Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes

Friedel-Crafts-Type Intermolecular C−H Silylation of Electron-Rich Arenes Initiated by Base-Metal Salts

(2016) Qin Yin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Acid Assisted Nickel-Catalyzed Cross-Coupling of Aryl Methyl Ethers by C−O Bond-Cleaving Alkylation: Prevention of Undesired β-Hydride Elimination

(2016) Xiangqian Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Activation of Acyl C−O Bonds of Methyl Esters

(2016) Liana Hie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Csp2–Csp3 Cross-Coupling via C–O Bond Activation

(2016) Lin Guo et al.   ACS Catalysis

Nickel catalyzed dealkoxylative Csp2–Csp3 cross coupling reactions – stereospecific synthesis of allylsilanes from enol ethers

(2015) Lin Guo et al.   CHEMICAL COMMUNICATIONS

Catalytic Silylation of Unactivated C–H Bonds

(2015) Chen Cheng et al.   CHEMICAL REVIEWS

Iridium-Catalyzed Intermolecular Dehydrogenative Silylation of Polycyclic Aromatic Compounds without Directing Groups

(2015) Masahito Murai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selective Silylative Reduction of Pyridines Leading to Structurally Diverse Azacyclic Compounds with the Formation of sp3 C–Si Bonds

(2015) Narasimhulu Gandhamsetty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Highly Substituted Racemic and Enantioenriched Allenylsilanes via Copper-Catalyzed Hydrosilylation of (Z)-2-Alken-4-ynoates with Silylboronate

(2015) Min Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni/Cu-Catalyzed Defluoroborylation of Fluoroarenes for Diverse C–F Bond Functionalizations

(2015) Takashi Niwa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Oxalyl Amide Directed Silylation and Germanylation of Amine Derivatives

(2015) Changpeng Chen et al.   ORGANIC LETTERS

Decarbonylative organoboron cross-coupling of esters by nickel catalysis

(2015) Kei Muto et al.   Nature Communications

Nickel-Catalyzed Direct Alkylation of Terminal Alkynes at Room Temperature: A Hemilabile Pincer Ligand Enhances Catalytic Activity

(2015) Pablo M. Pérez García et al.   ACS Catalysis

Metal catalyzed cross-coupling of aryl and benzyl methyl sulfides: nickel catalyzed Caryl–Csp3 and Csp3–Csp3 bond formations

(2015) Matthias Leiendecker et al.   Organic Chemistry Frontiers

Metal-Catalyzed Dealkoxylative CarylC sp 3 Cross-Coupling-Replacement of Aromatic Methoxy Groups of Aryl Ethers by Employing a Functionalized Nucleophile

(2014) Matthias Leiendecker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Study of Chemoselectivity in Ni-Catalyzed Coupling Reactions between Azoles and Aryl Carboxylates

(2014) Qianqian Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Mild Ni/Cu-Catalyzed Silylation via C–O Cleavage

(2014) Cayetana Zarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanisms and Origins of Switchable Chemoselectivity of Ni-Catalyzed C(aryl)–O and C(acyl)–O Activation of Aryl Esters with Phosphine Ligands

(2014) Xin Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Intermolecular C-H Silylation of Arenes with High Steric Regiocontrol

(2014) C. Cheng et al.   SCIENCE

Nickel-Catalyzed Sonogashira Reactions of Non-activated Secondary Alkyl Bromides and Iodides

(2013) Jun Yi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Addition of Nucleophilic Silicon to Aldehydes

(2013) Virginie Cirriez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Bis(silylene) and Bis(germylene) Pincer-Type Nickel(II) Complexes to Isolable Intermediates of the Nickel-Catalyzed Sonogashira Cross-Coupling Reaction

(2013) Daniel Gallego et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of Allyl and Vinyl Silanes by the Palladium-Catalyzed Silylation of Terminal Olefins: A Silyl-Heck Reaction

(2012) Jesse R. McAtee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Organosilicon Molecules with Medicinal Applications

(2012) Annaliese K. Franz et al.   JOURNAL OF MEDICINAL CHEMISTRY

Decarbonylative C–H Coupling of Azoles and Aryl Esters: Unprecedented Nickel Catalysis and Application to the Synthesis of Muscoride A

(2012) Kazuma Amaike et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silicon-based cross-coupling reaction: an environmentally benign version

(2011) Yoshiaki Nakao et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed 1,2-Addition of Nucleophilic Silicon to Aldehydes: Mechanistic Insight and Catalytic Systems

(2011) Christian Kleeberg et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Highly Regioselective Silylcupration of Terminal Alkynes to Form α-Vinylsilanes

(2011) Peng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of the Si−B Linkage: Copper-Catalyzed Addition of Nucleophilic Silicon to Imines

(2011) Devendra J. Vyas et al.   ORGANIC LETTERS

The Nickel/Copper-Catalyzed Direct Alkylation of Heterocyclic CH Bonds

(2010) Oleg Vechorkin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silicon-Based Cross-Coupling Reactions in the Total Synthesis of Natural Products

(2010) Scott E. Denmark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes

(2010) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silylboranes as New Tools in Organic Synthesis

(2009) Toshimichi Ohmura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides: Orthogonal Functionalization of Alkyl Iodides, Bromides, and Chlorides

(2009) Oleg Vechorkin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric CSi Bond Formation to Acyclic α,β-Unsaturated Acceptors by RhI-Catalyzed Conjugate Silyl Transfer Using a SiB Linkage

(2008) Christian Walter et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Iridium-Catalyzed CH Functionalization/Silylation of Heteroarenes

(2008) Biao Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Silylation of Electron-Deficient Aryl Iodides Using Triorganosilane in the Presence of Pyridine and LiCl

(2008) Muneaki Iizuka et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct and Selective Arylation of Tertiary Silanes with Rhodium Catalyst

(2008) Yoshinori Yamanoi et al.   JOURNAL OF ORGANIC CHEMISTRY