The mechanism of copper-catalyzed oxytrifluoromethylation of allylamines with CO2: a computational study
Published 2018 View Full Article
- Home
- Publications
- Publication Search
- Publication Details
Title
The mechanism of copper-catalyzed oxytrifluoromethylation of allylamines with CO2: a computational study
Authors
Keywords
-
Journal
Organic Chemistry Frontiers
Volume 5, Issue 4, Pages 633-639
Publisher
Royal Society of Chemistry (RSC)
Online
2017-11-07
DOI
10.1039/c7qo00838d
References
Ask authors/readers for more resources
Related references
Note: Only part of the references are listed.- Asymmetric Cu-Catalyzed Intermolecular Trifluoromethylarylation of Styrenes: Enantioselective Arylation of Benzylic Radicals
- (2017) Lianqian Wu et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Asymmetric silver-catalysed intermolecular bromotrifluoromethoxylation of alkenes with a new trifluoromethoxylation reagent
- (2017) Shuo Guo et al. Nature Chemistry
- Metathesis Mechanism of Zinc-Catalyzed Fluorination of Alkenes with Hypervalent Fluoroiodine
- (2017) Jiji Zhang et al. ACS Catalysis
- Stabilization of Two Radicals with One Metal: A Stepwise Coupling Model for Copper-Catalyzed Radical–Radical Cross-Coupling
- (2017) Xiaotian Qi et al. Scientific Reports
- Selective Oxytrifluoromethylation of Allylamines with CO2
- (2016) Jian-Heng Ye et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Why does Togni's reagent I exist in the high-energy hypervalent iodine form? Re-evaluation of benziodoxole based hypervalent iodine reagents
- (2016) Tian-Yu Sun et al. CHEMICAL COMMUNICATIONS
- Catalyst-free direct C–H trifluoromethylation of arenes in water–acetonitrile
- (2016) Dangui Wang et al. GREEN CHEMISTRY
- A Dual-Catalytic Strategy To Direct Asymmetric Radical Aminotrifluoromethylation of Alkenes
- (2016) Jin-Shun Lin et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Mechanism of Silver-Mediated Geminal Difluorination of Styrenes with a Fluoroiodane Reagent: Insights into Lewis-Acid-Activation Model
- (2016) Biying Zhou et al. ORGANIC LETTERS
- Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation
- (2016) Xiao-Qiang Hu et al. Nature Communications
- Isolation and Reactivity of Trifluoromethyl Iodonium Salts
- (2016) Johnathan N. Brantley et al. ACS Central Science
- Phosphine-Catalyzed Remote β-CH Functionalization of Amines Triggered by Trifluoromethylation of Alkenes: One-Pot Synthesis of Bistrifluoromethylated Enamides and Oxazoles
- (2015) Peng Yu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Copper-Catalyzed Radical/Radical C sp 3H/PH Cross-Coupling: α-Phosphorylation of Aryl KetoneO-Acetyloximes
- (2015) Jie Ke et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Efficient Cu-catalyzed Atom Transfer Radical Addition Reactions of Fluoroalkylsulfonyl Chlorides with Electron-deficient Alkenes Induced by Visible Light
- (2015) Xiao-Jun Tang et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Copper-catalyzed oxidative C(sp3)–H/N–H coupling of sulfoximines and amides with simple alkanes via a radical process
- (2015) Fan Teng et al. CHEMICAL COMMUNICATIONS
- Tuning radical reactivity using iodine in oxidative C(sp3)–H/C(sp)–H cross-coupling: an easy way toward the synthesis of furans and indolizines
- (2015) Shan Tang et al. CHEMICAL COMMUNICATIONS
- Sandmeyer-Type Trifluoromethylthiolation and Trifluoromethylselenolation of (Hetero)Aromatic Amines Catalyzed by Copper
- (2015) Christian Matheis et al. CHEMISTRY-A EUROPEAN JOURNAL
- (2 + 2) Cycloaddition of Benzyne to Endohedral Metallofullerenes M3N@C80 (M = Sc, Y): A Rotating-Intermediate Mechanism
- (2015) Tao Yang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Copper-Catalyzed Intermolecular Trifluoromethylazidation and Trifluoromethylthiocyanation of Allenes: Efficient Access to CF3-Containing Allyl Azides and Thiocyanates
- (2015) Na Zhu et al. ORGANIC LETTERS
- General Reaction Mode of Hypervalent Iodine Trifluoromethylation Reagent: A Density Functional Theory Study
- (2015) Lin Ling et al. ACS Catalysis
- Tuning the Reactivity of Radical through a Triplet Diradical Cu(II) Intermediate in Radical Oxidative Cross-Coupling
- (2015) Liangliang Zhou et al. Scientific Reports
- Copper-catalyzed aerobic oxidative coupling: From ketone and diamine to pyrazine
- (2015) K. Wu et al. Science Advances
- Recent Advances of Transition-Metal Catalyzed Radical Oxidative Cross-Couplings
- (2014) Chao Liu et al. ACCOUNTS OF CHEMICAL RESEARCH
- Trifluoromethylation of Alkenes with Concomitant Introduction of Additional Functional Groups
- (2014) Hiromichi Egami et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions
- (2014) Xiu-Hua Xu et al. CHEMICAL REVIEWS
- Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents
- (2014) Julie Charpentier et al. CHEMICAL REVIEWS
- Carbon-Centered Radical Addition to OC of Amides or Esters as a Route to CO Bond Formations
- (2014) Dong Liu et al. CHEMISTRY-A EUROPEAN JOURNAL
- Copper-Catalyzed Intermolecular Trifluoromethylarylation of Alkenes: Mutual Activation of Arylboronic Acid and CF3+ Reagent
