Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes

Rhodium(III)-Catalyzed CC Coupling between Arenes and Aziridines by CH Activation

(2013) Xingwei Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Rhodium(III)-Catalyzed Cyclization of Amides with α,β-Unsaturated Aldehydes and Ketones to Azepinones: Application to the Synthesis of the Homoprotoberberine Framework

(2013) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Rhodium(III)-Catalyzed Direct CH Allylation of Arenes with Allyl Carbonates

(2013) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Acceptorless Dehydrogenation of Nitrogen Heterocycles with a Versatile Iridium Catalyst

(2013) Jianjun Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[Cp*RhCl2]2-catalyzed ortho-C–H bond amination of acetophenone o-methyloximes with primary N-chloroalkylamines: convenient synthesis of N-alkyl-2-acylanilines

(2013) Ka-Ho Ng et al.   CHEMICAL COMMUNICATIONS

Bulky Phosphinines: From a Molecular Design to an Application in Homogeneous Catalysis

(2013) Jarno J. M. Weemers et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cyclometalated iridium complexes for transfer hydrogenation of carbonyl groups in water

(2013) Yawen Wei et al.   GREEN CHEMISTRY

Rhodium- and Iridium-Catalyzed Dehydrogenative Cyclization through Double C–H Bond Cleavages To Produce Fluorene Derivatives

(2013) Masaki Itoh et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Study of the Oxidative Coupling of Styrene with 2-Phenylpyridine Derivatives Catalyzed by Cationic Rhodium(III) via C–H Activation

(2013) Mikaël Brasse et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterobimetallic Carbene Complexes by a Single-Step Site-Selective Metalation of a Tricarbene Ligand

(2013) Ramananda Maity et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Efficient Rh/O2 Catalytic System for Oxidative C–H Activation/Annulation: Evidence for Rh(I) to Rh(III) Oxidation by Molecular Oxygen

(2013) Guoying Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Tandem C–H Allylation and Oxidative Cyclization of Anilides: A New Entry to Indoles

(2013) Ana Cajaraville et al.   ORGANIC LETTERS

Rh(iii)-catalyzed C–H activation/[4 + 3] cycloaddition of benzamides and vinylcarbenoids: facile synthesis of azepinones

(2013) Sunliang Cui et al.   Chemical Science

Unconventional Reactivity of Imidazolylidene Pyridylidene Ligands in Iridium(III) and Rhodium(III) Complexes

(2012) Candela Segarra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Intramolecular Annulation through CH Activation: Total Synthesis of (±)-Antofine, (±)-Septicine, (±)-Tylophorine, and Rosettacin

(2012) Xianxiu Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium/Copper-Catalyzed Annulation of Benzimides with Internal Alkynes: Indenone Synthesis through Sequential CH and CN Cleavage

(2012) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Rhodium(III)-Catalyzed CH Activation and Intermolecular Annulation with Allenes

(2012) Honggen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Direct CH Amination of Benzamides with Aryl Azides: A Synthetic Route to Diarylamines

(2012) Jaeyune Ryu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Dehydrogenative Heck Reaction of Salicylaldehydes

(2012) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient dynamic kinetic resolution of racemic secondary alcohols by a chemoenzymatic system using bifunctional iridium complexes with C–N chelate amido ligands

(2012) Yasuhiro Sato et al.   CHEMICAL COMMUNICATIONS

Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle

(2012) Wissam Iali et al.   CHEMICAL COMMUNICATIONS

Metal center dependent coordination modes of a tricarbene ligand

(2012) Ramananda Maity et al.   CHEMICAL COMMUNICATIONS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

The Selective Synthesis of Metallanucleosides and Metallanucleotides: A New Tool for the Functionalization of Nucleic Acids

(2012) Mamen Martín-Ortíz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh-Catalyzed CC Cleavage of Benzyl/Allylic Alcohols to Produce Benzyl/Allylic Amines or other Alcohols by Nucleophilic Addition of Intermediate Rhodacycles to Aldehydes and Imines

(2012) Xi-Sha Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Planar Chiral Iridacycles by Cationic Metal π-Coordination: Facial Selectivity, and Conformational and Stereochemical Consequences

