Cascade CuH-catalysed conversion of alkynes into enantioenriched 1,1-disubstituted products

Differential Dihydrofunctionalization of Terminal Alkynes: Synthesis of Benzylic Alkyl Boronates through Reductive Three-Component Coupling

(2019) Megan K. Armstrong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile synthesis of α-aminoboronic acids from amines and potassium acyltrifluoroborates (KATs) via trifluoroborate-iminiums (TIMs)

(2018) Tomoya Shiro et al.   Chemical Science

An Electrocatalytic Approach to the Radical Difunctionalization of Alkenes

(2018) Gregory S. Sauer et al.   ACS Catalysis

Enantioselective Synthesis of α-Amidoboronates Catalyzed by Planar-Chiral NHC-Cu(I) Complexes

(2018) C. Benjamin Schwamb et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst-Controlled 1,2- and 1,1-Arylboration of α-Alkyl Alkenyl Arenes

(2018) Allison M. Bergmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CuH-Catalyzed Regioselective Intramolecular Hydroamination for the Synthesis of Alkyl-Substituted Chiral Aziridines

(2017) Haoxuan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of Copper-Catalyzed Asymmetric Hydroboration of Alkenes

(2017) Yumeng Xi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Hydrocarbonylative C–C Coupling of Terminal Alkynes with Alkyl Iodides

(2017) Li-Jie Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism-based enhancement of scope and enantioselectivity for reactions involving a copper-substituted stereogenic carbon centre

(2017) Jaehee Lee et al.   Nature Chemistry

Decarboxylative borylation

(2017) Chao Li et al.   SCIENCE

NHC-Copper-Catalyzed Tandem Hydrocupration and Allylation of Alkenyl Boronates

(2017) Jaesook Yun et al.   SYNTHESIS-STUTTGART

Isolation and characterization of hydrocarbon soluble NHC copper(I) phosphoranimide complex and catalytic application for alkyne hydroboration reaction

(2017) Tao Bai et al.   TETRAHEDRON LETTERS

Synthesis of β-Boryl-α-Aminosilanes by Copper-Catalyzed Aminoboration of Vinylsilanes

(2016) Kodai Kato et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Homoallylic Boronates by Chemo-, SN2′-, Diastereo- and Enantioselective Catalytic Sequence of Cu−H Addition to Vinyl-B(pin)/Allylic Substitution

(2016) Jaehee Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coinage Metal Hydrides: Synthesis, Characterization, and Reactivity

(2016) Abraham J. Jordan et al.   CHEMICAL REVIEWS

Asymmetric Synthesis of Borylalkanes via Copper-Catalyzed Enantioselective Hydroallylation

(2016) Jung Tae Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed trans-Hydroboration of Terminal Aryl Alkynes: Stereodivergent Synthesis of Alkenylboron Compounds

(2016) Won Jun Jang et al.   ORGANIC LETTERS

Copper Hydride Catalyzed Hydroamination of Alkenes and Alkynes

(2015) Michael T. Pirnot et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Studies Lead to Dramatically Improved Reaction Conditions for the Cu-Catalyzed Asymmetric Hydroamination of Olefins

(2015) Jeffrey S. Bandar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective 1,1-Arylborylation of Alkenes: Merging Chiral Anion Phase Transfer with Pd Catalysis

(2015) Hosea M. Nelson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of α-Aminoboronic Acid Derivatives by Copper-Catalyzed Enantioselective Hydroamination

(2015) Daiki Nishikawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Asymmetric Pinacolboryl Addition of N-Boc-imines Using a Chiral Sulfoxide–Phosphine Ligand

(2015) Ding Wang et al.   ORGANIC LETTERS

Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines

(2015) Y. Yang et al.   SCIENCE

Enantioselective Synthesis of α-Aminosilanes by Copper-Catalyzed Hydroamination of Vinylsilanes

(2014) Nootaree Niljianskul et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalysed selective hydroamination reactions of alkynes

(2014) Shi-Liang Shi et al.   Nature Chemistry

Synthesis and Pharmacology of Proteasome Inhibitors

(2013) Andreas Rentsch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Enantioselective Copper(I)-Catalyzed Hydroboration of Borylalkenes: Asymmetric Synthesis of 1,1-Diborylalkanes

(2013) Xinhui Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

α-Boryl Isocyanides Enable Facile Preparation of Bioactive Boropeptides

(2013) Adam Zajdlik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Catalyzed Hydrosilylation of Ketones and Esters and Insight into the Mechanism

(2013) Kseniya Revunova et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Enantioselective One-pot Aminoborylation of Aldehydes: A Strategy for Construction of Nonracemic α-Amino Boronates

(2013) Kai Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boroalkyl Group Migration Provides a Versatile Entry into α-Aminoboronic Acid Derivatives

(2012) Zhi He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

(2011) Richard I. McDonald et al.   CHEMICAL REVIEWS

Aminoboronic acids and esters: from synthetic challenges to the discovery of unique classes of enzyme inhibitors

(2011) Sabrina Touchet et al.   CHEMICAL SOCIETY REVIEWS

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

(2011) Hwanjong Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective preparation and chemoselective cross-coupling of 1,1-diboron compounds

(2011) Jack Chang Hung Lee et al.   Nature Chemistry

Stereospecific Suzuki−Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration

(2010) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Copper-Catalyzed Synthesis of α-Amino Boronate Esters fromN-tert-Butanesulfinyl Aldimines

(2008) Melissa A. Beenen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

α-Amido boronic acids: A synthetic challenge and their properties as serine protease inhibitors

(2007) Donald S. Matteson   MEDICINAL RESEARCH REVIEWS