Late stage modifications of P-containing ligands using transition-metal-catalysed C–H bond functionalisation

A lesson for site-selective C–H functionalization on 2-pyridones: radical, organometallic, directing group and steric controls

(2018) Koji Hirano et al.   Chemical Science

P(O)R2-Directed Enantioselective C–H Olefination toward Chiral Atropoisomeric Phosphine–Olefin Compounds

(2017) Shi-Xia Li et al.   ORGANIC LETTERS

Ir(III)-Catalyzed Direct C–H Functionalization of Arylphosphine Oxides: A Strategy for MOP-Type Ligands Synthesis

(2017) Zhong Liu et al.   ORGANIC LETTERS

Copper-Mediated Annulation of Phosphorus-Containing Arenes with Alkynes: An Approach to Phosphindolium Salts

(2017) Qingmei Ge et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds

(2016) Joshua R. Hummel et al.   CHEMICAL REVIEWS

The medicinal chemist's toolbox for late stage functionalization of drug-like molecules

(2016) Tim Cernak et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed C–H Arylation of Indoles at the C7 Position

(2016) Youqing Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Direct C6-Arylation of Indoles

(2016) Youqing Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphaannulation of Aryl- and Benzylphosphonic Acids with Unactivated AlkenesviaPalladium-Catalyzed CH Activation/Oxidative Cyclization Reaction

(2015) Woo Hyung Jeon et al.   ADVANCED SYNTHESIS & CATALYSIS

Palladium-Catalyzed Enantioselective CH Arylation for the Synthesis of P-Stereogenic Compounds

(2015) Zi-Qi Lin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd(II)-Catalyzed Enantioselective Synthesis of P-Stereogenic Phosphinamides via Desymmetric C–H Arylation

(2015) Zhi-Jun Du et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of P-Stereogenic Phosphinic Amides via Pd(0)-Catalyzed Enantioselective Intramolecular C–H Arylation

(2015) Lantao Liu et al.   ORGANIC LETTERS

Pd(II)-Catalyzed P(O)R1R2-Directed Asymmetric C–H Activation and Dynamic Kinetic Resolution for the Synthesis of Chiral Biaryl Phosphates

(2015) Yan-Na Ma et al.   ORGANIC LETTERS

C–H Bond Transformations Leading to the Synthesis of Organic Functional Materials

(2015) Yoichiro Kuninobu et al.   SYNTHESIS-STUTTGART

Dual role of carboxylic acid additive: mechanistic studies and implication for the asymmetric C–H amidation

(2015) Donghyeon Gwon et al.   TETRAHEDRON

Cobalt-Catalyzed, Aminoquinoline-Directed Functionalization of Phosphinic Amide sp2 C–H Bonds

(2015) Tung Thanh Nguyen et al.   ACS Catalysis

Rhodium(III)-Catalyzed Direct Coupling of Arylphosphine Derivatives with Heterobicyclic Alkenes: A Concise Route to Biarylphosphines and Dibenzophosphole Derivatives

(2015) Yuto Unoh et al.   ACS Catalysis

Insights on the Design and Electron-Acceptor Properties of Conjugated Organophosphorus Materials

(2014) Thomas Baumgartner   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis of Dibenzophosphole OxidesviaPalladium-Catalyzed Intramolecular Direct Arylation Reactions ofortho-Halodiarylphosphine Oxides

(2014) Yuming Cui et al.   ADVANCED SYNTHESIS & CATALYSIS

Phosphine-Directed CH Borylation Reactions: Facile and Selective Access to Ambiphilic Phosphine Boronate Esters

(2014) Kristina M. Crawford et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

P(O)R2-directed Pd-catalyzed C–H functionalization of biaryl derivatives to synthesize chiral phosphorous ligands

(2014) Rong-Bin Hu et al.   Beilstein Journal of Organic Chemistry

Palladium-catalyzed R2(O)P directed C(sp2)–H acetoxylation

(2014) Heng Zhang et al.   CHEMICAL COMMUNICATIONS

Iridium(III)-Catalyzed CH Amidation of Arylphosphoryls Leading to aP-Stereogenic Center

(2014) Donghyeon Gwon et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Regioselective C–H Alkenylation of Phenylphosphine Sulfides

(2014) Yuki Yokoyama et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Synthesis of Six-Membered Benzofuzed Phosphacycles via Carbon–Phosphorus Bond Cleavage

(2014) Katsuaki Baba et al.   ORGANIC LETTERS

Photoredox Transformations with Dimeric Gold Complexes

(2013) Guillaume Revol et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Direct Synthesis of Phosphole Derivatives from Triarylphosphines through Cleavage of Carbon-Hydrogen and Carbon-Phosphorus Bonds

(2013) Katsuaki Baba et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Organic Frameworks as Biomimetic Catalysts

(2013) Zhi-Yuan Gu et al.   ChemCatChem

Rhodium-catalyzed oxidative coupling through C–H activation and annulation directed by phosphonamide and phosphinamide groups

(2013) Sangjune Park et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group

