β-Protic Pyrazole and N-Heterocyclic Carbene Complexes: Synthesis, Properties, and Metal-Ligand Cooperative Bifunctional Catalysis

Enantioselective and Z/E-Selective Conjugate Addition of α-Substituted Cyanoacetates to Acetylenic Esters Catalyzed by Bifunctional Ruthenium and Iridium Complexes

(2010) Yasuharu Hasegawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Bis(N-Alkylimidazole) to Bis(NH-NHC) in Rhenium Carbonyl Complexes

(2010) Miguel A. Huertos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chain mechanism for exchange of D2 with a ruthenium hydride

(2010) Charles P. Casey et al.   CHEMICAL COMMUNICATIONS

Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry

(2010) Hervé Clavier et al.   CHEMICAL COMMUNICATIONS

Discovery, Applications, and Catalytic Mechanisms of Shvo’s Catalyst

(2010) Brian L. Conley et al.   CHEMICAL REVIEWS

Bifunctional Organometallic Catalysis and Reactivity Using Heterocyclic Phosphines and Metallated Heterocycles

(2010) Douglas B. Grotjahn   CHEMISTRY LETTERS

Effect of the Nature of the Substituent in N-Alkylimidazole Ligands on the Outcome of Deprotonation: Ring Opening versus the Formation of N-Heterocyclic Carbene Complexes

(2010) Miguel A. Huertos et al.   CHEMISTRY-A EUROPEAN JOURNAL

Quest for metal/NH bifunctional bioinspired catalysis in a dinuclear platform

(2010) Shigeki Kuwata et al.   DALTON TRANSACTIONS

Pyrazole and (pyrazol-1-yl)metal complexes as carbon–carbon coupling catalysts

(2010) Stephen O. Ojwach et al.   INORGANICA CHIMICA ACTA

Mechanism of Enantioselective C−C Bond Formation with Bifunctional Chiral Ru Catalysts: NMR and DFT Study

(2010) Ilya D. Gridnev et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Hydrogenative Desymmetrization of Bicyclic Imides Leading to Multiply Functionalized Chiral Cyclic Compounds

(2010) Masato Ito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Hydrogenation of Amides to Alcohols and Amines under Mild Conditions

(2010) Ekambaram Balaraman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphine-Tethered Carbene Ligands: Template Synthesis and Reactivity of Cyclic and Acyclic Functionalized Carbenes

(2010) Insun Yu et al.   ORGANOMETALLICS

Synthesis and Reactivity of 2-Aminoethanethiolato-Bridged Dinuclear Ru(hmb) Complexes (hmb = η6-hexamethylbenzene): Mechanistic Consideration on Transfer Hydrogenation with Bifunctional [RuCl2(hmb)]2/2-Aminoethanethiol Catalyst System

(2010) Masato Ito et al.   ORGANOMETALLICS

On the Existence of an N-Metalated N-Heterocyclic Carbene: A Theoretical Study

(2010) Javier Ruiz et al.   ORGANOMETALLICS

Acyl Protection Strategy for Synthesis of a Protic NHC Complex via N-Acyl Methanolysis†

(2010) Graham E. Dobereiner et al.   ORGANOMETALLICS

Synthesis, Characterization, and H-Bonding Abilities of Ruthenium(II) Complexes Bearing Bidentate NR,NH-Carbene/Phosphine Ligands†

(2010) F. Ekkehardt Hahn et al.   ORGANOMETALLICS

Aerobic oxidation with bifunctional molecular catalysts

(2010) Takao Ikariya et al.   PURE AND APPLIED CHEMISTRY

Asymmetric nitrile-hydration with bifunctional ruthenium catalysts bearing chiral N-sulfonyldiamine ligands

(2010) Shoko Kamezaki et al.   TETRAHEDRON-ASYMMETRY

Bifunctional Transition Metal-Based Molecular Catalysts for Asymmetric C–C and C–N Bond Formation

(2010) Takao Ikariya et al.   TOPICS IN CATALYSIS

Mononuclear Complexes of Platinum Group Metals Containing η6- and η5-Cyclic Π-Perimeter Hydrocarbon and Pyridylpyrazolyl Derivatives: Syntheses and Structural Studies

(2010) Gajendra Gupta et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Development of Molecular Electrocatalysts for CO2Reduction and H2Production/Oxidation

(2009) M. Rakowski Dubois et al.   ACCOUNTS OF CHEMICAL RESEARCH

Anion-Exchange-Triggered 1,3-Shift of an NH Proton to Iridium in Protic N-Heterocyclic Carbenes: Hydrogen-Bonding and Ion-Pairing Effects

