Nickel-Catalyzed Regio- and Enantioselective Borylative Coupling of Terminal Alkenes with Alkyl Halides Enabled by an Anionic Bisoxazoline Ligand

Enantioselective C(sp3)–C(sp3) Reductive Cross-Electrophile Coupling of Unactivated Alkyl Halides with α-Chloroboronates via Dual Nickel/Photoredox Catalysis

(2023) Jun Zhou et al.   Journal of the American Chemical Society

Asymmetric Double Hydroxycarbonylation of Alkynes to Chiral Succinic Acids Enabled by Palladium Relay Catalysis

(2022) Xiaolei Ji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Migratory Benzylboration of Allylbenzenes

(2022) Yangyang Li et al.   TETRAHEDRON LETTERS

Practical Synthesis of Chiral Allylboronates by Asymmetric 1,1‐Difunctionalization of Terminal Alkenes

(2022) Caocao Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Stereospecific Transformations of Alkylboronic Esters

(2022) Ningxin Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote Stereocenter through Amide-Directed, Rhodium-Catalyzed Enantioselective Hydroboration of Unactivated Internal Alkenes

(2022) Wei Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Enantioselective Dialkyl Carbinol Synthesis via Decarboxylative Cross-Coupling: Development, Scope, and Applications

(2022) Yang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Retraction of “Iridium-Catalyzed Asymmetric Borylation of Unactivated Methylene C(sp3)–H Bonds”

(2022) Ronald L. Reyes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Coupling of Alkyl Vicinal Bis(boronic Esters) to an Array of Electrophiles

(2022) Ningxin Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective synthesis of α-aminoboronates by NiH-catalysed asymmetric hydroamidation of alkenyl boronates

(2022) Yao Zhang et al.   Nature Communications

Dual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters

(2021) Purui Zheng et al.   Nature Communications

Enantioselective Rh-Catalyzed Hydroboration of Silyl Enol Ethers

(2021) Wenke Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective synthesis of tertiary boronic esters through catalytic asymmetric reversed hydroboration

(2021) Tao-Tao Gao et al.   Nature Communications

α-Boryl Organometallic Reagents in Catalytic Asymmetric Synthesis

(2021) Chenlong Zhang et al.   ACS Catalysis

Enantioselective catalytic 1,2-boronate rearrangements

(2021) Hayden A. Sharma et al.   SCIENCE

A relay catalysis strategy for enantioselective nickel-catalyzed migratory hydroarylation forming chiral α-aryl alkylboronates

(2021) Yao Zhang et al.   Chem

Catalytic Enantioselective Synthesis of anti Vicinal Silylboronates by Conjunctive Cross Coupling

(2020) James Patrick Morken et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Methodologies and Strategies for Selective Borylation of C–Het and C–C Bonds

(2020) Minyan Wang et al.   CHEMICAL REVIEWS

Iridium-Catalyzed Enantioselective α-C(sp3)–H Borylation of Azacycles

(2020) Lili Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Borylative Difunctionalization of π-Systems

(2020) Andrew Whyte et al.   ACS Catalysis

Catalyst-controlled enantioselective 1,1-arylboration of unactivated olefins

(2020) Wang Wang et al.   Nature Catalysis

Anionic Bisoxazoline Ligands Enable Copper‐Catalyzed Asymmetric Radical Azidation of  Acrylamides

(2020) Guosheng Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective C(sp3)–C(sp3) cross-coupling of non-activated alkyl electrophiles via nickel hydride catalysis

(2020) Srikrishna Bera et al.   Nature Chemistry

Enantioconvergent Synthesis of Tertiary Cyclic Allylboronates Using (Guanidine)copper Complex-Catalyzed Allylic Borylation

(2019) Choon Hong Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereodivergent Synthesis through Catalytic Asymmetric Reversed Hydroboration

(2019) Tao-Tao Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed 1,1-Alkylboration of Electronically Unbiased Terminal Alkenes

(2019) Yangyang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Asymmetric Borylation of Unactivated Methylene C(sp3)–H Bonds

(2019) Ronald L. Reyes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Enantioconvergent Borylation of Racemic Benzyl Chlorides Enabled by Quadrant-by-Quadrant Structure Modification of Chiral Bisphosphine Ligands

(2019) Hiroaki Iwamoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Bidentate Boryl Ligand Enabled Iridium-Catalyzed Enantioselective C(sp3)–H Borylation of Cyclopropanes

(2019) Yongjia Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-Throughput Ligand Screening Enables the Enantioselective Conjugate Borylation of Cyclobutenones to Access Synthetically Versatile Tertiary Cyclobutylboronates