(2012) Jean-Pierre Djukic et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Ligand Cooperation in Catalytic Intramolecular Hydroamination: A Computational Study of Iridium-Pyrazolato Cooperative Activation of Aminoalkenes

(2012) Sven Tobisch   CHEMISTRY-A EUROPEAN JOURNAL

Investigation and Comparison of the Mechanistic Steps in the [(Cp*MCl2)2] (Cp*=C5Me5; M=Rh, Ir)-Catalyzed Oxidative Annulation of Isoquinolones with Alkynes

(2012) Nuancheng Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Amide-Directed Tandem CC/CN Bond Formation through CH Activation

(2012) Chen Zhu et al.   Chemistry-An Asian Journal

Photolytic water oxidation catalyzed by a molecular carbene iridium complex

(2012) Ana Petronilho et al.   DALTON TRANSACTIONS

Palladium, iridium and ruthenium complexes with acyclic imino-N-heterocyclic carbenes and their application in aqua-phase Suzuki–Miyaura cross-coupling reaction and transfer hydrogenation

(2012) Xu-Qing Guo et al.   DALTON TRANSACTIONS

Synthesis and X-ray structures of cyclometalated iridium complexes including the hydrides

(2012) Chao Wang et al.   DALTON TRANSACTIONS

Rh(III)-Catalyzed Regioselective Synthesis of Pyridines from Alkenes and α,β-Unsaturated Oxime Esters

(2012) Jamie M. Neely et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cationic Ir(III) Alkylidenes Are Key Intermediates in C–H Bond Activation and C–C Bond-Forming Reactions

(2012) Jesús Campos et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of the Rhodium(III)-Catalyzed Arylation of Imines via C–H Bond Functionalization: Inhibition by Substrate

(2012) Michael E. Tauchert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Mild Stepwise Allylation of N-Methoxybenzamides with Allenes

(2012) Rong Zeng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Intermolecular Amidation of Arenes with Sulfonyl Azides via Chelation-Assisted C–H Bond Activation

(2012) Ji Young Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-Yielding, Versatile, and Practical [Rh(III)Cp*]-Catalyzed Ortho Bromination and Iodination of Arenes

(2012) Nils Schröder et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Intermolecular Carbenoid Functionalization of Aromatic C–H Bonds by α-Diazomalonates

(2012) Wai-Wing Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Cascade Oxidative Annulation Leading to Substituted Naphtho[1,8-bc]pyrans by Sequential Cleavage of C(sp2)–H/C(sp3)–H and C(sp2)–H/O–H Bonds

(2012) Xing Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(iii)-catalyzed oxidative mono- and di-olefination of isonicotinamides

(2012) Xiaohong Wei et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(III)- and Ruthenium(II)-Catalyzed Olefination of Isoquinolones

(2012) Peng Zhao et al.   ORGANIC LETTERS

Synthesis, Electrochemistry, and Reactivity of New Iridium(III) and Rhodium(III) Hydrides

(2012) Yue Hu et al.   ORGANOMETALLICS

The Reaction of [Cp*RhCl2]2, Aniline, and a Terminal Alkyne: Formation of Cyclometalated Rhodium(III) Complexes

(2012) Elumalai Kumaran et al.   ORGANOMETALLICS

Catalytic Intramolecular Hydroamination with a Bifunctional Iridium Pyrazolato Complex: Substrate Scope and Mechanistic Elucidation

(2012) Yohei Kashiwame et al.   ORGANOMETALLICS

Efficient Route to Organometallic Cage Formation via C–H Activation-Directed Muticomponent Assembly Accompanying Aromatic Guest Encapsulation

(2012) Ying-Feng Han et al.   ORGANOMETALLICS

Bifunctional Mechanism with Unconventional Intermediates for the Hydrogenation of Ketones Catalyzed by an Iridium(III) Complex Containing an N-Heterocyclic Carbene with a Primary Amine Donor

(2012) Wylie W. N. O et al.   ORGANOMETALLICS

Regioselective Electrophilic C–H Bond Activation in Triazolylidene Metal Complexes Containing a N-Bound Phenyl Substituent

