Journal
ACS CATALYSIS
Volume 7, Issue 6, Pages 4209-4213Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.7b01208
Keywords
amino acids; C-H activation; imines; manganese; perfluoroalkenes
Categories
Funding
- European Research Council under the European Community [307535]
- DAAD
- DFG [SPP 1807]
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C-F/C-H functionalizations proved to be viable within a versatile manganese(I) catalysis manifold. Thus, a wealth of fluorinated alkenes were employed in C-F/C-H functionalizations through facile C-H activation. The robust nature of the manganese(I) catalysis regime was among others reflected by the first C-F/C-H activation with perfluoroalkenes as well as racemization-free C-H functionalizations on imines, amino acids, and peptides.
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