Developing Synthetic Approaches with Non-Innocent Metalloligands: Easy Access to IrI/Pd0 and IrI/Pd0/IrI Cores

Hidden Noninnocence: Theoretical and Experimental Evidence for Redox Activity of a β-Diketiminate(1−) Ligand

(2011) Marat M. Khusniyarov  et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligands that Store and Release Electrons during Catalysis

(2011) Wojciech I. Dzik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The radical mechanism of cobalt(ii) porphyrin-catalyzed olefin aziridination and the importance of cooperative H-bonding

(2011) Alma I. Olivos Suarez et al.   DALTON TRANSACTIONS

Synthesis, Electronic Structure, and Catalytic Activity of Reduced Bis(aldimino)pyridine Iron Compounds: Experimental Evidence for Ligand Participation

(2011) Sarah K. Russell et al.   INORGANIC CHEMISTRY

O2Activation by Bis(imino)pyridine Iron(II)−Thiolate Complexes

(2011) Yosra M. Badiei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Evidence for Cobalt(III)-Carbene Radicals: Key Intermediates in Cobalt(II)-Based Metalloradical Cyclopropanation

(2011) Hongjian Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Binuclear [(cod)(Cl)Ir(bpi)Ir(cod)]+for Catalytic Water Oxidation

(2011) Wojciech I. Dzik et al.   ORGANOMETALLICS

Exploiting Non-Innocent Ligands to Prepare Masked Palladium(0) Complexes

(2010) Dan A. Smith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dioxygen activation by mixed-valent dirhodium complexes of redox non-innocent azoaromatic ligands

(2010) Nanda D. Paul et al.   CHEMICAL COMMUNICATIONS

Coexistence of Two Thermally Induced Intramolecular Electron Transfer Processes in a Series of Metal Complexes [M(Cat-N-BQ)(Cat-N-SQ)]/[M(Cat-N-BQ)2] (M=Co, Fe, and Ni) bearing Non-Innocent Catechol-Based Ligands: A Combined Experimental and Theoretical S

(2010) Emi Evangelio et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electronic characteristics of an extensive series of ruthenium complexes with the non-innocent o-benzoquinonediimine ligand: A pedagogical approach

(2010) A.B.P. Lever   COORDINATION CHEMISTRY REVIEWS

Non-innocent ligands in bioinorganic chemistry—An overview

(2010) Wolfgang Kaim et al.   COORDINATION CHEMISTRY REVIEWS

o-Dithiolene and o-aminothiolate chemistry of iron: Synthesis, structure and reactivity

(2010) Stephen Sproules et al.   COORDINATION CHEMISTRY REVIEWS

‘Double redox-activity’ in azobenzene-quinonoid palladium(ii) complexes: a combined structural, electrochemical and spectroscopic study

(2010) Naina Deibel et al.   DALTON TRANSACTIONS

Influence of the Redox Active Ligand on the Reactivity and Electronic Structure of a Series of Fe(TIM) Complexes

(2010) Corinna R. Hess et al.   INORGANIC CHEMISTRY

Deprotonation and dehydrogenation of Di(2-pyridylmethyl)amine with M[N(SiMe3)2]2 (M = Mn, Fe, Co, Zn) and Fe(C6H2-2,4,6-Me3)2

(2010) Astrid Malassa et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Evidence for Ligand Non-innocence in a Formally Ruthenium(I) Hydride Complex

(2010) Noah L. Wieder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Electronic Structure of Cationic, Neutral, and Anionic Bis(imino)pyridine Iron Alkyl Complexes: Evaluation of Redox Activity in Single-Component Ethylene Polymerization Catalysts

(2010) Aaron M. Tondreau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

‘Carbene Radicals’ in CoII(por)-Catalyzed Olefin Cyclopropanation

(2010) Wojciech I. Dzik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Active Ligand-Mediated Oxidative Addition and Reductive Elimination at Square Planar Cobalt(III): Multielectron Reactions for Cross-Coupling

(2010) Aubrey L. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidation of Dihydrogen by Iridium Complexes of Redox-Active Ligands

(2010) Mark R. Ringenberg et al.   ORGANOMETALLICS

Radical Ligands Confer Nobility on Base-Metal Catalysts

(2010) P. J. Chirik et al.   SCIENCE

Well-Defined Regioselective Iminopyridine Rhodium Catalysts for Anti-Markovnikov Addition of Aromatic Primary Amines to 1-Octyne

(2009) Carlos Alonso-Moreno et al.   ADVANCED SYNTHESIS & CATALYSIS

Electromeric Rhodium Radical Complexes

(2009) Florian Frank Puschmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Odd-Electron Complex [Ruk(NOm)(Qn)(terpy)]2+with Two Prototypical Non-Innocent Ligands

