A Highly Reactive Rhodium(I)-Boryl Complex as a Useful Tool for CH Bond Activation and Catalytic CF Bond Borylation

Metallophosphoranes: The hidden face of transition metal–phosphine complexes

(2010) Jenni Goodman et al.   COORDINATION CHEMISTRY REVIEWS

Niobium-Catalyzed Activation of Aryl Trifluoromethyl Groups and Functionalization of CH Bonds: An Efficient and Convergent Approach to the Synthesis of N-Heterocycles

(2009) Tom G. Driver   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expedient Synthesis of N-Fused Indoles: A CF Activation and CH Insertion Approach

(2009) Kohei Fuchibe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic CF Activation and Hydrodefluorination of Fluoroalkyl Groups

(2009) Gregor Meier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CF Activation at Rhodium Boryl Complexes: Formation of 2-Fluoroalkyl-1,3,2-Dioxaborolanes by Catalytic Functionalization of Hexafluoropropene

(2009) Thomas Braun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Facile Route to Aryl Boronates: Room-Temperature, Copper-Catalyzed Borylation of Aryl Halides with Alkoxy Diboron Reagents

(2009) Christian Kleeberg et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boryl ligands and their roles in metal-catalysed borylation reactions

(2009) Li Dang et al.   CHEMICAL COMMUNICATIONS

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Activation of ethylene and ammonia at iridium: C–H versus N–H oxidative addition

(2009) Marcel Ahijado Salomon et al.   DALTON TRANSACTIONS

Synthesis and structure of indenyl rhodium(I) complexes containing unsaturated phosphines: catalyst precursors for alkene hydroboration

(2009) Christian N. Garon et al.   DALTON TRANSACTIONS

Hydrometalation of fluoroallenes

(2009) Moritz F. Kühnel et al.   DALTON TRANSACTIONS

Facile entry to 3d late transition metal boryl complexes

(2009) Ba L. Tran et al.   DALTON TRANSACTIONS

Conversion of Carbon-Fluorine Bonds α to Transition Metal Centers to Carbon-Hydrogen, Carbon-Carbon, and Carbon-Heteroatom Bonds

(2009) Russell P. Hughes   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Combined Experimental and Computational Study of Unexpected C−F Bond Activation Intermediates and Selectivity in the Reaction of Pentafluorobenzene with a (PEt3)2Ni Synthon

(2009) Samuel A. Johnson et al.   ORGANOMETALLICS

Rhodium Derivatives of Peroxoboronic Acids and Peroxoboric Acid: Formation of Metallatrioxaborolanes from an η2-Peroxo Complex

(2008) Marcel Ahijado et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stepwise Oxygenation of Pinacolborane by a Rhodiumperoxo Complex: Detection of an Intermediate Metal Borate and Perborate

(2008) Marcel Ahijado Salomon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylation of Organoboronic Esters Catalyzed by N‐Heterocyclic Carbene Copper(I) Complexes

(2008) Takeshi Ohishi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium catalysed dehydrogenative borylation of alkenes: Vinylboronates via C–H activation

(2008) Ibraheem A. I. Mkhalid et al.   DALTON TRANSACTIONS

Iridium derivatives of fluorinated aromatics by C–H activation: isolation of classical and non-classical hydrides

(2008) Marcel Ahijado Salomon et al.   DALTON TRANSACTIONS

Rhodium-Catalyzed Substitution Reaction of Aryl Fluorides with Disulfides:p-Orientation in the Polyarylthiolation of Polyfluorobenzenes

(2008) Mieko Arisawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−F Activation of Fluorinated Arenes using NHC-Stabilized Nickel(0) Complexes: Selectivity and Mechanistic Investigations

(2008) Thomas Schaub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

DFT Studies on the Mechanism of the Diboration of Aldehydes Catalyzed by Copper(I) Boryl Complexes

(2008) Haitao Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational Study of the Reaction of C6F6with [IrMe(PEt3)3]: Identification of a Phosphine-Assisted C−F Activation Pathway via a Metallophosphorane Intermediate

(2008) Stefan Erhardt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Competing C−F Activation Pathways in the Reaction of Pt(0) with Fluoropyridines: Phosphine-Assistance versus Oxidative Addition

(2008) Ainara Nova et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Bond Activation by Rhodium(I) Phenoxide and Acetate Complexes: Mechanism of H−D Exchange between Arenes and Water

(2008) Susan Kloek Hanson et al.   ORGANOMETALLICS

Insight into the Mechanism of Platinum-Catalyzed Cross-Coupling of Polyfluoroaryl Imines

(2008) Tongen Wang et al.   ORGANOMETALLICS

DFT Studies on the Borylation of α,β-Unsaturated Carbonyl Compounds Catalyzed by Phosphine Copper(I) Boryl Complexes and Observations on the Interconversions between O- and C-Bound Enolates of Cu, B, and Si

(2008) Li Dang et al.   ORGANOMETALLICS

4,4,5,5-Tetraphenyl-1,3,2-dioxaborolane: A Bulky Borane for the Transition Metal Catalysed Hydroboration of Alkenes

(2007) Claudia B. Fritschi et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

[(tBu2PCH2SiMe2)2N]RhI? Rapidly Reversible H−C(sp3) and H−C(sp2) Bond Cleavage by Rhodium(I)

(2007) Alexander Y. Verat et al.   ORGANOMETALLICS