(2012) Kate F. Donnelly et al.   ORGANOMETALLICS

Iridium(III) Cp* Complexes for the Efficient Hydroamination of Internal Alkynes

(2012) Katherine Gray et al.   ORGANOMETALLICS

Synthesis of highly substituted isocoumarins by rhodium-catalyzed annulation of readily available benzoic acids

(2012) Yuto Unoh et al.   TETRAHEDRON

Mechanistic understanding of Rh-catalyzed N-sulfonylaldimine insertion into aryl C–H bonds

(2012) Yang Li et al.   Chemical Science

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Oxidizing Directing Groups Enable Efficient and Innovative CH Activation Reactions

(2011) Frederic W. Patureau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Methyltransferase Activity of an Iridium Center with Methylpyridinium as Methylene Source

(2011) Ralte Lalrempuia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Charge-induced facial-selectivity in the formation of new cationic planar chiral iridacycles derived from aniline

(2011) Jean-Pierre Djukic et al.   CHEMICAL COMMUNICATIONS

Pyridine synthesis from oximes and alkynesviarhodium(iii) catalysis: Cp* and Cptprovide complementary selectivity

(2011) Todd K. Hyster et al.   CHEMICAL COMMUNICATIONS

Rhodium(iii)-catalyzed oxidative carbonylation of benzamides with carbon monoxide

(2011) Ya Du et al.   CHEMICAL COMMUNICATIONS

Hydrogenation of imino bonds with half-sandwich metal catalysts

(2011) Chao Wang et al.   CHEMICAL COMMUNICATIONS

Organic Synthesis Involving Iridium-Catalyzed Oxidation

(2011) Takeyuki Suzuki   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Construction of Tetranuclear Macrocycles through CH Activation and Structural Transformation Induced by [2+2] Photocycloaddition Reaction

(2011) Wei-Bin Yu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Intramolecular Oxidation of the Alcohol Functionalities in Hydroxyalkyl-N-Heterocyclic Carbene Complexes of Iridium and Rhodium

(2011) Miriam Benítez et al.   CHEMISTRY-A EUROPEAN JOURNAL

β-Protic Pyrazole and N-Heterocyclic Carbene Complexes: Synthesis, Properties, and Metal-Ligand Cooperative Bifunctional Catalysis

(2011) Shigeki Kuwata et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Scope of Ambiphilic Acetate-Assisted Cyclometallation with Half-Sandwich Complexes of Iridium, Rhodium and Ruthenium

(2011) Youcef Boutadla et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Annulation of N-Benzoylsulfonamide with Isocyanide through CH Activation

(2011) Chen Zhu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Versatile Reactivity of Half-Sandwich Ir and Rh Complexes toward Carboranylamidinates and Their Derivatives: Synthesis, Structure, and Catalytic Activity for Norbornene Polymerization

(2011) Zi-Jian Yao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Flexible Organometallic Cages: Efficient Formation by CH Activation-Directed Muticomponent Assembly, Isomerization, and Host-Guest Properties

(2011) Ying-Feng Han et al.   Chemistry-An Asian Journal

Variable coordination of amine functionalised N-heterocyclic carbene ligands to Ru, Rh and Ir: C–H and N–H activation and catalytic transfer hydrogenation

(2011) Warren B. Cross et al.   DALTON TRANSACTIONS

Unprecedented diastereoselective generation of chiral-at-metal, half sandwich Ir(iii) and Rh(iii) complexes via anomeric isomerism on “sugar-coated” N-heterocyclic carbene ligands

(2011) Teppei Shibata et al.   DALTON TRANSACTIONS

Bis-imine-cyclometalated macrocycles: synthesis, characterization and observation of solution behaviour

(2011) Hao Li et al.   DALTON TRANSACTIONS

Synthesis, Structures, and Transfer Hydrogenation Catalysis of Bifunctional Iridium Complexes Bearing a C-N Chelate Oxime Ligand

(2011) Megumi Watanabe et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Contrasting Reactivity and Cancer Cell Cytotoxicity of Isoelectronic Organometallic Iridium(III) Complexes