(2009) Guoyong Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2,2′:6′,2″-terpyridine

(2009) Margarita Paneque et al.   CHEMICAL COMMUNICATIONS

Metal-induced tautomerization of oxazole and thiazole molecules to heterocyclic carbenes

(2009) Javier Ruiz et al.   CHEMICAL COMMUNICATIONS

Bifunctional transition metal-based molecular catalysts for asymmetric CC and CN bond formation

(2009) Takao Ikariya et al.   CHEMICAL RECORD

Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic Applications

(2009) Macarena Poyatos et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Asymmetric hydrogenation, transfer hydrogenation and hydrosilylation of ketones catalyzed by iron complexes

(2009) Robert H. Morris   CHEMICAL SOCIETY REVIEWS

Transition-metal phosphors with cyclometalating ligands: fundamentals and applications

(2009) Yun Chi et al.   CHEMICAL SOCIETY REVIEWS

Metal-Pyrazole Bifunction in Half-Sandwich CN Chelate Iridium Complexes: Pyrazole-Pyrazolato Interconversion and Application to Catalytic Intramolecular Hydroamination of Aminoalkene

(2009) Yohei Kashiwame et al.   CHEMISTRY-A EUROPEAN JOURNAL

NHC–manganese(i) complexes as carbene transfer agents

(2009) Javier Ruiz et al.   DALTON TRANSACTIONS

Fused polycyclic nucleophilic carbenes – synthesis, structure, and function

(2009) Anthony J. Arduengo et al.   DALTON TRANSACTIONS

Synthesis of NHC complexes by template controlled cyclization of β-functionalized isocyanides

(2009) Aarón Flores-Figueroa et al.   DALTON TRANSACTIONS

Pyrazoles and pyrazolides—flexible synthons in self-assembly

(2009) Malcolm A. Halcrow   DALTON TRANSACTIONS

Palladium Complexes Containing Potentially Chelating Pyridylidene-Type Carbene Ligands

(2009) Aurélie Poulain et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Computational Study of theC- andN-Bound Tautomers of [Ru(Cl)(H)(CO)-(PPh3)2(IiPrMe2)] (IiPrMe2= 3-Isopropyl-4,5-dimethylimidazol-2-ylidene)

(2009) L. Jonas L. Häller et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Mono-, Bi- and Tridentate N-Heterocyclic Carbene Ligands for the Preparation of Transition-Metal-Based Homogeneous Catalysts

(2009) Rosa Corberán et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Pyrazole Complexes and Supramolecular Chemistry

(2009) Julio Pérez et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Pyrazole and Pyrazolyl Complexes ofcis-Bis(2,2′-bipyridine)chlororuthenium(II): Synthesis, Structural and Electronic Characterization, and Acid-Base Chemistry

(2009) Hershel Jude et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Diverse Chemical Applications of N-Heterocyclic Carbenes

(2009)   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Insights into Catalytic H2Oxidation by Ni Complexes Containing a Diphosphine Ligand with a Positioned Amine Base

(2009) Jenny Y. Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formation of an Iodide-Bridged Diruthenium Complex from [(η5-Ph4C4COH)(CO)2RuI] and [(Ph4C4CO)(CO)2Ru]2: An Efficient Catalyst for Alcohol Oxidation with Ag2O

(2009) Youngshil Do et al.   ORGANOMETALLICS

Effects of the Counteranion on the Pyrazole−Nitrile Coupling Reaction Mediated by Nickel(II) Ions

(2009) Chang-Chih Hsieh et al.   ORGANOMETALLICS

Synthesis of a Ruthenium(II) Complex Containing an [11]ane-P2CNHC(NHC = Imidazolidin-2-ylidene) Macrocycle

(2009) Aarón Flores-Figueroa et al.   ORGANOMETALLICS

Template Synthesis of Ruthenium Complexes with Saturated and Benzannulated NH,NH-Stabilized N-Heterocyclic Carbene Ligands

(2009) Oliver Kaufhold et al.   ORGANOMETALLICS

NH-Tautomerization of Quinolines and 2-Methylpyridine Promoted by a Hydride-Iridium(III) Complex: Importance of the Hydride Ligand

(2009) Miguel A. Esteruelas et al.   ORGANOMETALLICS

Remarkable Positive Effect of Silver Salts on Asymmetric Hydrogenation of Acyclic Imines with Cp*Ir Complexes Bearing Chiral N-Sulfonylated Diamine Ligands

