-Bromobenzyl Alcohols through Multiple Carbon–Carbon Bond Formations

(2017) Masayuki Iwasaki et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Oxidative C–H Allylation of Benzamides with 1,3-Dienes by Allyl-to-Allyl 1,4-Rh(III) Migration

(2016) Stamatis E. Korkis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Borylation of Olefin C–H Bond via Aryl to Vinyl Palladium 1,4-Migration

(2016) Tian-Jiao Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aryloxymethyltrifluoroborates for Rhodium-Catalyzed Asymmetric Conjugate Arylation. o-Methoxyarylation through 1,4-Rhodium Shift

(2016) Jialin Ming et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Cascade Annulation/C–H Activation of o-Ethynylanilines with Diazo Compounds: One-Pot Synthesis of Benzo[a]carbazoles via 1,4-Rhodium Migration

(2016) Songjin Guo et al.   ORGANIC LETTERS

Merging rhodium-catalysed C–H activation and hydroamination in a highly selective [4+2] imine/alkyne annulation

(2016) Rajith S. Manan et al.   Nature Communications

Cobalt-Catalyzed Arylative Cyclization of Acetylenic Esters and Ketones with Arylzinc Reagents through 1,4-Cobalt Migration

(2016) Jianming Yan et al.   ACS Catalysis

All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed CH Functionalization and 1,4-Migration

(2015) David J. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Through-Space 1,4-Palladium Migration and 1,2-Aryl Shift: Direct Access to Dibenzo[a,c]carbazoles through a Triple CH Functionalization Cascade

(2015) Samir Kumar Bhunia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd-Catalyzed Intramolecular C–N Bond Cleavage, 1,4-Migration, sp3 C–H Activation, and Heck Reaction: Four Controllable Diverse Pathways Depending on the Judicious Choice of the Base and Ligand

(2015) Min Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective C–C and C–H Bond Activation/Cleavage of Pinene Derivatives: Synthesis of Enantiopure Cyclohexenone Scaffolds and Mechanistic Insights

(2015) Ahmad Masarwa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalysed arylative annulation of 1,4-enynes with arylboronic acids

(2015) Takanori Matsuda et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Formation of Carbocycles via a 1,4-Rh Shift Triggered by a Rhodium-Catalyzed Addition of Terminal Alkynes to 3,3-Diarylcyclopropenes

(2015) Takahiro Sawano et al.   ORGANIC LETTERS

Rhodium-Catalyzed Addition–Spirocyclization of Arylboronic Esters Containing β-Aryl α,β-Unsaturated Ester Moiety

(2015) Takanori Matsuda et al.   SYNLETT

The Isomerization of Allylrhodium Intermediates in the Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines

(2014) Hamish B. Hepburn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Arylative Cyclization of Alkynones by 1,4-Iridium Migration

(2014) Benjamin M. Partridge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic 1,4-Rhodium(III) Migration Enables 1,3-Enynes to Function as One-Carbon Oxidative Annulation Partners in CH Functionalizations

(2014) David J. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Study on Rh-Catalyzed Stereoselective CC/CH Activation oftert-Cyclobutanols

(2014) Haizhu Yu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Polymerization of 3,3-Diarylcyclopropenes Involving a 1,4-Rhodium Migration

(2014) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Addition of Arylzinc Reagents to Norbornene Derivatives through 1,4-Cobalt Migration

(2014) Boon-Hong Tan et al.   ORGANIC LETTERS

Pd-Catalyzed Dehydrogenative Aryl–Aryl Bond Formation via Double C(sp2)–H Bond Activation: Efficient Synthesis of [3,4]-Fused Oxindoles

(2014) Ala Bunescu et al.   ORGANIC LETTERS

Reversibility of 1,4-Metal Migration in Cp*RhIII and Cp*IrIII Complexes

(2014) Yousuke Ikeda et al.   ORGANOMETALLICS

1,4- and 1,3-Metal Migration in a Cp*IrIII Complex: Experimental Evidence of Direct 1,3-Metal Migration

