Reactions of metallocarbenes derived from N-sulfonyl-1,2,3-triazoles

Rhodium(II)-Catalyzed Intramolecular Annulation of 1-Sulfonyl-1,2,3-Triazoles with Pyrrole and Indole Rings: Facile Synthesis of N-Bridgehead Azepine Skeletons

(2014) Jin-Ming Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Divergent Synthesis of Nitrogen Heterocycles by Rhodium(II)-Catalyzed Cycloadditions of 1-Sulfonyl 1,2,3-Triazoles with 1,3-Dienes

(2014) Hai Shang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Transannulation of NH-1,2,3-Triazoles with Olefins

(2014) Sen Wai Kwok et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular Dearomatizing [3 + 2] Annulation of α-Imino Carbenoids with Aryl Rings Furnishing 3,4-Fused Indole Skeletons

(2014) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium Catalyzed Direct Arylation of α-Diazoimines

(2014) Dongari Yadagiri et al.   ORGANIC LETTERS

Rhodium(II)-Catalyzed Stereocontrolled Synthesis of Dihydrofuran-3-imines from 1-Tosyl-1,2,3-triazoles

(2014) Alistair Boyer   ORGANIC LETTERS

DMF as a Source of Oxygen and Aminomethine: Stereoselective 1,2-Insertion of Rhodium(II) Azavinyl Carbenes into the C═O Bond of Formamides for the Synthesis of cis-Diamino Enones

(2014) Da Jung Jung et al.   ORGANIC LETTERS

Synthesis of Pyrroles from Terminal Alkynes, N-Sulfonyl Azides, and Alkenyl Alkyl Ethers through 1-Sulfonyl-1,2,3-triazoles

(2014) Cheol-Eui Kim et al.   ORGANIC LETTERS

Rhodium-Catalyzed Tandem Cyclopropanation/Cope Rearrangement of 4-Alkenyl-1-sulfonyl-1,2,3-triazoles with Dienes

(2013) Brendan T. Parr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Pot Procedure for the Introduction of Three Different Bonds onto Terminal Alkynes throughN-Sulfonyl-1,2,3-Triazole Intermediates

(2013) Tomoya Miura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Reactivity of Rhodium-Iminocarbenes Derived fromN-Sulfonyl Triazoles

(2013) Anton V. Gulevich et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Doyle–Kirmse Reaction Using Triazoles Leading to One-pot Multifunctionalization of Terminal Alkynes

(2013) Tomoya Miura et al.   CHEMISTRY LETTERS

Rhodium-Catalyzed Denitrogenative [2,3] Sigmatropic Rearrangement: An Efficient Entry to Sulfur-Containing Quaternary Centers

(2013) Dongari Yadagiri et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric Synthesis of Pyrroloindolines via a Rhodium(II)-Catalyzed Annulation of Indoles

(2013) Jillian E. Spangler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of 2,3-Dihydropyrroles from Terminal Alkynes, Azides, and α,β-Unsaturated Aldehydes via N-Sulfonyl-1,2,3-triazoles

(2013) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transannulation of 1-Sulfonyl-1,2,3-triazoles with Heterocumulenes

(2013) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Application of In Situ-Generated Rh-Bound Trimethylenemethane Variants to the Synthesis of 3,4-Fused Pyrroles

(2013) Erica E. Schultz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conversion of Cyclic Ketones to 2,3-Fused Pyrroles and Substituted Indoles

(2013) Joshua S. Alford et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective 1,3-Insertions of Rhodium(II) Azavinyl Carbenes

(2013) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Conversion of Furans to Highly Functionalized Pyrroles

(2013) Brendan T. Parr et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Transannulation of Alkynyl Triazoles via Alkyne–Carbene Metathesis Step: Access to Fused Pyrroles

(2013) Yi Shi et al.   ORGANIC LETTERS

Regiocontrolled Synthesis of Polysubstituted Pyrroles Starting from Terminal Alkynes, Sulfonyl Azides, and Allenes

(2013) Tomoya Miura et al.   ORGANIC LETTERS

Sulfonyl-1,2,3-Triazoles: Convenient Synthones for Heterocyclic Compounds

(2012) Mikhail Zibinsky et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ring expansion of alkynyl cyclopropanes to highly substituted cyclobutenes via a N-sulfonyl-1,2,3-triazole intermediate

(2012) Renhe Liu et al.   CHEMICAL COMMUNICATIONS

Arylation of Rhodium(II) Azavinyl Carbenes with Boronic Acids

(2012) Nicklas Selander et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Enaminones by Rhodium-Catalyzed Denitrogenative Rearrangement of 1-(N-Sulfonyl-1,2,3-triazol-4-yl)alkanols

(2012) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Expanding the Scope of Donor/Acceptor Carbenes to N-Phthalimido Donor Groups: Diastereoselective Synthesis of 1-Cyclopropane α-Amino Acids

(2012) Joshua S. Alford et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Denitrogenative Transannulation: Converting Triazoles into Other Heterocyclic Systems

(2011) Buddhadeb Chattopadhyay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Asymmetric C–H Insertions of Rhodium(II) Azavinyl Carbenes

(2011) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of α-Amino Ketones from Terminal Alkynes via Rhodium-Catalyzed Denitrogenative Hydration of N-Sulfonyl-1,2,3-triazoles

(2011) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Transannulation ofN-Tosyl-1,2,3-Triazoles with Terminal Alkynes

(2011) Buddhadeb Chattopadhyay et al.   ORGANIC LETTERS

Selective Formation of 1,5-Substituted Sulfonyl Triazoles Using Acetylides and Sulfonyl Azides

(2011) Maria Elena Meza-Aviña et al.   ORGANIC LETTERS

Highly controlling selectivity of copper(I)-catalyzed azide/alkyne cycloaddition (CuAAC) between sulfonyl azids and normal alkynes or propynoates

(2011) Yantao Liu et al.   TETRAHEDRON

Copper-catalyzed azide–alkyne cycloaddition (CuAAC) and beyond: new reactivity of copper(i) acetylides

(2010) Jason E. Hein et al.   CHEMICAL SOCIETY REVIEWS

Synthesis and Reactivity of Rhodium(II)N-Triflyl Azavinyl Carbenes

(2010) Neil Grimster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Synthesis of 1-Sulfonyl-1,2,3-triazoles

(2010) Jessica Raushel et al.   ORGANIC LETTERS

Stereochemistry and reactivity of F- and H-vinyldiazocarbonyl compounds and their phosphazines: synthesis of pyrazoles and pyridazines

(2010) Murat B. Supurgibekov et al.   TETRAHEDRON LETTERS

Nickel-catalysed denitrogenative alkyne insertion reactions of N-sulfonyl-1,2,3-triazoles

(2009) Tomoya Miura et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed Enantioselective Cyclopropanation of Olefins withN-Sulfonyl 1,2,3-Triazoles

(2009) Stepan Chuprakov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective C−C Bond Formation by Rhodium-Catalyzed Tandem Ylide Formation/[2,3]-Sigmatropic Rearrangement between Donor/Acceptor Carbenoids and Allylic Alcohols

(2009) Zhanjie Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Cyclobutenes by Highly Selective Transition-Metal-Catalyzed Ring Expansion of Cyclopropanes

(2008) Huadong Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cu-Catalyzed Azide−Alkyne Cycloaddition

(2008) Morten Meldal et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed Transannulation of 1,2,3-Triazoles with Nitriles

(2008) Tony Horneff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY