Enantioselective Synthesis of Chiral-at-Sulfur 1,2-Benzothiazines by Cpx RhIII -Catalyzed C−H Functionalization of Sulfoximines

Rhodium-Catalyzed Enantioposition-Selective Hydroarylation of Divinylphosphine Oxides with Aryl Boroxines

(2018) Zhe Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Enantioselective C−H Olefination of Diaryl Sulfoxides through Parallel Kinetic Resolution and Desymmetrization

(2018) Yu-Chao Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Bifunctional Phosphine-Carboxylate Ligands for Palladium(0)-Catalyzed Enantioselective C−H Arylation

(2018) Lei Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Planar-Chiral Rhodium(III) Catalyst with a Sterically Demanding Cyclopentadienyl Ligand and Its Application in the Enantioselective Synthesis of Dihydroisoquinolones

(2018) Evgeniya A. Trifonova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Readily Accessible Class of Chiral Cp Ligands and their Application in RuII -Catalyzed Enantioselective Syntheses of Dihydrobenzoindoles

(2018) Shou-Guo Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cp*Ir(iii)-catalyzed C–H/N–H functionalization of sulfoximines for the synthesis of 1,2-benzothiazines at room temperature

(2018) Yogesh N. Aher et al.   CHEMICAL COMMUNICATIONS

Enantioselective C(sp3)‒H bond activation by chiral transition metal catalysts

(2018) Tyler G. Saint-Denis et al.   SCIENCE

Rhodium(iii)-catalyzed annulative coupling between arenes and sulfoxonium ylides via C–H activation

(2018) Guangfan Zheng et al.   Organic Chemistry Frontiers

Chiral Carboxylic Acid Enabled Achiral Rhodium(III)-Catalyzed Enantioselective C−H Functionalization

(2018) Luqing Lin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to P - and Axially Chiral Biaryl Phosphine Oxides by Enantioselective Cpx IrIII -Catalyzed C−H Arylations

(2018) Yun-Suk Jang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Access to 1H -Isoindoles with Quaternary Stereogenic Centers by Palladium(0)-Catalyzed C−H Functionalization

(2018) Daria Grosheva et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective remote meta-C–H arylation and alkylation via a chiral transient mediator

(2018) Hang Shi et al.   NATURE

Sulfoximines from a Medicinal Chemist's Perspective: Physicochemical and in vitro Parameters Relevant for Drug Discovery

(2017) Marcus Frings et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Rhodium(III)-Catalyzed Ortho Halogenations of N-Acylsulfoximines and Synthetic Applications toward Functionalized Sulfoximine Derivatives

(2017) Ying Cheng et al.   ORGANIC LETTERS

P(O)R2-Directed Enantioselective C–H Olefination toward Chiral Atropoisomeric Phosphine–Olefin Compounds

(2017) Shi-Xia Li et al.   ORGANIC LETTERS

Ruthenium(II)-Catalyzed C–H Oxygenations of Reusable Sulfoximine Benzamides

(2017) Keshav Raghuvanshi et al.   ORGANIC LETTERS

Palladium-Catalyzed Enantioselective C(sp2)–H Imidoylation by Desymmetrization

(2017) Jian Wang et al.   ACS Catalysis

Ketene Aminal Phosphates: Competent Substrates for Enantioselective Pd(0)-Catalyzed C–H Functionalizations

(2017) Daria Grosheva et al.   ACS Catalysis

Rhodium(III)-Catalyzed Enantiotopic C−H Activation Enables Access to P -Chiral Cyclic Phosphinamides

(2016) Yang Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Hydroarylation and One-Pot Twofold Unsymmetrical C−H Functionalization of Arenes

(2016) Koushik Ghosh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Synthesis of Chiral Spiro-9-silabifluorenes by Dehydrogenative Silylation: Mechanistic Insights into the Construction of Tetraorganosilicon Stereocenters

(2016) Masahito Murai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed ortho -Amidations in the Preparation of Thiadiazine 1-Oxides

(2016) Ying Cheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organocatalytic Kinetic Resolution of Sulfoximines

(2016) Shunxi Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Catalysis Powered by Chiral Cyclopentadienyl Ligands

(2016) Christopher G. Newton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes

(2016) Jun Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 1,2-Benzothiazines by a Rhodium-Catalyzed Domino C–H Activation/Cyclization/Elimination Process from S-Aryl Sulfoximines and Pyridotriazoles

(2016) Woo Hyung Jeon et al.   ORGANIC LETTERS

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations

(2015) Baihua Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselectiveortho-CH Cross-Coupling of Diarylmethylamines with Organoborons

(2015) Brian N. Laforteza et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Enantioselective CH Arylation for the Synthesis of P-Stereogenic Compounds

(2015) Zi-Qi Lin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Syntheses of 1,2-Benzothiazines by Rhodium-Catalyzed Annulation Reactions

(2015) Ying Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium- and palladium-catalyzed consecutive coupling and cyclization of aromatic sulfoximines with phenylboronic acids: an efficient route to dibenzothiazines