(2014) Yousuke Ikeda et al.   ORGANOMETALLICS

Palladium-Catalyzed Through-Space C(sp3)H and C(sp2)H Bond Activation by 1,4-Palladium Migration: Efficient Synthesis of [3,4]-Fused Oxindoles

(2013) Tiffany Piou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,4-Metal migration in a Cp*Rh(iii) complex

(2013) Yousuke Ikeda et al.   CHEMICAL COMMUNICATIONS

Mild rhodium(i) catalyzed ring opening of cyclopropane appended spirotricyclic olefins through C–H activation of arylboronic acids

(2013) Praveen Prakash et al.   RSC Advances

Cobalt-Catalyzed Addition of Arylzinc Reagents to Alkynes to Form ortho-Alkenylarylzinc Species through 1,4-Cobalt Migration

(2012) Boon-Hong Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Double 1,4-rhodium migration cascade in rhodium-catalysed arylative ring-opening/spirocyclisation of (3-arylcyclobutylidene)acetates

(2012) Takanori Matsuda et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed oxidative arylation of trisubstituted olefin: an efficient synthesis of 3-(disubstituted)alkylidene-oxindoles

(2012) Hyun Ju Lee et al.   TETRAHEDRON LETTERS

Rhodium/diene-catalyzed tandem 1,4-shift/1,4-addition of (E)-1,2-diphenylethenylboronic acid to enones: density functional theory modeling and asymmetric catalysis

(2012) Keigo Sasaki et al.   Chemical Science

β-Carbon Elimination from Cyclobutanols: A Clean Access to Alkylrhodium Intermediates Bearing a Quaternary Stereogenic Center

(2011) Nicolai Cramer et al.   SYNLETT

Rhodium(I)-Catalyzed 1,4-Silicon Shift of Unactivated Silanes from Aryl to Alkyl: Enantioselective Synthesis of Indanol Derivatives

(2010) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Synthesis of Spirocarbocycles: Arylboron Reagents as Surrogates of 1,2-Dimetalloarenes

(2010) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular Palladium-Catalyzed Alkane C−H Arylation from Aryl Chlorides

(2010) Sophie Rousseaux et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Indanols from tert-Cyclobutanols Using a Rhodium-Catalyzed CC/CH Activation Sequence

(2009) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Restructuring of 3-Arylcyclobutanols into 1-Indanols by Sequential Breaking and Formation of Carbon–Carbon Bonds

(2009) Masanori Shigeno et al.   CHEMISTRY-A EUROPEAN JOURNAL

Water-Controlled Regioselectivity of Pd-Catalyzed Domino Reaction Involving a C−H Activation Process: Rapid Synthesis of Diverse Carbo- and Heterocyclic Skeletons

(2009) Zhiyao Lu et al.   ORGANIC LETTERS

Synthesis of cyclopropanes by Pd-catalyzed activation of alkyl C–H bonds

(2009) Qinhua Huang et al.   TETRAHEDRON LETTERS

Ligand Control in Enantioselective Desymmetrization of Bicyclic Hydrazines: Rhodium(I)-Catalyzed Ring-OpeningversusHydroarylation

(2008) Jane Panteleev et al.   ADVANCED SYNTHESIS & CATALYSIS

Chemodivergence in Enantioselective Desymmetrization of Diazabicycles: Ring-Opening versus Reductive Arylation

(2008) Frederic Menard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Rearrangement of Aryl Bis(alkynyl) Carbinols to 3-Alkynyl-1-indanones

(2008) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Benzocyclobutenes by Palladium-Catalyzed C−H Activation of Methyl Groups: Method and Mechanistic Study

(2008) Manon Chaumontet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Benzylic C–H activation and C–O bond formation via aryl to benzylic 1,4-palladium migrations

(2008) Tanay Kesharwani et al.   TETRAHEDRON