A relay catalysis strategy for enantioselective nickel-catalyzed migratory hydroarylation forming chiral α-aryl alkylboronates

Chiral Alkyl Amine Synthesis via Catalytic Enantioselective Hydroalkylation of Enecarbamates

(2021) Deyun Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic asymmetric reductive hydroalkylation of enamides and enecarbamates to chiral aliphatic amines

(2021) Jia-Wang Wang et al.   Nature Communications

Enantioselective access to chiral aliphatic amines and alcohols via Ni-catalyzed hydroalkylations

(2021) Shan Wang et al.   Nature Communications

Facile Synthesis of Chiral Arylamines, Alkylamines and Amides by Enantioselective NiH‐Catalyzed Hydroamination

(2021) Lingpu Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Multicomponent Coupling: Synthesis of α-Chiral Ketones by Reductive Hydrocarbonylation of Alkenes

(2021) Jian Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoinduced copper-catalysed asymmetric amidation via ligand cooperativity

(2021) Caiyou Chen et al.   NATURE

A catalytic asymmetric cross-coupling approach to the synthesis of cyclobutanes

(2021) F. Wieland Goetzke et al.   Nature Chemistry

Nickel-catalysed migratory hydroalkynylation and enantioselective hydroalkynylation of olefins with bromoalkynes

(2021) Xiaoli Jiang et al.   Nature Communications

Catalytic Asymmetric Hydroalkylation of α,β-Unsaturated Amides Enabled by Regio-Reversed and Enantiodifferentiating syn-Hydronickellation

(2021) Fang Zhou et al.   ACS Catalysis

Dynamic multiligand catalysis: A polar to radical crossover strategy expands alkyne carboboration to unactivated secondary alkyl halides

(2021) Shin-Ho Kim-Lee et al.   Chem

NiH-Catalyzed Reductive Hydrocarbonation of Enol Esters and Ethers

(2021) Xiao-Xu Wang et al.   CCS Chemistry

Nickel-Catalyzed Chain-Walking Cross-Electrophile Coupling of Alkyl and Aryl Halides and Olefin Hydroarylation Enabled by Electrochemical Reduction

(2020) Gadde Sathish Kumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-Enabled Nickel-Catalyzed Redox-Relay Migratory Hydroarylation of Alkenes with Arylborons

(2020) Yuli He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling

(2020) Yuqiang Li et al.   Nature Communications

A Transient‐Directing‐Group Strategy Enables Enantioselective Reductive Heck Hydroarylation of Alkenes

(2020) Lucas J. Oxtoby et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Convergent Catalytic Asymmetric Synthesis of Esters of Chiral Dialkyl Carbinols

(2020) Ze-Peng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Nickel‐Catalyzed Migratory Hydrocyanation of Nonconjugated Dienes

(2020) Rongrong Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Enantioselective Reductive Cross-Coupling Reactions

(2020) Kelsey E. Poremba et al.   ACS Catalysis

Regio‐ and Enantioselective Ni‐Catalyzed Formal Hydroalkylation, Hydrobenzylation and Hydropropargylation of Acrylamides to α‐Tertiary Amides

(2020) Wei Shu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand‐Controlled Regiodivergence in Nickel‐Catalyzed Hydroarylation and Hydroalkenylation of Alkenyl Carboxylic Acids

(2020) Zi‐Qi Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio‐ and Regioselective NiH‐Catalyzed Reductive Hydroarylation of Vinylarenes with Aryl Iodides

(2020) Yuli He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel‐Catalyzed Asymmetric Synthesis of α‐Arylbenzamides

(2020) Sergio Cuesta-Galisteo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in nickel-catalyzed reductive hydroalkylation and hydroarylation of electronically unbiased alkenes

(2020) Xiao-Xu Wang et al.   Science China-Chemistry

Catalyst-controlled enantioselective 1,1-arylboration of unactivated olefins

(2020) Wang Wang et al.   Nature Catalysis

NiH-Catalyzed Proximal-Selective Hydroamination of Unactivated Alkenes

(2020) Jinwon Jeon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective C(sp3)–C(sp3) cross-coupling of non-activated alkyl electrophiles via nickel hydride catalysis

(2020) Srikrishna Bera et al.   Nature Chemistry

Ligand-Enabled NiH-Catalyzed Migratory Hydroamination: Chain Walking as a Strategy for Regiodivergent/Regioconvergent Remote sp 3 C–H Amination

(2020) Yulong Zhang et al.   CCS Chemistry

Nickel-catalyzed Enantioselective Hydroarylation and Hydroalkenylation of Styrenes

(2019) Yue-Gang Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-catalysed selective migratory hydrothiolation of alkenes and alkynes with thiols

(2019) Yulong Zhang et al.   Nature Communications

Nickel-Catalyzed Regioselective Hydroalkylation and Hydroarylation of Alkenyl Boronic Esters

