RhII-Catalyzed Cyclization of Ester/Thioester-ContainingN-Sulfonyl-1,2,3-triazoles: Facile Synthesis of Alkylidenephthalans and Alkylidenethiophthalans

Rhodium(II)-Catalysed Skeletal Rearrangement of Ether TetheredN-Sulfonyl 1,2,3-Triazoles: a Rapid Approach to 2-Aminoindanone and Dihydroisoquinoline Derivatives

(2016) Yinghua Yu et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Synthesis of 4-Bromo-1,2-dihydroisoquinolines: Access to Bromonium Ylides by the Intramolecular Reaction of a Benzyl Bromide and an α-Imino Carbene

(2016) Jun He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(II)-Catalyzed and Thermally Induced Intramolecular Migration ofN-Sulfonyl-1,2,3-triazoles: New Approaches to 1,2-Dihydroisoquinolines and 1-Indanones

(2016) Run Sun et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(II)-Catalyzed Regioselective Carbenoid Insertion Reaction of Simple Indoles withN-Sulfonyltriazoles: A Rapid Access to Tryptamine Vinylogues

(2015) Jiapian Huang et al.   ADVANCED SYNTHESIS & CATALYSIS

A Reaction of Triazoles with Thioesters to Produce β-Sulfanyl Enamides by Insertion of an Enamine Moiety into the Sulfur-Carbonyl Bond

(2015) Tomoya Miura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular annulation of aromatic rings with N-sulfonyl 1,2,3-triazoles: divergent synthesis of 3-methylene-2,3-dihydrobenzofurans and 3-methylene-2,3-dihydroindoles

(2015) Xiang-Ying Tang et al.   CHEMICAL COMMUNICATIONS

Rh(ii)-catalyzed cycloadditions of 1-tosyl 1,2,3-triazoles with 2H-azirines: switchable reactivity of Rh-azavinylcarbene as [2C]- or aza-[3C]-synthon

(2015) Yuanhao Wang et al.   CHEMICAL COMMUNICATIONS

A Rh-catalyzed 1,2-sulfur migration/aza-Diels–Alder cascade initiated by aza-vinyl carbenoids from sulfur-tethered N-sulfonyl-1,2,3-triazoles

(2015) Yu Jiang et al.   CHEMICAL COMMUNICATIONS

RhII-Catalyzed [3+2] Cycloaddition of 2 H-Azirines withN-Sulfonyl-1,2,3-Triazoles

(2015) Yun-Zhou Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Intramolecular C−H Bond Activation with Triazoles: Preparation of Stereodefined Pyrrolidines and Other Related Cyclic Compounds

(2015) Masato Senoo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of 2-Bromoimidazoles from Alkynes, N-Sulfonylazides, and Bromocyanides

(2015) Eunsook Lee et al.   ORGANIC LETTERS

Facile Synthesis of 2,5-Disubstituted Thiazoles from Terminal Alkynes, Sulfonyl Azides, and Thionoesters

(2015) Tomoya Miura et al.   ORGANIC LETTERS

The Divergent Synthesis of Nitrogen Heterocycles by Rhodium(II)-Catalyzed Cycloadditions of 1-Sulfonyl 1,2,3-Triazoles with 1,3-Dienes

(2014) Hai Shang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Transannulation of NH-1,2,3-Triazoles with Olefins

(2014) Sen Wai Kwok et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(II)-Catalyzed Intramolecular Cycloisomerizations of Methylenecyclopropanes withN-Sulfonyl 1,2,3-Triazoles

(2014) Kai Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phthalides and Phthalans: Synthetic Methodologies and Their Applications in the Total Synthesis

(2014) Raju Karmakar et al.   CHEMICAL REVIEWS

Reactions of metallocarbenes derived from N-sulfonyl-1,2,3-triazoles

(2014) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Concise Stereoselective Synthesis of Oxaspirocycles with 1-Tosyl-1,2,3-triazoles: Application to the Total Syntheses of (±)-Tuberostemospiroline and (±)-Stemona-lactam R

(2014) Junkai Fu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient Synthesis of Isothiochromene Derivatives by Pd-Catalyzed Hydrothiolation Reaction

