A Planar-Chiral Rhodium(III) Catalyst with a Sterically Demanding Cyclopentadienyl Ligand and Its Application in the Enantioselective Synthesis of Dihydroisoquinolones

Tailored trisubstituted chiral CpxRhIII catalysts for kinetic resolutions of phosphinic amides

(2018) Y. Sun et al.   Chemical Science

Synthesis of Intricate Fused N-Heterocycles via Ring-Rearrangement Metathesis

(2017) Sambasivarao Kotha et al.   JOURNAL OF ORGANIC CHEMISTRY

Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C–H Activation Reactions: An Experimental and Computational Study

(2017) Tiffany Piou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Nonnatural Helical Polypeptide via Asymmetric Polymerization and Reductive Cleavage of N–O Bond

(2017) Yuki Ishido et al.   MACROMOLECULES

Heptamethylindenyl (Ind*) enables diastereoselective benzamidation of cyclopropenes via Rh(iii)-catalyzed C–H activation

(2017) Natthawat Semakul et al.   Chemical Science

Rhodium(III)-Catalyzed Enantiotopic C−H Activation Enables Access to P -Chiral Cyclic Phosphinamides

(2016) Yang Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Simple and Versatile Amide Directing Group for C−H Functionalizations

(2016) Ru-Yi Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Catalysis Powered by Chiral Cyclopentadienyl Ligands

(2016) Christopher G. Newton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Conjugated Polycyclic Quinoliniums by Rhodium(III)-Catalyzed Multiple C–H Activation and Annulation of Arylpyridiniums with Alkynes

(2016) Qingmei Ge et al.   ORGANIC LETTERS

Cyclobutadiene Arene Complexes of Rhodium and Iridium

(2016) Nikita V. Shvydkiy et al.   ORGANOMETALLICS

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations

(2015) Baihua Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

Opportunity Knocks: Organic Chemistry for Fragment-Based Drug Discovery (FBDD)

(2015) Christopher W. Murray et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Spiroindenes by Enol-Directed Rhodium(III)-Catalyzed CH Functionalization and Spiroannulation

(2015) Suresh Reddy Chidipudi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

RhIII-Catalyzed CH Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection

(2015) Ju Hyun Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio- and diastereoselective asymmetric allylic alkylation catalyzed by a planar-chiral cyclopentadienyl ruthenium complex

(2015) Naoya Kanbayashi et al.   CHEMICAL COMMUNICATIONS

General Route to Cyclobutadiene Rhodium Complexes

(2015) Dmitry S. Perekalin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ligand design for Rh(iii)-catalyzed C–H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones

(2015) Todd K. Hyster et al.   Chemical Science

Construction of Axial Chirality by Rhodium-Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes

(2014) Jun Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-Controlled Regiodivergent Pathways of Rhodium(III)-Catalyzed Dihydroisoquinolone Synthesis: Experimental and Computational Studies of Different Cyclopentadienyl Ligands

(2014) Matthew D. Wodrich et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations

(2013) Lutz Ackermann   ACCOUNTS OF CHEMICAL RESEARCH

Benzohydroxamic acids as potent and selective anti-HCV agents

(2013) Maxim V. Kozlov et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Employing a robustness screen: rapid assessment of rhodium(III)-catalysed C–H activation reactions

(2013) Karl D. Collins et al.   TETRAHEDRON

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Half-sandwich organometallic complexes with stereogenic metal centres: Synthesis and characterization of diastereomeric [(ηn-ring)M(Aa)X] (Aa = α-amino carboxylate) compounds

(2012) Daniel Carmona et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C-H Activation

(2012) T. K. Hyster et al.   SCIENCE

Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization

(2012) B. Ye et al.   SCIENCE

RhCl3-Mediated Coupling Reactions of tert-Butyl Acetylene

(2012) Gregor Kiefer et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Catalytic [2+2+1] Cross-Cyclotrimerization of Silylacetylenes and Two Alkynyl Esters To Produce Substituted Silylfulvenes

(2011) Yu Shibata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

(2011) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

(2011) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

3D Pharmacophore Model-Assisted Discovery of Novel CDC7 Inhibitors

(2011) Mika Lindvall et al.   ACS Medicinal Chemistry Letters

Enantioselective Synthesis of Allylic Esters via Asymmetric Allylic Substitution with Metal Carboxylates Using Planar-Chiral Cyclopentadienyl Ruthenium Catalysts

(2010) Naoya Kanbayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemistry, Biology, and Medicinal Potential of Narciclasine and its Congeners

(2008) Alexander Kornienko et al.   CHEMICAL REVIEWS

Synthesis, Structure, and Reactivity of the Methoxy-Bridged Dimer [Cp∧Ru(μ-OMe)]2(Cp∧= η5-1-Methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl)

(2008) Barnali Dutta et al.   ORGANOMETALLICS