Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 134, Issue 5, Pages 2477-2480Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja210180q
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Funding
- National Science Foundation [CHE-0848982]
- Swedish Research Council (VR)
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0848982] Funding Source: National Science Foundation
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Diazo sulfonylamidines readily undergo enantioselective oxygen transfer from sulfur to carbon atom in the presence of chiral rhodium(II) carboxylates resulting in chiral sulfinylamidines. This unusual asymmetric atom transfer reduction occurs rapidly under mild conditions, and sulfinylamidines are obtained in excellent yield.
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