Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 135, Issue 12, Pages 4716-4718Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja401386z
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- National Science Foundation [CHE 1213246]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1213246] Funding Source: National Science Foundation
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The synthesis of highly functionalized pyrroles has been achieved by reaction of rhodium-stabilized imino-carbenes with furans. The reaction features an initial [3+2] annulation to form bicyclic hemiaminals, followed by ring opening to generate trisubstituted pyrroles.
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