(2014) Jie Feng et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Intramolecular Dearomatizing [3 + 2] Annulation of α-Imino Carbenoids with Aryl Rings Furnishing 3,4-Fused Indole Skeletons

(2014) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of Triazoloindoles via Tandem Copper Catalysis and Their Utility as α-Imino Rhodium Carbene Precursors

(2014) Yanpeng Xing et al.   ORGANIC LETTERS

Direct Production of Enaminones from Terminal Alkynes via Rhodium-Catalyzed Reaction of Formamides with N-Sulfonyl-1,2,3-triazoles

(2014) Tomoya Miura et al.   ORGANIC LETTERS

Rhodium(II)-Catalyzed Stereocontrolled Synthesis of 2-Tetrasubstituted Saturated Heterocycles from 1-Sulfonyl-1,2,3-triazoles

(2014) Alistair Boyer   ORGANIC LETTERS

Rhodium(II)-Catalyzed Stereocontrolled Synthesis of Dihydrofuran-3-imines from 1-Tosyl-1,2,3-triazoles

(2014) Alistair Boyer   ORGANIC LETTERS

Tunable and Chemoselective Syntheses of Dihydroisobenzofurans and Indanones via Rhodium-Catalyzed Tandem Reactions of 2-Triazole-benzaldehydes and 2-Triazole-alkylaryl Ketones

(2014) Hongjuan Shen et al.   ORGANIC LETTERS

DMF as a Source of Oxygen and Aminomethine: Stereoselective 1,2-Insertion of Rhodium(II) Azavinyl Carbenes into the C═O Bond of Formamides for the Synthesis of cis-Diamino Enones

(2014) Da Jung Jung et al.   ORGANIC LETTERS

Synthesis of Pyrroles from Terminal Alkynes, N-Sulfonyl Azides, and Alkenyl Alkyl Ethers through 1-Sulfonyl-1,2,3-triazoles

(2014) Cheol-Eui Kim et al.   ORGANIC LETTERS

Rhodium-Catalyzed Tandem Cyclopropanation/Cope Rearrangement of 4-Alkenyl-1-sulfonyl-1,2,3-triazoles with Dienes

(2013) Brendan T. Parr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Procedure for the Introduction of Three Different Bonds onto Terminal Alkynes throughN-Sulfonyl-1,2,3-Triazole Intermediates

(2013) Tomoya Miura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Reactivity of Rhodium-Iminocarbenes Derived fromN-Sulfonyl Triazoles

(2013) Anton V. Gulevich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Synthesis of Pyrroloindolines via a Rhodium(II)-Catalyzed Annulation of Indoles

(2013) Jillian E. Spangler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of 2,3-Dihydropyrroles from Terminal Alkynes, Azides, and α,β-Unsaturated Aldehydes via N-Sulfonyl-1,2,3-triazoles

(2013) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transannulation of 1-Sulfonyl-1,2,3-triazoles with Heterocumulenes

(2013) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Application of In Situ-Generated Rh-Bound Trimethylenemethane Variants to the Synthesis of 3,4-Fused Pyrroles

(2013) Erica E. Schultz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conversion of Cyclic Ketones to 2,3-Fused Pyrroles and Substituted Indoles

(2013) Joshua S. Alford et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective 1,3-Insertions of Rhodium(II) Azavinyl Carbenes

(2013) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Conversion of Furans to Highly Functionalized Pyrroles

(2013) Brendan T. Parr et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ring Expansion and Rearrangements of Rhodium(II) Azavinyl Carbenes

(2012) Nicklas Selander et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sulfonyl-1,2,3-Triazoles: Convenient Synthones for Heterocyclic Compounds

(2012) Mikhail Zibinsky et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploiting the Lithiation-Directing Ability of Oxetane for the Regioselective Preparation of Functionalized 2-Aryloxetane Scaffolds under Mild Conditions

(2012) Donato Ivan Coppi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Active Methylene Compounds in the Synthesis of 3-substituted Isobenzofuranones, Isoindolinones and Related Compounds

