Synthesis of heterocycles via transition-metal-catalyzed hydroarylation of alkynes

Brønsted Acid Catalyzed Intramolecular Hydroarylation for the Synthesis of Cycloalkenyl Selenides and Tellurides

(2013) Dahan Eom et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Total Syntheses of the Coumarin-Containing Natural Products Pimpinellin and Fraxetin Using Au(I)-Catalyzed Intramolecular Hydroarylation (IMHA) Chemistry

(2013) Aymeric Cervi et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Synthesis of Carbo- and Heterocycles through Norbornene-Mediated ortho C-H Functionalization

(2013) Raffaella Ferraccioli   SYNTHESIS-STUTTGART

A reductive Mizoroki–Heck approach to dibenzo[b,e]oxepine

(2013) K.C. Majumdar et al.   TETRAHEDRON LETTERS

Synthesis of Azocino[5,4-b]indolesviaGold-Catalyzed Intramolecular Alkyne Hydroarylation

(2012) Vsevolod A. Peshkov et al.   ADVANCED SYNTHESIS & CATALYSIS

Gold-Catalysis: Highly Efficient and Regio-Selective Carbonyl Migration in Alkynyl-Substituted Indole-3-Carboxamides Leading to Azepino[3,4-b]indol-1-ones

(2012) A. Stephen K. Hashmi et al.   ADVANCED SYNTHESIS & CATALYSIS

A concise route to indoloazocines via a sequential Ugi–gold-catalyzed intramolecular hydroarylation

(2012) Sachin G. Modha et al.   CHEMICAL COMMUNICATIONS

Gold(i) and platinum(ii) switch: a post-Ugi intramolecular hydroarylation to pyrrolopyridinones and pyrroloazepinones

(2012) Sachin G. Modha et al.   CHEMICAL COMMUNICATIONS

Dual Hard/Soft Gold Catalysis: Intermolecular Friedel-Crafts-Type α-Amidoalkylation/Alkyne Hydroarylation Sequences byN-Acyliminium Ion Chemistry

(2012) Liliana Boiaryna et al.   CHEMISTRY-A EUROPEAN JOURNAL

Intramolecular Cascade Hydroarylation/Cycloisomerization Strategy for the Synthesis of Polycyclic Aromatic and Heteroaromatic Systems

(2012) Jan Storch et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Vinyl Sulfides and Vinylamines through Catalytic Intramolecular Hydroarylation in the Presence of FeCl3and AgOTf

(2012) Dahan Eom et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Intramolecular Hydroarylation of 4-Benzofuranyl Alkynoates. Approach to Angelicin Derivatives

(2012) Tsugio Kitamura et al.   JOURNAL OF ORGANIC CHEMISTRY

Gold versus silver catalyzed intramolecular hydroarylation reactions of [(3-arylprop-2-ynyl)oxy]benzene derivatives

(2012) Antonio Arcadi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Hybrid System of Metal/Brønsted Acid Relay Catalysis for the Intramolecular Double Hydroarylation and Cationic Cyclization of Diyne Diethers and Diamines

(2012) Juntae Mo et al.   ORGANIC LETTERS

Synthesis of 3-Arylindole-2-carboxylates via Copper-Catalyzed Hydroarylation of o-Nitrophenyl-Substituted Alkynoates and Subsequent Cadogan Cyclization

(2011) Yoshihiko Yamamoto et al.   ADVANCED SYNTHESIS & CATALYSIS

Merging Organocatalysis and Gold Catalysis: Enantioselective Synthesis of Tetracyclic Indole Derivatives through a Sequential Double Friedel-Crafts Type Reaction

(2011) Charles C. J. Loh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of the Azocino[cd]indole Framework through Pd-Catalyzed Intramolecular Acetylene Hydroarylation

(2011) Vsevolod A. Peshkov et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ph3PAuNTf2 as a Superior Catalyst for the Selective Synthesis of 2H-Chromenes: Application to the Concise Synthesis of Benzopyran Natural Products

(2011) Ioannis N. Lykakis et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

One-Pot Synthesis of Indole-Fused Scaffolds via Gold-Catalyzed Tandem Annulation Reactions of 1,2-Bis(alkynyl)-2-en-1-ones with Indoles

(2011) Xin Xie et al.   JOURNAL OF ORGANIC CHEMISTRY

Transition-Metal-Catalyzed C-H Functionalization for the Synthesis of Substituted Pyridines

