Transition metal-catalysed couplings between arenes and strained or reactive rings: combination of C–H activation and ring scission

Mild C−H/C−C Activation by Z -Selective Cobalt Catalysis

(2016) Daniel Zell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp3)−H and C(sp2)−H under Rhodium(III) Catalysis

(2016) Songjie Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cp*CoIII-Catalyzed C(sp3)−H Bond Amidation of 8-Methylquinoline

(2016) Nagaraju Barsu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Co(III)-Catalyzed Synthesis of Quinazolines via C–H Activation of N-Sulfinylimines and Benzimidates

(2016) Fen Wang et al.   ORGANIC LETTERS

Access to Structurally Diverse Quinoline-Fused Heterocycles via Rhodium(III)-Catalyzed C–C/C–N Coupling of Bifunctional Substrates

(2016) Songjie Yu et al.   ORGANIC LETTERS

Synthesis of 1,2-Benzothiazines by a Rhodium-Catalyzed Domino C–H Activation/Cyclization/Elimination Process from S-Aryl Sulfoximines and Pyridotriazoles

(2016) Woo Hyung Jeon et al.   ORGANIC LETTERS

Oxazolinyl-Assisted C–H Amidation by Cobalt(III) Catalysis

(2016) Ruhuai Mei et al.   ACS Catalysis

Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

(2015) Guoyong Song et al.   ACCOUNTS OF CHEMICAL RESEARCH

RhIII-Catalyzed CH Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection

(2015) Ju Hyun Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Comparative Catalytic Activity of Group 9 [Cp*MIII] Complexes: Cobalt-Catalyzed CH Amidation of Arenes with Dioxazolones as Amidating Reagents

(2015) Juhyeon Park et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Amidation of Unactivated C(sp3)H Bonds

(2015) He Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A rhodium(i)-catalysed formal intramolecular C–C/C–H bond metathesis

(2015) Takanori Matsuda et al.   CHEMICAL COMMUNICATIONS

Rhodium(iii)-catalyzed C–H/C–C activation sequence: vinylcyclopropanes as versatile synthons in direct C–H allylation reactions

(2015) Jia-Qiang Wu et al.   CHEMICAL COMMUNICATIONS

Cationic Cobalt(III)-Catalyzed Aryl and Alkenyl CH Amidation: A Mild Protocol for the Modification of Purine Derivatives

(2015) Yujie Liang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic Understanding of the Divergent Reactivity of Cyclopropenes in Rh(III)-Catalyzed C–H Activation/Cycloaddition Reactions of N-Phenoxyacetamide and N-Pivaloxybenzamide

(2015) Wei Guo et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Oxirane-Opening Reaction with Arenes via C–H Bond Activation

(2015) Zhen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies on the Rh(III)-Mediated Amido Transfer Process Leading to Robust C–H Amination with a New Type of Amidating Reagent

(2015) Yoonsu Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Formation of α-Aryl Ketones by C–H Functionalization with Cyclic Alkenyl Carbonates and One-Pot Synthesis of Isocoumarins

(2015) Yusuke Hara et al.   ORGANIC LETTERS

Mechanistic Understanding of the Aryl-Dependent Ring Formations in Rh(III)-Catalyzed C–H Activation/Cycloaddition of Benzamides and Methylenecyclopropanes by DFT Calculations

(2015) Wei Guo et al.   ORGANOMETALLICS

Rhodium(III)-Catalyzed Coupling of Arenes with Cyclopropanols via C–H Activation and Ring Opening

(2015) Xukai Zhou et al.   ACS Catalysis

Rhodium(III)-Catalyzed Direct Coupling of Arylphosphine Derivatives with Heterobicyclic Alkenes: A Concise Route to Biarylphosphines and Dibenzophosphole Derivatives

(2015) Yuto Unoh et al.   ACS Catalysis

Ruthenium-Catalyzed Hydroarylations of Oxa- and Azabicyclic Alkenes

(2015) Hanchao Cheng et al.   ACS Catalysis

Cobalt-Catalyzedortho-CH Alkylation of 2-ArylpyridinesviaRing-Opening of Aziridines

