Journal
ORGANIC LETTERS
Volume 21, Issue 21, Pages 8842-8846Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03484
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Funding
- SERB-India [CRG/2018/003915]
- Lombardy Region, Italy
- Cariplo Foundation, Italy
- J. C. Bose Fellowship (SERB, DST-India)
- UGC-India
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Unactivated olefins usually react poorly in conventional alkenylation reactions. Their introduction via C-H activation is limited to aromatic acids. Herein, we disclose a C-H functionalization protocol of aromatic amines with unactivated olefins, which shows exclusive allylic selectivity for the distal ring of the biphenyl system by exploiting a readily available cobalt(II) catalyst. The allylation proceeds smoothly involving a broad set of unbiased olefins and biaryls, giving access to the functionalization of the biphenyl scaffold.
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