(2011) Zhe Liu et al.   INORGANIC CHEMISTRY

Synthesis of Isochromene and Related Derivatives by Rhodium-Catalyzed Oxidative Coupling of Benzyl and Allyl Alcohols with Alkynes

(2011) Keisuke Morimoto et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Quinolines via Rh(III)-Catalyzed Oxidative Annulation of Pyridines

(2011) Guoyong Song et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Regioselective Olefination Directed by a Carboxylic Group

(2011) Satoshi Mochida et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Azaheterocycles from Aryl KetoneO-Acetyl Oximes and Internal Alkynes by Cu–Rh Bimetallic Relay Catalysts

(2011) Pei Chui Too et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient Catalytic Interconversion between NADH and NAD+ Accompanied by Generation and Consumption of Hydrogen with a Water-Soluble Iridium Complex at Ambient Pressure and Temperature

(2011) Yuta Maenaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

(2011) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diverse Strategies toward Indenol and Fulvene Derivatives: Rh-Catalyzed C−H Activation of Aryl Ketones Followed by Coupling with Internal Alkynes

(2011) Frederic W. Patureau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Heterocycle Synthesis Using an Internal Oxidant: Improved Reactivity and Mechanistic Studies

(2011) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and reactivity of half-sandwich (η5-C5Me5)Ir(iii) complexes of a cyclometallated aryl phosphine ligand

(2011) Jesús Campos et al.   NEW JOURNAL OF CHEMISTRY

Dehydrogenative Oxidation of Primary and Secondary Alcohols Catalyzed by a Cp*Ir Complex Having a Functional C,N-Chelate Ligand

(2011) Ken-ichi Fujita et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Intermolecular Direct Amination of Aromatic C–H Bonds with N-Chloroamines

(2011) Ka-Ho Ng et al.   ORGANIC LETTERS

Rh[III]-Catalyzed Direct C–H Amination Using N-Chloroamines at Room Temperature

(2011) Christoph Grohmann et al.   ORGANIC LETTERS

Organometallic Iridium(III) Cyclopentadienyl Anticancer Complexes Containing C,N-Chelating Ligands

(2011) Zhe Liu et al.   ORGANOMETALLICS

Rational Design of Half-Sandwich Iridium Metallamacrocycles Assembled by C–H Activation

(2011) Wei-Bin Yu et al.   ORGANOMETALLICS

Discrete Iridamacrocycle Formation via C–H Activation of an N-Heterocycle

(2011) Wei-Bin Yu et al.   ORGANOMETALLICS

An Iridium(IV) Species, [Cp*Ir(NHC)Cl]+, Related to a Water-Oxidation Catalyst

(2011) Timothy P. Brewster et al.   ORGANOMETALLICS

Alkyne Insertion Induced Regiospecific C−H Activation with [Cp*MCl2]2(M = Ir, Rh)

(2011) Ying-Feng Han et al.   ORGANOMETALLICS

Reaction of Chiral Secondary Amines with [(η5-C5Me5)MCl2]2(M = Rh(III), Ir(III)): Cyclometalation with or without Dehydrogenation

(2011) Laurent Barloy et al.   ORGANOMETALLICS

An improved catalyst architecture for rhodium(iii) catalyzed C–H activation and its application to pyridone synthesis

(2011) Todd K. Hyster et al.   Chemical Science

Water Oxidation Catalyzed by Strong Carbene-Type Donor-Ligand Complexes of Iridium

(2010) Ralte Lalrempuia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Oxidative Olefination of CH Bonds in Acetophenones and Benzamides

(2010) Frederic W. Patureau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Versatile Catalyst for Reductive Amination by Transfer Hydrogenation

(2010) Chao Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient formation of organoiridium macrocycles via C–H activation directed self-assembly

(2010) Ying-Feng Han et al.   CHEMICAL COMMUNICATIONS

Iridium(iii) molecular catalysts for water oxidation: the simpler the faster

(2010) Arianna Savini et al.   CHEMICAL COMMUNICATIONS

C–H activation of 2,4,6-triphenylphosphinine: unprecedented formation of cyclometalated [(P⁁C)Ir(iii)] and [(P⁁C)Rh(iii)] complexes