(2019) Helen A. Clement et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Regiodivergent and Enantioselective Hydroboration of Enamides

(2019) Xiao-Yan Bai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aminoazanium of DABCO: An Amination Reagent for Alkyl and Aryl Pinacol Boronates

(2019) Xingxing Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of α-Aminoboronates via Rhodium-Catalyzed Enantioselective C(sp3)–H Borylation

(2019) Ronald L. Reyes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cascade CuH-catalysed conversion of alkynes into enantioenriched 1,1-disubstituted products

(2019) De-Wei Gao et al.   Nature Catalysis

A Copper(I)-Catalyzed Enantioselective γ-Boryl Substitution of Trifluoromethyl-Substituted Alkenes: Synthesis of Enantioenriched γ,γ-gem -Difluoroallylboronates

(2018) Ryoto Kojima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Enantioconvergent Borylation of Racemic Secondary Benzylic Electrophiles

(2018) Zhaobin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric remote C-H borylation of internal alkenes via alkene isomerization

(2018) Xu Chen et al.   Nature Communications

Copper-Catalyzed Asymmetric Defluoroborylation of 1-(Trifluoromethyl)Alkenes

(2018) Pan Gao et al.   Chem

Diastereoselective and Enantioselective Conjunctive Cross-Coupling Enabled by Boron Ligand Design

(2018) Jesse A. Myhill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Emmyguyacins A and B, Potential Fusion Inhibitors of Influenza Virus

(2018) Santanu Jana et al.   ORGANIC LETTERS

Mechanistic Studies of Copper-Catalyzed Asymmetric Hydroboration of Alkenes

(2017) Yumeng Xi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective Hydroboration of Unactivated 1,1-Disubstituted Alkenes

(2017) Won Jun Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Enantioselective C(sp3)–H Borylation

(2017) Jian He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Conjunctive Cross-Coupling of Bis(alkenyl)borates: A General Synthesis of Chiral Allylboron Reagents

(2017) Emma K. Edelstein et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Conjunctive Cross-Coupling between Grignard-Derived Boron “Ate” Complexes and C(sp2) Halides or Triflates: NaOTf as a Grignard Activator and Halide Scavenger

(2017) Gabriel J. Lovinger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Enantioselective Conjunctive Coupling with C(sp3) Electrophiles: A Radical-Ionic Mechanistic Dichotomy

(2017) Gabriel J. Lovinger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modular Synthesis of Enantioenriched 1,1,2-Triarylethanes by an Enantioselective Arylboration and Cross-Coupling Sequence

(2017) Bin Chen et al.   ACS Catalysis

Catalytic Enantioselective Functionalization of Unactivated Terminal Alkenes

(2016) John R. Coombs et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of α-aminoboronic acids

(2016) Patricia Andrés et al.   CHEMICAL SOCIETY REVIEWS

Accessing Both Retention and Inversion Pathways in Stereospecific, Nickel-Catalyzed Miyaura Borylations of Allylic Pivalates

(2016) Qi Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Biocatalytic Route to the Novel Antiepileptic Drug Brivaracetam

(2016) Arnaud Schülé et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters

(2016) J. Schmidt et al.   SCIENCE

Silver-Assisted, Iridium-Catalyzed Allylation of Bis[(pinacolato)boryl]methane Allows the Synthesis of Enantioenriched Homoallylic Organoboronic Esters

(2016) Miao Zhan et al.   ACS Catalysis

Stereospecific Coupling of Boronic Esters with N-Heteroaromatic Compounds

(2015) Josep Llaveria et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Regiodivergent Cu-Catalyzed Aminoboration of Unactivated Terminal Alkenes

(2015) Ryosuke Sakae et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic conjunctive cross-coupling enabled by metal-induced metallate rearrangement

(2015) L. Zhang et al.   SCIENCE

A Catalytic Enantiotopic-Group-Selective Suzuki Reaction for the Construction of Chiral Organoboronates

(2014) Chunrui Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiospecific sp2–sp3 coupling of secondary and tertiary boronic esters

(2014) Amadeu Bonet et al.   Nature Chemistry

Boronic Esters in Asymmetric Synthesis

(2013) Donald S. Matteson   JOURNAL OF ORGANIC CHEMISTRY

Highly Diastereo- and Enantioselective Allylboration of Aldehydes using α-Substituted Allyl/Crotyl Pinacol Boronic Esters via in Situ Generated Borinic Esters

(2013) Jack L.-Y. Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

(2011) Javier Magano et al.   CHEMICAL REVIEWS

An Efficient Process for the Manufacture of Carmegliptin§

(2011) Stefan Abrecht et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols

(2008) Jake L. Stymiest et al.   NATURE