(2011) Yoshiaki Nakao   SYNTHESIS-STUTTGART

Sequential alkylation/gold-catalyzed annulation reactions of anilines with propargylic bromide derivatives

(2011) Maria Alfonsi et al.   TETRAHEDRON LETTERS

Regioselective formation of medium-ring heterocycles of biological relevance by intramolecular cyclization

(2011) K. C. Majumdar   RSC Advances

Gold-Catalyzed Intramolecular Alkyne Cycloisomerization Cascade: Direct Synthesis of Aryl-Annulated[a]carbazoles from Aniline-Substituted Diethynylarenes

(2010) Kimio Hirano et al.   ADVANCED SYNTHESIS & CATALYSIS

Cationic iron-catalyzed intramolecular alkyne-hydroarylation with electron-deficient arenes

(2010) Kimihiro Komeyama et al.   CHEMICAL COMMUNICATIONS

Gold(i)-catalyzed formation of dihydroquinolines and indoles from N-aminophenyl propargyl malonates

(2010) Colombe Gronnier et al.   CHEMICAL COMMUNICATIONS

Gold nanoparticles supported on TiO2catalyse the cycloisomerisation/oxidative dimerisation of aryl propargyl ethers

(2010) Christina Efe et al.   CHEMICAL COMMUNICATIONS

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

(2010) David Lapointe et al.   CHEMISTRY LETTERS

Transition-Metal-Catalyzed Synthesis of Hydroxylated Arenes

(2010) Diego A. Alonso et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Diversity-Oriented Microwave-Assisted Synthesis of the 3-Benzazepine Framework

(2010) Vsevolod A. Peshkov et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Azaanthraquinone Assembly fromN-Propargylamino Quinone via a Au(I)-Catalyzed 6-endo-digCycloisomerization

(2010) Chunhui Jiang et al.   JOURNAL OF ORGANIC CHEMISTRY

Formation of cinnoline derivatives by a gold(I)-catalyzed hydroarylation of N-propargyl-N′-arylhydrazines

(2010) Igor Dias Jurberg et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Regiocontrolled gold(I)-catalyzed cyclization reactions of N-(3-iodoprop-2-ynyl)-N-tosylanilines

(2010) Pablo Morán-Poladura et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Platinum-catalyzed cyclization reaction of alkynes: synthesis of azepino[3,4-b]indol-1-ones

(2010) Marina Gruit et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of substituted β-carbolines via gold(III)-catalyzed cycloisomerization of N-propargylamides

(2010) Guido Verniest et al.   TETRAHEDRON

Synthesis of pyrroloazepinones: platinum- and gold-catalyzed cyclization reactions of alkynes

(2010) Marina Gruit et al.   TETRAHEDRON

Palladium-mediated reductive Mizoroki–Heck cyclization strategy for the regioselective formation of dibenzoazocinone framework

(2010) K.C. Majumdar et al.   TETRAHEDRON LETTERS

Gold-Catalyzed Intermolecular Reactions of (Z)-Enynols with Indoles for the Construction of Dihydrocyclohepta[b]indole Skeletons through a Cascade Friedel-Crafts/Hydroarylation Sequence

(2009) Yuhua Lu et al.   ADVANCED SYNTHESIS & CATALYSIS

Platinum-Catalyzed Intramolecular Cyclizations of Alkynes: Efficient Synthesis of Pyrroloazepinone Derivatives

(2009) Marina Gruit et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in aryl–aryl bond formation by direct arylation

(2009) Gerard P. McGlacken et al.   CHEMICAL SOCIETY REVIEWS

Gold and platinum catalysis—a convenient tool for generating molecular complexity

(2009) Alois Fürstner   CHEMICAL SOCIETY REVIEWS

An Asymmetric Approach towards (-)-Aphanorphine and Its Analogues

(2009) Pavel A. Donets et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Transition-Metal-Catalyzed Hydroarylation Reactions of Alkynes Through Direct Functionalization of C-H Bonds: A Convenient Tool for Organic Synthesis

(2009) Tsugio Kitamura   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 4-Aryl-Substituted Butenolides and Pentenolides by Copper-Catalyzed Hydroarylation