(2010) Leen E. E. Broeckx et al.   CHEMICAL COMMUNICATIONS

Rhodium-catalyzed Oxidative Coupling/Cyclization of Benzamides with Alkynes via C–H Bond Cleavage

(2010) Satoshi Mochida et al.   CHEMISTRY LETTERS

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Naphtho[1,8-bc]pyran Derivatives and Related Compounds through Hydroxy Group Directed CH Bond Cleavage under Rhodium Catalysis

(2010) Satoshi Mochida et al.   Chemistry-An Asian Journal

Alkyne insertion into cyclometallated pyrazole and imine complexes of iridium, rhodium and ruthenium; relevance to catalytic formation of carbo- and heterocycles

(2010) Youcef Boutadla et al.   DALTON TRANSACTIONS

Rh-Catalyzed Oxidative Coupling between Primary and Secondary Benzamides and Alkynes: Synthesis of Polycyclic Amides

(2010) Guoyong Song et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Oxidative 1:1, 1:2, and 1:4 Coupling Reactions of Phenylazoles with Internal Alkynes through the Regioselective Cleavages of Multiple C−H Bonds

(2010) Nobuyoshi Umeda et al.   JOURNAL OF ORGANIC CHEMISTRY

Insertion of nitrene and chalcogenolate groups into the Ir–C σ bond in a cyclometalated iridium(III) complex

(2010) Yiu-Keung Sau et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Self-assembly directed by C–H activation: Synthesis and characterization of [(Cp∗Ir)2(R–NC–Ph–CNR)]2(4,4-bipyridine)2·(OTf)4 (R=Ph, Me)

(2010) Hao Li et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Rhodium(III)-Catalyzed Isoquinolone Synthesis: The N−O Bond as a Handle for C−N Bond Formation and Catalyst Turnover

(2010) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cationic Rh(III) Complex That Efficiently Catalyzes Hydrogen Isotope Exchange in Hydrosilanes

(2010) Jesús Campos et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Arene and Alkene C−H Bond Functionalization Leading to Indoles and Pyrroles

(2010) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides

(2010) Frederic W. Patureau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C−H/N−H Activation

(2010) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyrrole Synthesis via Allylic sp3C−H Activation of Enamines Followed by Intermolecular Coupling with Unactivated Alkynes

(2010) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 2-Pyridones and Iminoesters via Rh(III)-Catalyzed Oxidative Coupling between Acrylamides and Alkynes

(2010) Yan Su et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Synthesis of Isoquinolines from Aryl KetoneO-Acyloxime Derivatives and Internal Alkynes

(2010) Pei Chui Too et al.   ORGANIC LETTERS

Orthometalated Amino-Carbene Derivatives of Iridium via Anilines and Terminal Alkynes

(2010) Elumalai Kumaran et al.   ORGANOMETALLICS

Cleavage of C−H Bonds for Building Tetranuclear Half-Sandwich Iridium Macrocycles with Ortho-Metalated Spacers

(2010) Wei-Bin Yu et al.   ORGANOMETALLICS

Reactions of Cyclometalated Oxazoline Half-Sandwich Complexes of Iridium and Ruthenium with Alkynes and CO

(2010) David L. Davies et al.   ORGANOMETALLICS

Reactivity and Regioselectivity of Insertion of Unsaturated Molecules into M−C (M = Ir, Rh) Bonds of Cyclometalated Complexes

(2010) Ling Li et al.   ORGANOMETALLICS

Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C–H bond cleavage

(2009) Tatsuya Fukutani et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends

(2009) Martin Albrecht   CHEMICAL REVIEWS

Metal-Pyrazole Bifunction in Half-Sandwich CN Chelate Iridium Complexes: Pyrazole-Pyrazolato Interconversion and Application to Catalytic Intramolecular Hydroamination of Aminoalkene