- (2014) Fei Wang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Transition-Metal-Assisted Radical/Radical Cross-Coupling: A New Strategy to the Oxidative C(sp3)–H/N–H Cross-Coupling
- (2014) Liangliang Zhou et al. ORGANIC LETTERS
- Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols
- (2013) Zhi-Min Chen et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Copper-Catalyzed Trifluoromethylation-Initiated Radical 1,2-Aryl Migration in α,α-Diaryl Allylic Alcohols
- (2013) Xiaowu Liu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Visible-Light-Mediated Decarboxylation/Oxidative Amidation of α-Keto Acids with Amines under Mild Reaction Conditions Using O2
- (2013) Jie Liu et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Copper-Catalyzed Cyclic Oxytrifluoromethylation of 2,3-Allenoic Acids to Trifluoromethylated Butenolides
- (2013) Qiong Yu et al. CHEMISTRY-A EUROPEAN JOURNAL
- In Situ Generation of PhI+CF3and Transition-Metal-Free Oxidative sp2CH Trifluoromethylation
- (2013) Cong Xu et al. CHEMISTRY-A EUROPEAN JOURNAL
- Visible-Light-Induced Trifluoromethylation ofN-Aryl Acrylamides: A Convenient and Effective Method To Synthesize CF3-Containing Oxindoles Bearing a Quaternary Carbon Center
- (2013) Pan Xu et al. CHEMISTRY-A EUROPEAN JOURNAL
- The Direct Oxidative Addition of O2 to a Mononuclear Cr(I) Complex Is Spin Forbidden
- (2013) Fang Dai et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Global and local reactivity indices for electrophilic/nucleophilic free radicals
- (2013) Luis R. Domingo et al. ORGANIC & BIOMOLECULAR CHEMISTRY
- From N-benzoylpyridinium imides to pyrazolo[1,5-a]pyridines: a mechanistic discussion on a stoichiometric Cu protocol
- (2013) Lin Ling et al. ORGANIC & BIOMOLECULAR CHEMISTRY
- Recent advance in transition-metal-mediated trifluoromethylation for the construction of C(sp3)–CF3 bonds
- (2013) Jun Xu et al. TETRAHEDRON LETTERS
- Copper(i)-catalyzed diastereoselective hydroxytrifluoromethylation of dienes accelerated by phosphine ligands
- (2013) Deng-Fu Lu et al. Chemical Science
- Computational Studies on the Mechanism of the Copper-Catalyzed sp3-CH Cross-Dehydrogenative Coupling Reaction
- (2013) Gui-Juan Cheng et al. ChemPlusChem
- Transition Metal-Catalyzed C—H Trifluoromethylation
- (2012) Fei Pan et al. ACTA CHIMICA SINICA
- Radical Cascades Initiated by Intermolecular Radical Addition to Alkynes and Related Triple Bond Systems
- (2012) Uta Wille CHEMICAL REVIEWS
- Photoredox Catalysis: A Mild, Operationally Simple Approach to the Synthesis of α-Trifluoromethyl Carbonyl Compounds
- (2011) Phong V. Pham et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- Aromatic Trifluoromethylation with Metal Complexes
- (2011) Olesya A. Tomashenko et al. CHEMICAL REVIEWS
- Copper-Catalyzed Trifluoromethylation of Terminal Alkenes through Allylic C–H Bond Activation
- (2011) Jun Xu et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Copper-Catalyzed C(sp3)–C(sp3) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic Trifluoromethylation
- (2011) Xi Wang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Catalysis for fluorination and trifluoromethylation
- (2011) Takeru Furuya et al. NATURE
- Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis
- (2011) David A. Nagib et al. NATURE
- The nucleophilicity N index in organic chemistry
- (2011) Luis R. Domingo et al. ORGANIC & BIOMOLECULAR CHEMISTRY
- Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent
- (2011) Tianfei Liu et al. ORGANIC LETTERS
- Asymmetric Construction of Stereogenic Carbon Centers Featuring a Trifluoromethyl Group from Prochiral Trifluoromethylated Substrates
- (2010) Jing Nie et al. CHEMICAL REVIEWS
- The Productive Merger of Iodonium Salts and Organocatalysis: A Non-photolytic Approach to the Enantioselective α-Trifluoromethylation of Aldehydes
- (2010) Anna E. Allen et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Pd(II)-Catalyzedortho-Trifluoromethylation of Arenes Using TFA as a Promoter
- (2010) Xisheng Wang et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Zinc-Mediated Formation of Trifluoromethyl Ethers from Alcohols and Hypervalent Iodine Trifluoromethylation Reagents
- (2009) Raffael Koller et al. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
- CpCo-Mediated Reactions of Cyclopropenones: A DFT Study
- (2009) Daniel B. Werz et al. ORGANOMETALLICS
- Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(iii)–CF3 reagents
- (2008) Patrick Eisenberger et al. CHEMICAL COMMUNICATIONS
- Reactivity of a 10-I-3 Hypervalent Iodine Trifluoromethylation Reagent With Phenols
- (2008) Kyrill Stanek et al. JOURNAL OF ORGANIC CHEMISTRY
- Understanding organofluorine chemistry. An introduction to the C–F bond
- (2007) David O'Hagan CHEMICAL SOCIETY REVIEWS
Find Funding. Review Successful Grants.
Explore over 25,000 new funding opportunities and over 6,000,000 successful grants.
ExploreBecome a Peeref-certified reviewer
The Peeref Institute provides free reviewer training that teaches the core competencies of the academic peer review process.
Get Started