(2013) Li Yan Chan et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed P(O)R2 directed C–H arylation to synthesize electron-rich polyaromatic monophosphorus ligands

(2013) Rong-Bin Hu et al.   CHEMICAL COMMUNICATIONS

The modern interpretation of the Wittig reaction mechanism

(2013) Peter A. Byrne et al.   CHEMICAL SOCIETY REVIEWS

Rhodium-Catalyzed Oxidative C-H Activation/Cyclization for the Synthesis of Phosphaisocoumarins and Phosphorous 2-Pyrones

(2013) Youngchul Park et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Direct Arylation of Luminescent Bis-Cyclometalated Iridium(III) Complexes Incorporating C^N- or O^O-Coordinating Thiophene-Based Ligands: an Efficient Method for Color Tuning

(2013) Kassem Beydoun et al.   INORGANIC CHEMISTRY

Ruthenium-Catalyzed C–H Activation/Cyclization for the Synthesis of Phosphaisocoumarins

(2013) Youngchul Park et al.   JOURNAL OF ORGANIC CHEMISTRY

ortho-Acetoxylation of Phosphonic and Phosphoric Monoacids via Pd(II) Catalysis

(2013) Li Yan Chan et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed ortho-Alkenylation of Phenylphosphine Oxides through Regio- and Stereoselective Alkyne Insertion into C–H Bonds

(2013) Masaki Itoh et al.   JOURNAL OF ORGANIC CHEMISTRY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Rhodium(iii)-catalyzed ortho-olefination of aryl phosphonates

(2013) Bathoju Chandra Chary et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(III)-catalyzed Oxidative Coupling through C–H Bond Cleavage Directed by Phosphinoxy Groups

(2013) Yuto Unoh et al.   ORGANIC LETTERS

Pd(II)-Catalyzed ortho-Arylation of Aryl Phosphates and Aryl Hydrogen Phosphates with Diaryliodonium Triflates

(2013) Li Yan Chan et al.   ORGANIC LETTERS

Synthesis of Phosphaisocoumarins through Rhodium-Catalyzed Cyclization Using Alkynes and Arylphosphonic Acid Monoesters

(2013) Jungmin Seo et al.   ORGANIC LETTERS

Rhodium-Catalyzed Oxidative Cyclization of Arylphosphonic Acid Monoethyl Esters with Alkenes: Efficient Synthesis of Benzoxaphosphole 1-Oxides

(2013) Taekyu Ryu et al.   ORGANIC LETTERS

Palladium-Catalyzed C–H Arylation Using Phosphoramidate as a Directing Group at Room Temperature

(2013) Bathoju Chandra Chary et al.   ORGANIC LETTERS

Pd(II)-Catalyzed Ph2(O)P-Directed C–H Olefination toward Phosphine–Alkene Ligands

(2013) Hong-Li Wang et al.   ORGANIC LETTERS

Phosphoryl-Related Directing Groups in Rhodium(III) Catalysis: A General Strategy to Diverse P-Containing Frameworks

(2013) Dongbing Zhao et al.   ORGANIC LETTERS

Palladium(II)-catalyzed ortho -arylation via phosphate-group-directed C–H activation

(2013) Woo Hyung Jeon et al.   TETRAHEDRON

Oxidative ortho-alkenylation of arylphosphine oxides by rhodium-catalyzed C–H bond twofold cleavage

(2013) Juntae Mo et al.   RSC Advances

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Surface Modification Using Phosphonic Acids and Esters

(2012) Clémence Queffélec et al.   CHEMICAL REVIEWS

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

From C(sp2)–H to C(sp3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

(2012) Bi-Jie Li et al.   CHEMICAL SOCIETY REVIEWS

[Ir(cod)2]BARF-Catalyzed C–H Bond Alkenylation and Alkylation of Ferrocenes

(2012) Satoshi Takebayashi et al.   ORGANOMETALLICS

Ruthenium-catalyzed direct arylation of C–H bonds in aromatic amides containing a bidentate directing group: significant electronic effects on arylation

(2012) Yoshinori Aihara et al.   Chemical Science

Palladium-catalysed direct arylation of a tris-cyclometallated Ir(iii) complex bearing 2,2′-thienylpyridine ligands: a powerful tool for the tuning of luminescence properties

(2011) Kassem Beydoun et al.   CHEMICAL COMMUNICATIONS

Phosphine−Phosphinite and Phosphine−Phosphite Ligands: Preparation and Applications in Asymmetric Catalysis

(2011) Héctor Fernández-Pérez et al.   CHEMICAL REVIEWS

Review on Modern Advances of Chemical Methods for the Introduction of a Phosphonic Acid Group

(2011) Charles S. Demmer et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Multifunctional Chiral Phosphine Organocatalysts in Catalytic Asymmetric Morita−Baylis−Hillman and Related Reactions

(2010) Yin Wei et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct Phosphonylation of Aromatic Azaheterocycles

(2009) Sarah Van der Jeught et al.   CHEMICAL REVIEWS