(2019) Srikrishna Bera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rapid Access to Highly Functionalized Alkyl Boronates by NiH-Catalyzed Remote Hydroarylation of Boron-Containing Alkenes

(2019) Yao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tackling Remote sp 3 C−H Functionalization via Ni‐Catalyzed “chain‐walking” Reactions

(2019) Daniel Janssen‐Müller et al.   ISRAEL JOURNAL OF CHEMISTRY

Site-Selective Catalytic Deaminative Alkylation of Unactivated Olefins

(2019) Shang-Zheng Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Enantioconvergent Reductive Hydroalkylation of Olefins with α-Heteroatom Phosphorus or Sulfur Alkyl Electrophiles

(2019) Shi-Jiang He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NiH-Catalyzed Reductive Relay Hydroalkylation: A Strategy for the Remote C(sp3 )−H Alkylation of Alkenes

(2018) Fang Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective C(sp3)‒H bond activation by chiral transition metal catalysts

(2018) Tyler G. Saint-Denis et al.   SCIENCE

Walking Metals for Remote Functionalization

(2018) Heiko Sommer et al.   ACS Central Science

Remote sp 3 C–H Amination of Alkenes with Nitroarenes

(2018) Jichao Xiao et al.   Chem

Nickel-Catalyzed Enantioconvergent Borylation of Racemic Secondary Benzylic Electrophiles

(2018) Zhaobin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Interrogation of Co/Ni-Dual Catalyzed Hydroarylation

(2018) Sophia L. Shevick et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective Ni-Catalyzed Reductive Coupling of α-Haloboranes with Unactivated Olefins

(2018) Shang-Zheng Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiodivergent Pd-catalyzed C–C bond formation enabled through ligand parameterization

(2018) Shibin Zhao et al.   SCIENCE

NiH-Catalyzed Remote Asymmetric Hydroalkylation of Alkenes with Racemic α-Bromo Amides

(2018) Fang Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst-Controlled 1,2- and 1,1-Arylboration of α-Alkyl Alkenyl Arenes

(2018) Allison M. Bergmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic enantioconvergent coupling of secondary and tertiary electrophiles with olefins

(2018) Zhaobin Wang et al.   NATURE

Remote Migratory Cross-Electrophile Coupling and Olefin Hydroarylation Reactions Enabled by in Situ Generation of NiH

(2017) Fenglin Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild and Regioselective Benzylic C–H Functionalization: Ni-Catalyzed Reductive Arylation of Remote and Proximal Olefins

(2017) Yuli He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO2 and Water

(2017) Morgane Gaydou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide

(2017) Francisco Juliá-Hernández et al.   NATURE

Combinatorial Nickel-Catalyzed Monofluoroalkylation of Aryl Boronic Acids with Unactivated Fluoroalkyl Iodides

(2017) Jie Sheng et al.   ORGANIC LETTERS

Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to SN1 and SN2 Processes

(2017) Gregory C. Fu   ACS Central Science

Nickel-Catalyzed Difluoroalkylation of (Hetero)Arylborons with Unactivated 1-Bromo-1,1-difluoroalkanes

(2016) Yu-Lan Xiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel Hydride Complexes

(2016) Nathan A. Eberhardt et al.   CHEMICAL REVIEWS

Asymmetric Hydroarylation of Vinylarenes Using a Synergistic Combination of CuH and Pd Catalysis

(2016) Stig D. Friis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote functionalization through alkene isomerization

(2016) Alexandre Vasseur et al.   Nature Chemistry

Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation

(2016) Xi Lu et al.   Nature Communications

Alkene Hydrosilylation Using Tertiary Silanes with α-Diimine Nickel Catalysts. Redox-Active Ligands Promote a Distinct Mechanistic Pathway from Platinum Catalysts

(2016) Iraklis Pappas et al.   ACS Catalysis

Chemoselective Alkene Hydrosilylation Catalyzed by Nickel Pincer Complexes

(2015) Ivan Buslov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Well-defined transition metal hydrides in catalytic isomerizations

(2014) Evgeny Larionov et al.   CHEMICAL COMMUNICATIONS

Investigating the Nature of Palladium Chain-Walking in the Enantioselective Redox-Relay Heck Reaction of Alkenyl Alcohols

(2014) Margaret J. Hilton et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Mechanism and Selectivity in Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Halides with Alkyl Halides

(2013) Soumik Biswas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allylic CH Alkylation of Unactivated α-Olefins: Serial Ligand Catalysis Resumed

(2011) Andrew J. Young et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Multiligand Based Pd Catalyst for C−N Cross-Coupling Reactions

(2010) Brett P. Fors et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combinatorial Transition-Metal Catalysis: Mixing Monodentate Ligands to Control Enantio-, Diastereo-, and Regioselectivity

(2008) Manfred T. Reetz   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic effect of binary component ligands in chiral catalyst library engineering for enantioselective reactions

(2008) Kuiling Ding   CHEMICAL COMMUNICATIONS