(2015) Ravi Kiran Chinnagolla et al.   CHEMICAL COMMUNICATIONS

Sulfur imidations: access to sulfimides and sulfoximines

(2015) Vincent Bizet et al.   CHEMICAL SOCIETY REVIEWS

Pd(II)-Catalyzed Enantioselective Synthesis of P-Stereogenic Phosphinamides via Desymmetric C–H Arylation

(2015) Zhi-Jun Du et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Enantioselective Silylation of Arene C–H Bonds: Desymmetrization of Diarylmethanols

(2015) Taegyo Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of P-Stereogenic Phosphinic Amides via Pd(0)-Catalyzed Enantioselective Intramolecular C–H Arylation

(2015) Lantao Liu et al.   ORGANIC LETTERS

Dual role of carboxylic acid additive: mechanistic studies and implication for the asymmetric C–H amidation

(2015) Donghyeon Gwon et al.   TETRAHEDRON

Efficient synthesis of P-chiral biaryl phosphonates by stereoselective intramolecular cyclization

(2015) Guangqing Xu et al.   Organic Chemistry Frontiers

Fluorinated sulfoximines: syntheses, properties and applications

(2014) Vincent Bizet et al.   CHEMICAL SOCIETY REVIEWS

Hydroarylations of Heterobicyclic Alkenes through Rhodium-Catalyzed Directed CH Functionalizations of S-Aryl Sulfoximines

(2014) Wanrong Dong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Selectiveortho-Olefinations ofN-Acyl andN-Aroyl Sulfoximines by CH Bond Activation

(2014) Kanniyappan Parthasarathy et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sulfoximine-Directed Ruthenium-Catalyzed ortho-C–H Alkenylation of (Hetero)Arenes: Synthesis of EP3 Receptor Antagonist Analogue

(2014) M. Ramu Yadav et al.   JOURNAL OF ORGANIC CHEMISTRY

General synthetic strategies towards N-alkyl sulfoximine building blocks for medicinal chemistry and the use of dimethylsulfoximine as a versatile precursor

(2014) Frederick W. Goldberg et al.   TETRAHEDRON

Sulfoximines: A Neglected Opportunity in Medicinal Chemistry

(2013) Ulrich Lücking   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Oxidative Annulation of Sulfoximines and Alkynes as an Approach to 1,2-Benzothiazines

(2013) Wanrong Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Nitrene Transfer to Sulfides Catalyzed by a Chiral Iron Complex

(2013) Jun Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective CH Arylation Strategy for Functionalized Dibenzazepinones with Quaternary Stereocenters

(2013) Tanguy Saget et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Imidative Kinetic Resolution of Racemic Sulfoxides

(2013) Jun Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric C(sp2)H Activation

(2013) Joanna Wencel-Delord et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Tunable Class of Chiral Cp Ligands for Enantioselective Rhodium(III)-Catalyzed C–H Allylations of Benzamides

(2013) Baihua Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Enantioselective C–H Activation/C–O Bond Formation: Synthesis of Chiral Benzofuranones

(2013) Xiu-Fen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Enantioselective C–H Iodination: Asymmetric Synthesis of Chiral Diarylmethylamines

(2013) Ling Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sulfoximine Directed Intermolecular o-C–H Amidation of Arenes with Sulfonyl Azides

(2013) M. Ramu Yadav et al.   ORGANIC LETTERS

Recent development of direct asymmetric functionalization of inert C–H bonds

(2013) Chao Zheng et al.   RSC Advances

Rhodium-Catalyzed Asymmetric Synthesis of Spirosilabifluorene Derivatives

(2012) Yoichiro Kuninobu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sulfoximines: A Reusable Directing Group for Chemo- and Regioselective ortho CH Oxidation of Arenes

(2012) M. Ramu Yadav et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C–H Bond Functionalization

(2012) Ryo Shintani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

BAY 1000394, a Novel Cyclin-Dependent Kinase Inhibitor, with Potent Antitumor Activity in Mono- and in Combination Treatment upon Oral Application

(2012) G. Siemeister et al.   MOLECULAR CANCER THERAPEUTICS

Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization

(2012) B. Ye et al.   SCIENCE

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Novel nicotinic action of the sulfoximine insecticide sulfoxaflor

(2011) Gerald B. Watson et al.   INSECT BIOCHEMISTRY AND MOLECULAR BIOLOGY

Enantioselective Palladium-Catalyzed Direct Arylations at Ambient Temperature: Access to Indanes with Quaternary Stereocenters

(2009) Martin���R. Albicker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Escape from Flatland: Increasing Saturation as an Approach to Improving Clinical Success

(2009) Frank Lovering et al.   JOURNAL OF MEDICINAL CHEMISTRY

Pd(II)-Catalyzed Enantioselective C−H Olefination of Diphenylacetic Acids

(2009) Bing-Feng Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

PdII-Catalyzed Enantioselective Activation of C(sp2)H and C(sp3)H Bonds Using Monoprotected Amino Acids as Chiral Ligands

(2008) Bing-Feng Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Rhodium-Catalyzed Imination of Sulfides

(2008) Florence Collet et al.   ORGANIC LETTERS