Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 36, Pages 14670-14673Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja3062453
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Funding
- National Science Foundation [CHE-0848982]
- National Institute of General Medical Sciences, National Institutes of Health [GM-087620]
- Swedish Research Council (VR)
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0848982] Funding Source: National Science Foundation
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A highly efficient and stereoselective arylation of in situ-generated azavinyl carbenes affording enamines at ambient temperatures has been developed. These transition-metal carbenes are directly produced from readily available and stable 1-sulfonyl-1,2,3-triazoles in the presence of a rhodium carboxylate catalyst. In several cases, the enamines generated in this reaction can be cyclized into substituted indoles employing copper catalysis.
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