(2009) Yohei Kashiwame et al.   CHEMISTRY-A EUROPEAN JOURNAL

Fast Racemisation of Chiral Amines and Alcohols by Using Cationic Half-Sandwich Ruthena- and Iridacycle Catalysts

(2009) Thomas Jerphagnon et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Stereospecific Ligand Exchange at a Pseudo-BenzylicT-4 Iridium Centre in Planar-Chiral Cycloiridium (η6-Arene)tricarbonylchromium Complexes

(2009) Jean-Pierre Djukic et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cyclometallation and Hydrogen/Deuterium Exchange Reactions of an Arylphosphine Ligand upon Coordination to {Ir(η5-C5Me5)}

(2009) Jesús Campos et al.   CHEMISTRY-A EUROPEAN JOURNAL

Waste-Free Synthesis of Condensed Heterocyclic Compounds by Rhodium-Catalyzed Oxidative Coupling of Substituted Arene or Heteroarene Carboxylic Acids with Alkynes

(2009) Masaki Shimizu et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Functionalized α-Pyrone and Butenolide Derivatives by Rhodium-Catalyzed Oxidative Coupling of Substituted Acrylic Acids with Alkynes and Alkenes

(2009) Satoshi Mochida et al.   JOURNAL OF ORGANIC CHEMISTRY

Isoquinoline Synthesis via Rhodium-Catalyzed Oxidative Cross-Coupling/Cyclization of Aryl Aldimines and Alkynes

(2009) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation

(2009) Jonathan F. Hull et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Activation of Phenyl Imines and 2-Phenylpyridines with [Cp*MCl2]2(M = Ir, Rh): Regioselectivity, Kinetics, and Mechanism

(2009) Ling Li et al.   ORGANOMETALLICS

Aerobic Oxidative Kinetic Resolution of Racemic Secondary Alcohols with Chiral Bifunctional Amido Complexes

(2008) Sachiko Arita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorescent Naphthyl- and Anthrylazoles from the Catalytic Coupling of Phenylazoles with Internal Alkynes through the Cleavage of Multiple CH Bonds

(2008) Nobuyoshi Umeda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aerobic Oxidation of Alcohols with Bifunctional Transition-Metal Catalysts Bearing C-N Chelate Ligands

(2008) Sachiko Arita et al.   Chemistry-An Asian Journal

Half-sandwich iridium complexes—Synthesis and applications in catalysis

(2008) Jianke Liu et al.   COORDINATION CHEMISTRY REVIEWS

Imidazol-2-yl Complexes of Cp*Ir as Bifunctional Ambident Reactants

(2008) Valentín Miranda-Soto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Resolution of Racemic β-Haloalcohols: Direct Access to Enantioenriched Epoxides

(2008) Robert M. Haak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Efficient Low-Temperature Route to Polycyclic Isoquinoline Salt Synthesis via C−H Activation with [Cp*MCl2]2(M = Rh, Ir)

(2008) Ling Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Indole Synthesis via Rhodium Catalyzed Oxidative Coupling of Acetanilides and Internal Alkynes

(2008) David R. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands

(2008) Sachiko Arita et al.   ORGANOMETALLICS

Iridium and Ruthenium Complexes with Chelating N-Heterocyclic Carbenes: Efficient Catalysts for Transfer Hydrogenation, β-Alkylation of Alcohols, and N-Alkylation of Amines

(2008) Dinakar Gnanamgari et al.   ORGANOMETALLICS

Mechanistic Study of Acetate-Assisted C−H Activation of 2-Substituted Pyridines with [MCl2Cp*]2(M = Rh, Ir) and [RuCl2(p-cymene)]2

(2008) Youcef Boutadla et al.   ORGANOMETALLICS

Rhodium- and iridium-catalyzed oxidative coupling of benzoic acids with alkynes and alkenes

(2008) Tetsuya Satoh et al.   PURE AND APPLIED CHEMISTRY

Rhodium-Catalyzed Oxidative Coupling of Triarylmethanols with Internal Alkynes via Successive C−H and C−C Bond Cleavages

(2007) Toshihiko Uto et al.   JOURNAL OF ORGANIC CHEMISTRY