Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 16, Pages 7649-7655Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo501542b
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Funding
- MEXT, JSPS
- JST, Japan
- Grants-in-Aid for Scientific Research [14J00760, 25288048, 25105733] Funding Source: KAKEN
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The regioselective alkenylation at the ortho position of phenylphosphine sulfides using alkenes proceeds efficiently in the presence of a cationic Cp*-rhodium(III) catalyst and an appropriate oxidant. A similar rhodium catalyst also promotes the redox-neutral coupling of the phosphine sulfides with alkynes to afford ortho-alkenylated products.
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