Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reaction

Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes

(2016) Richard Y. Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese(I)-Catalyzed Substitutive C−H Allylation

(2016) Weiping Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild C−H/C−C Activation by Z -Selective Cobalt Catalysis

(2016) Daniel Zell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

DiverseN-Heterocyclic Ring Systems via Aza-Heck Cyclizations ofN-(Pentafluorobenzoyloxy)sulfonamides

(2016) Ian R. Hazelden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-catalyzed C–H olefination of aromatics with unactivated alkenes

(2016) Ramasamy Manoharan et al.   CHEMICAL COMMUNICATIONS

Cobalt-catalyzed chelation assisted C–H allylation of aromatic amides with unactivated olefins

(2016) Takuma Yamaguchi et al.   CHEMICAL COMMUNICATIONS

Cobalt-Catalyzed Oxidase C−H/N−H Alkyne Annulation: Mechanistic Insights and Access to Anticancer Agents

(2016) Ruhuai Mei et al.   CHEMISTRY-A EUROPEAN JOURNAL

Emergence of Unactivated Olefins for the Synthesis of Olefinated Arenes

(2016) Arghya Deb et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed, Site-Selective Direct Allylation of Aryl C–H Bonds by Silver-Mediated C–H Activation: A Synthetic and Mechanistic Investigation

(2016) Sarah Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Oxidative C–H Allylation of Benzamides with 1,3-Dienes by Allyl-to-Allyl 1,4-Rh(III) Migration

(2016) Stamatis E. Korkis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aerobic Linear Allylic C–H Amination: Overcoming Benzoquinone Inhibition

(2016) Christopher C. Pattillo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols To Form Allylic Quaternary Centers

(2016) Harshkumar H. Patel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heteroarene-Directed Oxidative sp2 C–H Bond Allylation with Aliphatic Alkenes Catalyzed by an (Electron-Deficient η5-Cyclopentadienyl)rhodium(III) Complex

(2016) Yuji Takahama et al.   ORGANIC LETTERS

Switch to Allylic Selectivity in Cobalt-Catalyzed Dehydrogenative Heck Reactions with Unbiased Aliphatic Olefins

(2016) Soham Maity et al.   ACS Catalysis

Rhodium(III)-Catalyzed Direct CH Olefination of Arenes with Aliphatic Olefins

(2015) Xiao Xue et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Asymmetric Reductive Heck Reaction of Aryl Halides

(2015) Guizhou Yue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dehydrative Direct CH Allylation with Allylic Alcohols under [Cp*CoIII] Catalysis

(2015) Yudai Suzuki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expedient Iron-Catalyzed C−H Allylation/Alkylation by Triazole Assistance with Ample Scope

(2015) Gianpiero Cera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Olefination of Anilides with Unactivated Alkenes Catalyzed by an (Electron-Deficient η5-Cyclopentadienyl)Rhodium(III) Complex Under Ambient Conditions

(2015) Yuji Takahama et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Allylation of Quinones with Allylboronates

(2015) Hong-Ping Deng et al.   JOURNAL OF ORGANIC CHEMISTRY

Cu(II)-Mediated C(sp2)–H Hydroxylation

(2015) Shang-Zheng Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Dehydrogenative Heck Arylations of Trisubstituted Alkenes with Indoles to Construct Quaternary Stereocenters

(2015) Chun Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Enantioselective Heck Alkenylation of Acyclic Alkenols Using a Redox-Relay Strategy

(2015) Harshkumar H. Patel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote para-C–H Functionalization of Arenes by a D-Shaped Biphenyl Template-Based Assembly

(2015) Sukdev Bag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt(III)-Catalyzed Directed C–H Allylation

(2015) Tobias Gensch et al.   ORGANIC LETTERS

Dearomatization of Indoles via Palladium-Catalyzed Allylic C–H Activation

(2015) Heng Zhang et al.   ORGANIC LETTERS

Cobalt-Catalyzed, Aminoquinoline-Directed C(sp2)H Bond Alkenylation by Alkynes

(2014) Liene Grigorjeva et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exceedingly Fast Copper(II)-Promotedortho CH Trifluoromethylation of Arenes using TMSCF3

(2014) Ming Shang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed aerobic oxidative allylic C–H arylation of alkenes with polyfluorobenzenes

(2014) Huanfeng Jiang et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Aryl C–H Olefination with Unactivated, Aliphatic Alkenes

(2014) Arghya Deb et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(II)-Mediated C–H Amidation and Amination of Arenes: Exceptional Compatibility with Heterocycles

(2014) Ming Shang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(II)-Mediated Ortho C–H Alkynylation of (Hetero)Arenes with Terminal Alkynes

(2014) Ming Shang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Intermolecular Heck Reaction of Aryl Halides