(2009) Shin-yo Shirai et al.   ORGANOMETALLICS

Construction of Highly Active Ruthenium(II) NNN Complex Catalysts Bearing a Pyridyl-Supported Pyrazolyl-Imidazolyl Ligand for Transfer Hydrogenation of Ketones

(2009) Fanlong Zeng et al.   ORGANOMETALLICS

Study of novel η5-cyclopentadienyl and η6-arene platinum group metal complexes containing a N4-type ligand and their structural characterization

(2009) Gajendra Gupta et al.   POLYHEDRON

Consecutive Thermal H2and Light-Induced O2Evolution from Water Promoted by a Metal Complex

(2009) Stephan W. Kohl et al.   SCIENCE

Room-temperature Ru(II)-catalyzed transfer hydrogenation of ketones and aldehydes in air

(2009) Miao Zhao et al.   TETRAHEDRON LETTERS

Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C−H Bond Activation

(2008) Jared C. Lewis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Surveying Sterically Demanding N-Heterocyclic Carbene Ligands with Restricted Flexibility for Palladium-catalyzed Cross-Coupling Reactions

(2008) Sebastian Würtz et al.   ACCOUNTS OF CHEMICAL RESEARCH

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperating Ligands in Catalysis

(2008) Hansjörg Grützmacher   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen bonding-assisted tautomerization of pyridine moieties in the coordination sphere of an Ir(i) complex

(2008) Guoyong Song et al.   CHEMICAL COMMUNICATIONS

A Donor-Stabilized Silanethione or a Si-Substituted N-Heterocyclic Platinum Carbene?

(2008) Erica Brendler et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aerobic Oxidation of Alcohols with Bifunctional Transition-Metal Catalysts Bearing C-N Chelate Ligands

(2008) Sachiko Arita et al.   Chemistry-An Asian Journal

Bifunctional catalysts and related complexes: structures and properties

(2008) Douglas B. Grotjahn   DALTON TRANSACTIONS

Donor-Functionalised N-Heterocyclic Carbene Complexes of Group 9 and 10 Metals in Catalysis: Trends and Directions

(2008) Adrien T. Normand et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Chelate-tethered nucleobases: New architectures and insights in metal ion–nucleobase chemistry

(2008) Miguel A. Galindo et al.   INORGANICA CHIMICA ACTA

Imidazol-2-yl Complexes of Cp*Ir as Bifunctional Ambident Reactants

(2008) Valentín Miranda-Soto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

FromN-Alkylimidazole Ligands at a Rhenium Center: Ring Opening or Formation of NHC Complexes

(2008) Miguel A. Huertos et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal Template Controlled Formation of [11]ane-P2CNHCMacrocycles

(2008) Oliver Kaufhold et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Pyridylpyrazole Ligands for the Heck Reaction. A Combined Experimental and Computational Study

(2008) Vanessa Montoya et al.   ORGANOMETALLICS

Cβ(sp2)−H Bond Activation of α,β-Unsaturated Ketones Promoted by a Hydride-Elongated Dihydrogen Complex: Formation of Osmafuran Derivatives with Carbene, Carbyne, and NH-Tautomerized α-Substituted Pyridine Ligands

(2008) María L. Buil et al.   ORGANOMETALLICS

Rhodium-Catalyzed C−C Coupling Reactions: Mechanistic Considerations

(2008) Kirsty J. Hawkes et al.   ORGANOMETALLICS

Isolation and Interconversion of ProticN-Heterocyclic Carbene and Imidazolyl Complexes: Application to Catalytic Dehydrative Condensation ofN-(2-Pyridyl)benzimidazole and Allyl Alcohol

(2008) Kenjirou Araki et al.   ORGANOMETALLICS

Exceptionally Efficient Unsymmetrical Ruthenium(II) NNN Complex Catalysts Bearing a Pyridyl-Based Pyrazolyl−Imidazolyl Ligand for Transfer Hydrogenation of Ketones

(2008) Fanlong Zeng et al.   ORGANOMETALLICS

Ruthenium(II) Complexes Bearing a Pyridyl-Supported Pyrazolyl−N-Heterocyclic Carbene (NNC) Ligand and Their Catalytic Activity in the Transfer Hydrogenation of Ketones

(2008) Fanlong Zeng et al.   ORGANOMETALLICS

Synthesis and characterization of some new mononuclear ruthenium complexes containing 4-(un)substituted dipyridylpyrazole ligands

(2008) Wei Zhang et al.   POLYHEDRON