Highly selective directed arylation reactions via back-to-back dehydrogenative C–H borylation/arylation reactions

Direct Borylation of Primary CH Bonds in Functionalized Molecules by Palladium Catalysis

(2014) Li-Sheng Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functional group directed C–H borylation

(2014) A. Ros et al.   CHEMICAL SOCIETY REVIEWS

Iridium-catalyzed ortho-C–H borylation of aromatic aldimines derived from pentafluoroaniline with bis(pinacolate)diboron

(2014) Ikuo Sasaki et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-Catalyzedortho-Selective CH Borylation of 2-Phenylpyridine and Its Derivatives at Room Temperature

(2013) Yoichiro Kuninobu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(I)-Catalyzed Redox-Economic Cross-Coupling of Carboxylic Acids with Arenes Directed by N-Containing Groups

(2013) Fei Pan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A New Access to 4 H-Quinolizines from 2-Vinylpyridine and Alkynes Promoted by Rhodium-N-Heterocyclic-Carbene Catalysts

(2013) Ramón Azpíroz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Amino-Directed RhIII-Catalyzed CH Activation Leading to One-Pot Synthesis of NH Carbazoles

(2013) Qibai Jiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Free-Amine Directed Arylation of Biaryl-2-amines with Aryl Iodides by Palladium Catalysis

(2013) Zunjun Liang et al.   ORGANIC LETTERS

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed monoselective C–H borylation of acetanilides under acidic conditions

(2012) Bin Xiao et al.   CHEMICAL COMMUNICATIONS

Heteroleptic rhodium NHC complexes with pyridine-derived ligands: synthetic accessibility and reactivity towards oxygen

(2012) Olena V. Zenkina et al.   DALTON TRANSACTIONS

Rh-Catalyzed Borylation of N-Adjacent C(sp3)–H Bonds with a Silica-Supported Triarylphosphine Ligand

(2012) Soichiro Kawamorita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rollover Cyclometalation Pathway in Rhodium Catalysis: Dramatic NHC Effects in the C–H Bond Functionalization

(2012) Jaesung Kwak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrazone as the Directing Group for Ir-Catalyzed Arene Diborylations and Sequential Functionalizations

(2012) Abel Ros et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Regioselectivity in the Hydrothiolation of Alkynes by Rhodium N-Heterocyclic Carbene Catalysts

(2012) Andrea Di Giuseppe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A C–H Borylation Approach to Suzuki–Miyaura Coupling of Typically Unstable 2–Heteroaryl and Polyfluorophenyl Boronates

(2012) Daniel W. Robbins et al.   ORGANIC LETTERS

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Borylation and Silylation of C–H Bonds: A Platform for Diverse C–H Bond Functionalizations

(2011) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

Double Single-Crystal-to-Single-Crystal Transformation and Small-Molecule Activation in Rhodium NHC Complexes

(2011) Olena V. Zenkina et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild and Selective H/D Exchange at the β Position of Aromatic α-Olefins by N-Heterocyclic Carbene-Hydride-Rhodium Catalysts

(2011) Andrea Di Giuseppe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Use of Hemilabile N,N Ligands in Nitrogen-Directed Iridium-Catalyzed Borylations of Arenes

(2011) Abel Ros et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh-CatalyzedOrtho-Selective C–H Borylation ofN-Functionalized Arenes with Silica-Supported Bridgehead Monophosphine Ligands

(2011) Soichiro Kawamorita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Oxidative ortho-C–H Borylation of Arenes

(2011) Hui-Xiong Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Directedortho-Metalation–Cross-Coupling Strategies. One-Pot Suzuki Reaction to Biaryl and Heterobiaryl Sulfonamides

(2011) Cédric Schneider et al.   ORGANIC LETTERS

Dimeric Rhodium–Ethylene NHC Complexes As Reactive Intermediates for the Preparation of Tetra-heteroleptic NHC Complexes

(2011) Olena V. Zenkina et al.   ORGANOMETALLICS

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium-Catalyzed CH Activation versus DirectedorthoMetalation: Complementary Borylation of Aromatics and Heteroaromatics

(2010) Timothy E. Hurst et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stereospecific Suzuki−Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration

(2010) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Oxidative C−H Arylation of 2-Arylpyridine Derivatives via Decarbonylation of Aromatic Aldehydes

(2010) Qi Shuai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expanding the scope of transformations of organoboron species: carbon–carbon bond formation with retention of configuration

(2009) Cathleen M. Crudden et al.   CHEMICAL COMMUNICATIONS

Ortho-C–H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium–phosphine complexes

(2009) Tatsuo Ishiyama et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbene Rhodium Complexes and Their Reactions with H2and with CO

(2009) Xiao-Yan Yu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Directed Ortho Borylation of Functionalized Arenes Catalyzed by a Silica-Supported Compact Phosphine−Iridium System

(2009) Soichiro Kawamorita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 1-Borylisoindoles via Palladium-Catalyzed Dehydrogenation/C−H Borylation of Isoindolines

(2009) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Rh(I)-Catalyzed Direct Arylation and Alkenylation of Arene C−H Bonds via Decarbonylation of Benzoic and Cinnamic Anhydrides

(2009) Weiwei Jin et al.   ORGANIC LETTERS

Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond Activation

(2008) Jared C. Lewis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbenes: Synthesis, properties, and organometallic chemistry

(2008) Pierre de Frémont et al.   COORDINATION CHEMISTRY REVIEWS

Rhodium catalysed dehydrogenative borylation of alkenes: Vinylboronates via C–H activation

(2008) Ibraheem A. I. Mkhalid et al.   DALTON TRANSACTIONS

Rhodium-Catalyzed Regioselective C−H Functionalization via Decarbonylation of Acid Chlorides and C−H Bond Activation under Phosphine-Free Conditions

(2008) Xiaodan Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Counteranion-Accelerated RhIOAc-Catalyzed Regioselective Hydroboration of Vinylarenes

(2008) Kohei Endo et al.   ORGANOMETALLICS

Oxidative Coupling of Arylboronic Acids with Arenes via Rh-Catalyzed Direct C−H Arylation

(2007) Thomas Vogler et al.   ORGANIC LETTERS