(2014) Ke Gao et al.   ADVANCED SYNTHESIS & CATALYSIS

α-MsO/TsO/Cl Ketones as Oxidized Alkyne Equivalents: Redox-Neutral Rhodium(III)-Catalyzed CH Activation for the Synthesis of N-Heterocycles

(2014) Da-Gang Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Transannulation of Cyclopropenes withN-Phenoxyacetamides through CH Activation

(2014) Hang Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Small Heterocycles in Multicomponent Reactions

(2014) Benjamin H. Rotstein et al.   CHEMICAL REVIEWS

Hydroarylations of Heterobicyclic Alkenes through Rhodium-Catalyzed Directed CH Functionalizations of S-Aryl Sulfoximines

(2014) Wanrong Dong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mild Synthesis of Chalcones via Rhodium(III)-Catalyzed C–C Coupling of Arenes and Cyclopropenones

(2014) Songjie Yu et al.   ORGANIC LETTERS

Mild Rhodium(III)-Catalyzed C–H Allylation with 4-Vinyl-1,3-dioxolan-2-ones: Direct and Stereoselective Synthesis of (E)-Allylic Alcohols

(2014) Shang-Shi Zhang et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed C–C Coupling of Arenes with 2-Vinyloxiranes: Synthesis of Allylic Alcohols

(2014) Songjie Yu et al.   ORGANIC LETTERS

Gold-Catalyzed Tandem Reactions of Methylenecyclopropanes and Vinylidenecyclopropanes

(2013) Di-Han Zhang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium(III)-Catalyzed CC Coupling between Arenes and Aziridines by CH Activation

(2013) Xingwei Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Coupling of Arenes with 7-Oxa/Azabenzonorbornadienes by CH Activation

(2013) Zisong Qi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium catalyzed oxidative coupling of salicylaldehydes with diazabicyclic olefins: a one pot strategy involving aldehyde C–H cleavage and π-allyl chemistry towards the synthesis of fused ring chromanones

(2013) E. Jijy et al.   CHEMICAL COMMUNICATIONS

Rh(iii)-catalyzed C–H activation/cycloaddition of benzamides and methylenecyclopropanes: divergence in ring formation

(2013) Sunliang Cui et al.   Chemical Science

Rh(iii)-catalyzed C–H activation–desymmetrization of diazabicycles with arenes: facile synthesis of functionalized cyclopentenes

(2013) Yan Zhang et al.   Chemical Science

Double 1,4-rhodium migration cascade in rhodium-catalysed arylative ring-opening/spirocyclisation of (3-arylcyclobutylidene)acetates

(2012) Takanori Matsuda et al.   CHEMICAL COMMUNICATIONS

Ruthenium-Catalyzed Hydroarylation of Methylenecyclopropanes through CH Bond Cleavage: Scope and Mechanism

(2012) Lutz Ackermann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rapid Generation of Molecular Complexity in the Lewis or Brønsted Acid-Mediated Reactions of Methylenecyclopropanes

(2011) Min Shi et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cyclobutanes in Catalysis

(2011) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of α-indanones via intramolecular direct arylation with cyclopropanol-derived homoenolates

(2011) David Rosa et al.   CHEMICAL COMMUNICATIONS

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

(2011) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

New Reactivity of Oxaziridine: Pd(II)-Catalyzed Aromatic C–H Ethoxycarbonylation via C–C Bond Cleavage

(2011) Xingao Peng et al.   ORGANIC LETTERS

Enantioselective Synthesis of Indanols from tert-Cyclobutanols Using a Rhodium-Catalyzed CC/CH Activation Sequence

(2009) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Stereoselective Restructuring of 3-Arylcyclobutanols into 1-Indanols by Sequential Breaking and Formation of Carbon–Carbon Bonds

(2009) Masanori Shigeno et al.   CHEMISTRY-A EUROPEAN JOURNAL