(2012) Antonia Di Mola et al.   CURRENT ORGANIC CHEMISTRY

Arylation of Rhodium(II) Azavinyl Carbenes with Boronic Acids

(2012) Nicklas Selander et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(II)-Catalyzed Asymmetric Sulfur(VI) Reduction of Diazo Sulfonylamidines

(2012) Nicklas Selander et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Enaminones by Rhodium-Catalyzed Denitrogenative Rearrangement of 1-(N-Sulfonyl-1,2,3-triazol-4-yl)alkanols

(2012) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Expanding the Scope of Donor/Acceptor Carbenes to N-Phthalimido Donor Groups: Diastereoselective Synthesis of 1-Cyclopropane α-Amino Acids

(2012) Joshua S. Alford et al.   ORGANIC LETTERS

Rhodium-Catalyzed [2+2+2] Cycloaddition of Alkynes for the Synthesis of Substituted Benzenes: Catalysts, Reaction Scope, and Synthetic Applications

(2012) Ken Tanaka et al.   SYNTHESIS-STUTTGART

Total Synthesis of Paecilospirone

(2011) Tsz-Ying Yuen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Denitrogenative Transannulation: Converting Triazoles into Other Heterocyclic Systems

(2011) Buddhadeb Chattopadhyay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric C–H Insertions of Rhodium(II) Azavinyl Carbenes

(2011) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of α-Amino Ketones from Terminal Alkynes via Rhodium-Catalyzed Denitrogenative Hydration of N-Sulfonyl-1,2,3-triazoles

(2011) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Transannulation ofN-Tosyl-1,2,3-Triazoles with Terminal Alkynes

(2011) Buddhadeb Chattopadhyay et al.   ORGANIC LETTERS

Synthesis and Reactivity of Sulfamoyl Azides and 1-Sulfamoyl-1,2,3-triazoles

(2011) Jeffrey C. Culhane et al.   ORGANIC LETTERS

Highly controlling selectivity of copper(I)-catalyzed azide/alkyne cycloaddition (CuAAC) between sulfonyl azids and normal alkynes or propynoates

(2011) Yantao Liu et al.   TETRAHEDRON

Isolation and Identification of FR198248, a Hydroxylated 1,3-Dihydroisobenzofuran, fromAspergillus flavipesas an Inhibitor of Peptide Deformylase

(2010) Yun-Ju KWON et al.   BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY

Structure−Activity Relationships for a Novel Series of Citalopram (1-(3-(Dimethylamino)propyl)-1-(4-fluorophenyl)-1,3-dihydroisobenzofuran-5-carbonitrile) Analogues at Monoamine Transporters

(2010) Peng Zhang et al.   JOURNAL OF MEDICINAL CHEMISTRY

Synthesis and Reactivity of Rhodium(II)N-Triflyl Azavinyl Carbenes

(2010) Neil Grimster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formal [2 + 2 + 2] Cycloaddition Strategy Based on an Intramolecular Propargylic Ene Reaction/Diels−Alder Cycloaddition Cascade

(2010) Julia M. Robinson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Total Synthesis of (+)-Salvileucalin B

(2010) Sergiy Levin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Synthesis of 1-Sulfonyl-1,2,3-triazoles

(2010) Jessica Raushel et al.   ORGANIC LETTERS

Rh(I)-Catalyzed Carbonylative Carbocyclization of Tethered Ene− and Yne−cyclopropenes

(2010) Changkun Li et al.   ORGANIC LETTERS

Cascade Reactions: Catalytic Synthesis of Functionalized 1,3-Dihydroisobenzofuran and Tetrahydrofuran Derivatives by Sequential Nucleophilic Ring Opening-Heterocyclization- Oxidative Carbonylation of Alkynyloxiranes

(2009) Nicola Della Ca' et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Enantioselective Cyclopropanation of Olefins withN-Sulfonyl 1,2,3-Triazoles

(2009) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Oxa-Pictet–Spengler Reaction: A Highlight on the Different Efficiency between Isochroman and Phthalan or Homoisochroman Derivative Syntheses

(2008) Marcella Guiso et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Regioselective reductive opening of substituted phthalans: synthetic applications

(2008) Daniel García et al.   TETRAHEDRON