Journal
CHEMICAL COMMUNICATIONS
Volume 51, Issue 21, Pages 4507-4510Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00268k
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Funding
- NSFC [21102081, 21272133]
- Beijing Natural Science Foundation [2132037]
- New Teachers' Fund for Doctor Stations, Ministry of Education [20110002120011]
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The Rh(II)-catalyzed formal [3+2] and [3+3] cycloadditions of 1-tosyl 1,2,3-triazoles with 2H-azirines have been developed, which enable the efficient synthesis of polysubstituted 3-aminopyrroles and 1,2-dihydropyrazines, respectively. The reported [3+2] cycloaddition represents the first application of 1-sulfonyl 1,2,3-triazole as a [2C]-component in relevant cycloaddition reactions.
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