Palladium-catalyzed R2(O)P directed C(sp2)–H acetoxylation

The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

(2013) Simon A. Girard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed oxidative coupling through C–H activation and annulation directed by phosphonamide and phosphinamide groups

(2013) Sangjune Park et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group

(2013) Li Yan Chan et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed P(O)R2 directed C–H arylation to synthesize electron-rich polyaromatic monophosphorus ligands

(2013) Rong-Bin Hu et al.   CHEMICAL COMMUNICATIONS

Palladium(II)-Catalyzed Ortho-Arylation of Benzylic Phosphonic Monoesters Using Potassium Aryltrifluoroborates

(2013) Xiangjian Meng et al.   JOURNAL OF ORGANIC CHEMISTRY

ortho-Acetoxylation of Phosphonic and Phosphoric Monoacids via Pd(II) Catalysis

(2013) Li Yan Chan et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed ortho-Alkenylation of Phenylphosphine Oxides through Regio- and Stereoselective Alkyne Insertion into C–H Bonds

(2013) Masaki Itoh et al.   JOURNAL OF ORGANIC CHEMISTRY

Pd(II)-Catalyzed Enantioselective C–H Activation/C–O Bond Formation: Synthesis of Chiral Benzofuranones

(2013) Xiu-Fen Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Rhodium(III)-catalyzed Oxidative Coupling through C–H Bond Cleavage Directed by Phosphinoxy Groups

(2013) Yuto Unoh et al.   ORGANIC LETTERS

Pd(II)-Catalyzed ortho-Arylation of Aryl Phosphates and Aryl Hydrogen Phosphates with Diaryliodonium Triflates

(2013) Li Yan Chan et al.   ORGANIC LETTERS

Palladium-Catalyzed C–H Arylation Using Phosphoramidate as a Directing Group at Room Temperature

(2013) Bathoju Chandra Chary et al.   ORGANIC LETTERS

Steric Control of Site Selectivity in the Pd-Catalyzed C–H Acetoxylation of Simple Arenes

(2013) Amanda K. Cook et al.   ORGANIC LETTERS

Pd(II)-Catalyzed C(sp2)–H Hydroxylation with R2(O)P-Coordinating Group

(2013) Hong-Yu Zhang et al.   ORGANIC LETTERS

Pd(II)-Catalyzed Ph2(O)P-Directed C–H Olefination toward Phosphine–Alkene Ligands

(2013) Hong-Li Wang et al.   ORGANIC LETTERS

Phosphoryl-Related Directing Groups in Rhodium(III) Catalysis: A General Strategy to Diverse P-Containing Frameworks

(2013) Dongbing Zhao et al.   ORGANIC LETTERS

Palladium(II)-catalyzed ortho -arylation via phosphate-group-directed C–H activation

(2013) Woo Hyung Jeon et al.   TETRAHEDRON

Oxidative ortho-alkenylation of arylphosphine oxides by rhodium-catalyzed C–H bond twofold cleavage

(2013) Juntae Mo et al.   RSC Advances

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From C(sp2)–H to C(sp3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

(2012) Bi-Jie Li et al.   CHEMICAL SOCIETY REVIEWS

Nitrate as a redox co-catalyst for the aerobic Pd-catalyzed oxidation of unactivated sp3-C–H bonds

(2012) Kara J. Stowers et al.   Chemical Science

Innate and Guided C–H Functionalization Logic

(2011) Tobias Brückl et al.   ACCOUNTS OF CHEMICAL RESEARCH

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium-Catalyzed Direct Addition of Aryl CH Bonds to N-Sulfonyl Aldimines

(2011) Yang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

C–H functionalization logic in total synthesis

(2011) Will R. Gutekunst et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

An Enantioselective, Intermolecular α-Arylation of Ester Enolates To Form Tertiary Stereocenters

(2011) Zhiyan Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

(2011) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Dibenzofurans via Palladium-Catalyzed Phenol-Directed C–H Activation/C–O Cyclization

(2011) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-catalyzed C–H acetoxylation of 2-methoxyimino-2-aryl-acetates and acetamides

(2011) Liang Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Oxidative Cyclization of 2-Arylphenols to Dibenzofurans under Pd(II)/Peroxybenzoate Catalysis

(2011) Ye Wei et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative C–H Bond Alkenylations in Water: Expedient Synthesis of Annulated Lactones

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Multifunctional Chiral Phosphine Organocatalysts in Catalytic Asymmetric Morita−Baylis−Hillman and Related Reactions

(2010) Yin Wei et al.   ACCOUNTS OF CHEMICAL RESEARCH

Platinum and Palladium Complexes Containing Cationic Ligands as Catalysts for Arene H/D Exchange and Oxidation

(2010) Marion H. Emmert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Beyond Traditional Cross Couplings: The Scope of the Cross Dehydrogenative Coupling Reaction

(2010) Caroline J. Scheuermann   Chemistry-An Asian Journal

Copper(II)-Catalyzed Ortho-Acyloxylation of the 2-Arylpyridines sp2C−H Bonds with Anhydrides, Using O2as Terminal Oxidant

(2010) Wenhui Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(III)-Catalyzed Isoquinolone Synthesis: The N−O Bond as a Handle for C−N Bond Formation and Catalyst Turnover

(2010) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-CatalyzedOrtho-Arylation ofO-Phenylcarbamates with Simple Arenes and Sodium Persulfate

(2010) Xiaodan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of β- and γ-Carbolinones via Pd-Catalyzed Direct Dehydrogenative Annulation (DDA) of Indole-carboxamides with Alkynes Using Air as the Oxidant

(2010) Zhuangzhi Shi et al.   ORGANIC LETTERS

High-Oxidation-State Palladium Catalysis: New Reactivity for Organic Synthesis

(2009) Kilian Muñiz   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organopalladium(iv) chemistry

(2009) Ling-Min Xu et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Alkoxylation ofN-Methoxybenzamides via Direct sp2C−H Bond Activation

(2009) Guan-Wu Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Aryl C−H Bonds Activation/Acetoxylation Utilizing a Bidentate System

(2009) Fa-Rong Gou et al.   ORGANIC LETTERS

O-Acetyl Oximes as Transformable Directing Groups for Pd-Catalyzed C−H Bond Functionalization

(2009) Sharon R. Neufeldt et al.   ORGANIC LETTERS

Pd-Catalyzed C−H Functionalizations ofO-Methyl Oximes with Arylboronic Acids

(2009) Chang-Liang Sun et al.   ORGANIC LETTERS

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic aerobic oxidation of substituted 8-methylquinolines in PdII-2,6-pyridinedicarboxylic acid systems

(2008) Jing Zhang et al.   CHEMICAL COMMUNICATIONS

Direct Ortho-Acetoxylation of Anilides via Palladium-Catalyzed sp2C−H Bond Oxidative Activation

(2008) Guan-Wu Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

Phosphinates as new electrophilic partners for cross-coupling reactions

(2008) Jun Guo et al.   ORGANIC & BIOMOLECULAR CHEMISTRY