Metal-free borylation of electron-rich aryl (pseudo)halides under continuous-flow photolytic conditions

Synthesis of aryl trimethylstannanes from aryl halides: an efficient photochemical method

(2016) Kai Chen et al.   CHEMICAL COMMUNICATIONS

Applications of Continuous-Flow Photochemistry in Organic Synthesis, Material Science, and Water Treatment

(2016) Dario Cambié et al.   CHEMICAL REVIEWS

Scalable, Metal- and Additive-Free, Photoinduced Borylation of Haloarenes and Quaternary Arylammonium Salts

(2016) Adelphe M. Mfuh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient metal-free photochemical borylation of aryl halides under batch and continuous-flow conditions

(2016) Kai Chen et al.   Chemical Science

Copper-Catalyzed Boron-Selective C(sp2)–C(sp3) Oxidative Cross-Coupling of Arylboronic Acids and Alkyltrifluoroborates Involving a Single-Electron Transmetalation Process

(2016) Siyi Ding et al.   ACS Catalysis

A mild carbon–boron bond formation from diaryliodonium salts

(2015) N. Miralles et al.   CHEMICAL COMMUNICATIONS

Direct introduction of a naphthalene-1,8-diamino boryl [B(dan)] group by a Pd-catalysed selective boryl transfer reaction

(2015) Liang Xu et al.   CHEMICAL COMMUNICATIONS

sp2–sp3 diboranes: astounding structural variability and mild sources of nucleophilic boron for organic synthesis

(2015) Rian D. Dewhurst et al.   CHEMICAL COMMUNICATIONS

Boron-selective reactions as powerful tools for modular synthesis of diverse complex molecules

(2015) Liang Xu et al.   CHEMICAL SOCIETY REVIEWS

Synthesis, Structure, and Reactivity of Anionic sp2-sp3Diboron Compounds: Readily Accessible Boryl Nucleophiles

(2015) Sabrina Pietsch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Borylation of Aryl- and Benzyltrimethylammonium Salts via C–N Bond Cleavage

(2015) Jiefeng Hu et al.   JOURNAL OF ORGANIC CHEMISTRY

Reaction Mechanism of the Anomalous Formal Nucleophilic Borylation of Organic Halides with Silylborane: Combined Theoretical and Experimental Studies

(2015) Ryohei Uematsu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed C–H Borylation of Arenes

(2015) Thomas Dombray et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Double N,B-Type Bidentate Boryl Ligands Enabling a Highly Active Iridium Catalyst for C–H Borylation

(2015) Guanghui Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Borylation of Aryl Fluorides via C–F Cleavage

(2015) Xiang-Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A leap ahead for activating C-H bonds

(2015) S. K. Bose et al.   SCIENCE

Metal-free catalytic C-H bond activation and borylation of heteroarenes

(2015) M.-A. Legare et al.   SCIENCE

Boryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides with silylborane and an alkoxy base: expanded scope and mechanistic studies

(2015) Eiji Yamamoto et al.   Chemical Science

Site-Differentiated Polyboron Arenes Prepared by Direct CH Borylation and Their Highly Selective Suzuki-Miyaura Cross-Coupling Reactions

(2014) Liang Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Borylation of Primary CH Bonds in Functionalized Molecules by Palladium Catalysis

(2014) Li-Sheng Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functional group directed C–H borylation

(2014) A. Ros et al.   CHEMICAL SOCIETY REVIEWS

Synergistic Effects of Lewis Bases and Substituents on the Electronic Structure and Reactivity of Boryl Radicals

(2014) Dongmei Lu et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Easy Route to (Hetero)arylboronic Acids

(2014) William Erb et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt-Catalyzed C–H Borylation

(2014) Jennifer V. Obligacion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Application of Cooperative Iron/Copper Catalysis to a Palladium-Free Borylation of Aryl Bromides with Pinacolborane

(2014) Flavien Labre et al.   ORGANIC LETTERS

3-Center-5-Electron Boryl Radicals with σ0π1 Ground State Electronic Structure

(2014) Dongmei Lu et al.   ORGANIC LETTERS

Peptide Fragment Coupling Using a Continuous-Flow Photochemical Rearrangement of Nitrones

(2013) Yuan Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Complexity from Simplicity: Tricyclic Aziridines from the Rearrangement of Pyrroles by Batch and Flow Photochemistry

(2013) Katie G. Maskill et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Mild, One-Pot Stadler-Ziegler Synthesis of Arylsulfides Facilitated by Photoredox Catalysis in Batch and Continuous-Flow

(2013) Xiao Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Microfluidic System for the Continuous Recycling of Unmodified Homogeneous Palladium Catalysts through Liquid/Liquid Phase Separation

(2013) Pengfei Li et al.   ChemCatChem

Selection of boron reagents for Suzuki–Miyaura coupling

(2013) Alastair J. J. Lennox et al.   CHEMICAL SOCIETY REVIEWS

Cesium Carbonate Mediated Borylation of Aryl Iodides with Diboron in Methanol

(2013) Jieming Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Transition-Metal-Free Arylations via Photogenerated Triplet 4-Alkyl- and 4-Trimethylsilylphenyl Cations