(2009) Yoshihiko Yamamoto et al.   HETEROCYCLES

Palladium-Catalyzed Intramolecular 5-exo-digHydroarylations ofN-Arylpropiolamides: Thermodynamics-Controlled Stereoselective Synthesis of 3-Methyleneoxindoles

(2009) Tao-Shan Jiang et al.   JOURNAL OF ORGANIC CHEMISTRY

The Au(I)-Catalyzed Intramolecular Hydroarylation of Terminal Alkynes Under Mild Conditions: Application to the Synthesis of 2H-Chromenes, Coumarins, Benzofurans, and Dihydroquinolines

(2009) Rajeev S. Menon et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient Synthesis of the Indoloazocine Framework via Intramolecular Alkyne Carbocyclization

(2009) Pavel A. Donets et al.   ORGANIC LETTERS

Investigation of Synthetic Routes to a Key Benzopyran Intermediate of a 5HT4Agonist

(2009) Geracimos Rassias et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Alkenylation of aromatic compounds

(2009) A. V. Vasil’ev   RUSSIAN JOURNAL OF ORGANIC CHEMISTRY

Palladium-Mediated Reductive Heck Cyclization for the Formation of Dibenzoazepinone Framework

(2009) K. Majumdar et al.   SYNLETT

Synthesis of the tetracyclic core skeleton of the lundurines by a gold-catalyzed cyclization

(2009) Catalina Ferrer et al.   TETRAHEDRON

Recent advances in the synthesis of (hetero)aryl-substituted heteroarenes via transition metal-catalysed direct (hetero)arylation of heteroarene C–H bonds with aryl halides or pseudohalides, diaryliodonium salts, and potassium aryltrifluoroborates

(2009) Fabio Bellina et al.   TETRAHEDRON

Cycloisomerization of 1,n-Enynes: Challenging Metal-Catalyzed Rearrangements and Mechanistic Insights

(2008) Véronique Michelet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cu-catalyzed stereoselective conjugate addition of arylboronic acids to alkynoates

(2008) Yoshihiko Yamamoto et al.   CHEMICAL COMMUNICATIONS

Gold-Catalyzed Cycloisomerizations of Enynes: A Mechanistic Perspective

(2008) Eloísa Jiménez-Núñez et al.   CHEMICAL REVIEWS

Cobalt(II)-Catalyzed Regio- and Stereoselective Hydroarylation of Alkynes with Organoboronic Acids

(2008) Pao-Shun Lin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Thermal Rearrangements of 2-Ethynylbiphenyl: A DFT Study of Competing Reaction Mechanisms

(2008) Iain D. Mackie et al.   JOURNAL OF ORGANIC CHEMISTRY

Exclusive 5-exo-digHydroarylation ofo-Alkynyl Biaryls Proceeding via C−H Activation Pathway

(2008) Natalia Chernyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Cycloisomerization ofN-Propargylindole-2-carboxamides: Application toward the Synthesis of Lavendamycin Analogues

(2008) Dylan B. England et al.   ORGANIC LETTERS

Synthesis of 4-Arylcoumarins via Cu-Catalyzed Hydroarylation with Arylboronic Acids

(2008) Yoshihiko Yamamoto et al.   ORGANIC LETTERS

Pd-catalyzed regioselective hydroarylation of α-(2-aminoaryl)-α,β-ynones with organoboron derivatives as a tool for the synthesis of quinolines: experimental evidence and quantum-chemical calculations

(2008) Antonio Arcadi et al.   TETRAHEDRON

Sequential catalytic process: synthesis of quinoline derivatives by AuCl3/CuBr-catalyzed three-component reaction of aldehydes, amines, and alkynes

(2008) Fengping Xiao et al.   TETRAHEDRON

A facile gold(I)-catalysed intramolecular alkyne hydroarylation approach to methyl 5-amino-2H-1-benzopyran-8-carboxylate derivatives

(2008) Neil R. Curtis et al.   TETRAHEDRON LETTERS

Palladium-Catalyzed Hydrophenylation of Alkynes with Sodium Tetraphenylborate under Mild Conditions

(2007) Hanxiang Zeng et al.   JOURNAL OF ORGANIC CHEMISTRY

Non-conventional methodologies for transition-metal catalysed carbon–carbon coupling: a critical overview. Part 2: The Suzuki reaction

(2007) Francisco Alonso et al.   TETRAHEDRON