(2014) Chunlin Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Oxidative Olefination of Furans with Unactivated Alkenes

(2014) Christo S. Sevov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism, Reactivity, and Selectivity in Palladium-Catalyzed Redox-Relay Heck Arylations of Alkenyl Alcohols

(2014) Liping Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective construction of remote quaternary stereocentres

(2014) Tian-Sheng Mei et al.   NATURE

Cu(OAc)2-Catalyzed Coupling of Aromatic C–H Bonds with Arylboron Reagents

(2014) Ming Shang et al.   ORGANIC LETTERS

Nickel-Catalyzed C–H Coupling with Allyl Phosphates: A Site-Selective Synthetic Route to Linear Allylarenes

(2014) Xuefeng Cong et al.   ORGANIC LETTERS

Cobalt-Catalyzed, Aminoquinoline-Directed Coupling of sp2 C–H Bonds with Alkenes

(2014) Liene Grigorjeva et al.   ORGANIC LETTERS

Copper catalyzed Heck-like cyclizations of oxime esters

(2014) Adele Faulkner et al.   Chemical Science

Mild Rhodium(III)-Catalyzed Direct CH Allylation of Arenes with Allyl Carbonates

(2013) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Ortho-Allylation of Aromatic Carboxamides with Allyl Ethers

(2013) Sobi Asako et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Redox-Relay Oxidative Heck Arylations of Acyclic Alkenyl Alcohols using Boronic Acids

(2013) Tian-Sheng Mei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Narasaka-Heck Cyclizations Mediated by P(3,5-(CF3)2C6H3)3: Facile Access to N-Heterobicyclic Scaffolds

(2012) Adele Faulkner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Mizoroki-Heck Reaction of Aliphatic Olefins with High Selectivity for Substitution at the Internal Position

(2012) Liena Qin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Stereocontrolled Introduction of Secondary Alkyl Groups to Electron-Deficient Arenes through Copper-Catalyzed Allylic Alkylation

(2012) Yusuke Makida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed, Asymmetric Mizoroki–Heck Reaction of Benzylic Electrophiles Using Phosphoramidites as Chiral Ligands

(2012) Zhigang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst-Controlled Regioselectivity in the Synthesis of Branched Conjugated Dienes via Aerobic Oxidative Heck Reactions

(2012) Changwu Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed N-Nitroso-Directed C–H Olefination of Arenes. High-Yield, Versatile Coupling under Mild Conditions

(2012) Baoqing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of remote meta-C–H bonds assisted by an end-on template

(2012) Dasheng Leow et al.   NATURE

Enantioselective Heck Arylations of Acyclic Alkenyl Alcohols Using a Redox-Relay Strategy

(2012) E. W. Werner et al.   SCIENCE

Stereospecific Copper-Catalyzed CH Allylation of Electron-Deficient Arenes with Allyl Phosphates

(2011) Tomoyuki Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Evolution and Synthetic Applications of the Heck-Matsuda Reaction: The Return of Arenediazonium Salts to Prominence

(2011) Jason G. Taylor et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Pyridinyl Directed Alkenylation with Olefins via Rh(III)-Catalyzed C–C Bond Cleavage of Secondary Arylmethanols

(2011) Hu Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Heck-Type Reactions of Benzyl Chlorides and Simple Olefins

(2011) Ryosuke Matsubara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Operationally Simple and Highly (E)-Styrenyl-Selective Heck Reactions of Electronically Nonbiased Olefins

(2011) Erik W. Werner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Oxidative Olefination ofN-(1-Naphthyl)sulfonamides Using Activated and Unactivated Alkenes

(2011) Xuting Li et al.   ORGANIC LETTERS

Pd(II)-Catalyzed Hydroxyl-Directed C−H Olefination Enabled by Monoprotected Amino Acid Ligands

(2010) Yi Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Accelerated C−H Activation Reactions: Evidence for a Switch of Mechanism

(2010) Keary M. Engle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Selective and General Palladium Catalyst for the Oxidative Heck Reaction of Electronically Nonbiased Olefins

(2010) Erik W. Werner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C−H Activation

(2010) Andy S. Tsai et al.   ORGANIC LETTERS

Direct, ChemoselectiveN-tert-Prenylation of Indoles by CH Functionalization

(2009) Michael R. Luzung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-Enabled Reactivity and Selectivity in a Synthetically Versatile Aryl C-H Olefination

(2009) D.-H. Wang et al.   SCIENCE

A General and Highly Selective Chelate-Controlled Intermolecular Oxidative Heck Reaction

(2008) Jared H. Delcamp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrogenation of Inert Alkyl Groups via Remote C−H Activation: Converting a Propyl Group into a π-Allylic Complex

(2008) Ramesh Giri et al.   ORGANOMETALLICS