(2013) Hisham Qrareya et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Borylation of Halides and Pseudohalides with Tetrahydroxydiboron [B2(OH)4]

(2013) Gary A. Molander et al.   JOURNAL OF ORGANIC CHEMISTRY

Design, Generation, and Synthetic Application of Borylzincate: Borylation of Aryl Halides and Borylzincation of Benzynes/Terminal Alkyne

(2013) Yuki Nagashima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Base Metal Catalysts for Photochemical C–H Borylation That Utilize Metal–Metal Cooperativity

(2013) Thomas J. Mazzacano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free, Visible Light-Induced Borylation of Aryldiazonium Salts: A Simple and Green Synthetic Route to Arylboronates

(2012) Jian Yu et al.   ADVANCED SYNTHESIS & CATALYSIS

An Efficient Flow-Photochemical Synthesis of 5H-Furanones Leads to an Understanding of Torquoselectivity in Cyclobutenone Rearrangements

(2012) David C. Harrowven et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Photoflow Reactor for the Continuous Photoredox-Mediated Synthesis ofC-Glycoamino Acids andC-Glycolipids

(2012) R. Stephen Andrews et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Continuous-Flow Synthesis of the Anti-Malaria Drug Artemisinin

(2012) François Lévesque et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light Photoredox Catalysis in Flow

(2012) Joseph W. Tucker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Photochemical Route to 2-Substituted Benzo[b]furans

(2012) Stefano Protti et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Pinacol Arylboronates from Aromatic Amines: A Metal-Free Transformation

(2012) Di Qiu et al.   JOURNAL OF ORGANIC CHEMISTRY

Anomalous Reactivity of Silylborane: Transition-Metal-Free Boryl Substitution of Aryl, Alkenyl, and Alkyl Halides with Silylborane/Alkoxy Base Systems

(2012) Eiji Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope of the Palladium-Catalyzed Aryl Borylation Utilizing Bis-Boronic Acid

(2012) Gary A. Molander et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies into Amine-Mediated Electrophilic Arene Borylation and Its Application in MIDA Boronate Synthesis

(2012) Viktor Bagutski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed, Substrate-Directed C–H Borylation Reactions of Benzylic Amines

(2012) Andrew J. Roering et al.   ORGANIC LETTERS

Metal-Free Ortho C–H Borylation of 2-Phenoxypyridines under Mild Conditions

(2012) Liting Niu et al.   ORGANIC LETTERS

Transition-Metal-Free Borylation of Aryltriazene Mediated by BF3·OEt2

(2012) Chuan Zhu et al.   ORGANIC LETTERS

Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

(2011) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-Catalyzed Borylation of Sterically Demanding Aryl Halides with a Silica-Supported Compact Phosphane Ligand

(2011) Soichiro Kawamorita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Continuous-Flow Synthesis of 3,3-Disubstituted Oxindoles by a Palladium-Catalyzed α-Arylation/Alkylation Sequence

(2011) Pengfei Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Boronium Ion with Exceptional Electrophilicity

(2011) Aleksandrs Prokofjevs et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-Catalyzed Oxidative ortho-C–H Borylation of Arenes

(2011) Hui-Xiong Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NiCl2(PMe3)2-Catalyzed Borylation of Aryl Chlorides

(2011) Tetsuya Yamamoto et al.   ORGANIC LETTERS

Direct Conversion of Arylamines to Pinacol Boronates: A Metal-Free Borylation Process

(2010) Fanyang Mo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Borylation of Aryl and Alkenyl Carbamates through Ni-Catalyzed CO Activation

(2010) Kun Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Neopentylglycolborylation of Aryl Mesylates and Tosylates Catalyzed by Ni-Based Mixed-Ligand Systems Activated with Zn

(2010) Daniela A. Wilson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiomerically Puretrans-β-Lactams from α-Amino Acids via Compact Fluorescent Light (CFL) Continuous-Flow Photolysis

(2010) Yvette S. Mimieux Vaske et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed, Direct Boronic Acid Synthesis from Aryl Chlorides: A Simplified Route to Diverse Boronate Ester Derivatives

(2010) Gary A. Molander et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

(2009) Christian Kleeberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Eco-friendly hydrodehalogenation of electron-rich aryl chlorides and fluorides by photochemical reaction

(2009) Valentina Dichiarante et al.   GREEN CHEMISTRY

Directed Ortho Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine−Iridium System

(2009) Soichiro Kawamorita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A General Palladium-Catalyzed Suzuki-Miyaura Coupling of Aryl Mesylates

(2008) Chau Ming So et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoinduced Three-Component Reaction: A Convenient Access to 3-Arylacetals or 3-Arylketals

(2008) Simone Lazzaroni et al.   ORGANIC LETTERS