(2009) Atanu Kumar Das et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[{Fe(tim)}2]: An FeFe Dimer Containing an Unsupported Metal-Metal Bond and Redox-Active N4Macrocyclic Ligands

(2009) Corinna R. Hess et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Carbonylation Reactions of Aryl Halides and Related Compounds

(2009) Anne Brennführer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-noninnocence of N,N′-bis(6-methyl-2-pyridylmethylene)ethane-1,2-diamine (L): synthesis and characterization of diamagnetic [NiII2(L˙˙)2] and [ZnII2(L)Cl4]((L˙˙)2−π diradical dianion of L)

(2009) Amrita Mondal et al.   CHEMICAL COMMUNICATIONS

Stabilising a quinonoid-bridged dicopper(i) complex by use of a dppf (dppf = (diphenylphosphino)ferrocene) backbone

(2009) Alexa Paretzki et al.   CHEMICAL COMMUNICATIONS

Ligand-Centred Reactivity of Bis(picolyl)amine Iridium: Sequential Deprotonation, Oxidation and Oxygenation of a “Non-Innocent” Ligand

(2009) Cristina Tejel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Square-planar d8 metal mixed-ligand dithiolene complexes as second order nonlinear optical chromophores: Structure/property relationship

(2009) Paola Deplano et al.   COORDINATION CHEMISTRY REVIEWS

Ruthenium complexes with non-innocent ligands: Electron distribution and implications for catalysis

(2009) Julie L. Boyer et al.   COORDINATION CHEMISTRY REVIEWS

Accessing the Different Redox States of α-Iminopyridines within Cobalt Complexes

(2009) Connie C. Lu et al.   INORGANIC CHEMISTRY

Electron Paramagnetic Resonance and Electron Nuclear Double Resonance Investigation of the Diradical Bis(α-iminopyridinato)zinc Complex

(2009) Maurice van Gastel et al.   INORGANIC CHEMISTRY

Structure-dependent spectroscopic and redox properties of copper(I) complexes with bidentate iminopyridine ligands

(2009) Werner Massa et al.   INORGANICA CHIMICA ACTA

Rhodium(0) Metalloradicals in Binuclear C−H Activation

(2009) Florian F. Puschmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Half-Sandwich Lanthanide(III) Complexes Coordinated by Two α-Iminopyridine Radical Anions

(2009) Alexander A. Trifonov et al.   ORGANOMETALLICS

Mercury(I) complexes with bidentate iminopyridine ligands: Synthesis, spectral characterization and structural analysis

(2009) Saeed Dehghanpour et al.   POLYHEDRON

Structures of Co, Pd and Ni complexes with iminopyridine ligands having an hydroxymethyl or acrylate pendant group

(2009) Junpei Kuwabara et al.   POLYHEDRON

An Electron-Transfer Series of High-Valent Chromium Complexes with Redox Non-Innocent, Non-Heme Ligands

(2008) Connie C. Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal Complexes of Aminyl Radicals

(2008) Robin G. Hicks   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperating Ligands in Catalysis

(2008) Hansjörg Grützmacher   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand Oxidation of a Deprotonated Bis(picolyl)amine IrI(cod) Complex

(2008) Cristina Tejel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Targeted Oxidase Reactivity with a New Redox-Active Ligand Incorporating N2O2Donor Atoms. Complexes of Cu(II), Ni(II), Pd(II), Fe(III), and V(V)

(2008) Chandan Mukherjee et al.   INORGANIC CHEMISTRY

From symmetrical to unsymmetrical bimetallic nickel complexes bearing aryl-linked iminopyridines; synthesis, structures and ethylene polymerisation studies

(2008) Jérémie D.A. Pelletier et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Deprotonation Induced Ligand-to-Metal Electron Transfer: Synthesis of a Mixed-Valence Rh(−I,I) Dinuclear Compound and Its Reaction with Dioxygen

(2008) Cristina Tejel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Neutral Bis(α-iminopyridine)metal Complexes of the First-Row Transition Ions (Cr, Mn, Fe, Co, Ni, Zn) and Their Monocationic Analogues:  Mixed Valency Involving a Redox Noninnocent Ligand System

(2008) Connie C. Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Bench-Stable Pd Catalyst for the Hydroarylation of Fullerene with Boronic Acids

(2008) Susumu Mori et al.   ORGANIC LETTERS

Iron-Catalyzed 1,4-Addition of α-Olefins to Dienes

(2008) Benoît Moreau et al.   ORGANIC LETTERS

Reactions of Cationic Palladium α-Diimine Complexes with Nitrogen-Containing Olefins: Branched Polyethylene with Carbazole Functionalities

(2008) Weidong Li et al.   ORGANOMETALLICS

Synthesis and X-ray Crystal Structures of Acenaphthenequinone-based α-Diimine Palladium Complexes and a Novel V-shape Tripalladium Cluster

(2008) Jin Zhou et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE