Organophotocatalytic silyl transfer of silylboranes enabled by methanol association: a versatile strategy for C–Si bond construction

Organic Photoredox-Catalyzed Silyl Radical Generation from Silylboronate

(2022) Naho Takemura et al.   ACS Catalysis

Synthesis of β-Silyl α-Amino Acids via Visible-Light-Mediated Hydrosilylation

(2021) Yi Wan et al.   ORGANIC LETTERS

Diastereotopic Group-Selective Intramolecular Aldol Reactions Initiated by Enantioselective Conjugate Silylation: Diastereodivergence Controlled by the Silicon Nucleophile

(2021) Liangliang Zhang et al.   ACS Catalysis

Copper‐Photocatalyzed Hydrosilylation of Alkynes and Alkenes under Continuous Flow

(2021) Mingbing Zhong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Emerging building blocks for medicinal chemistry: recent synthetic advances

(2021) Oleksandr O Grygorenko et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

HMPA-Free Generation of Trialkylsilyllithium Reagents and Its Applications to the Synthesis of Silylboronic Esters

(2021) Martin Oestreich et al.   SYNTHESIS-STUTTGART

Iron-Catalyzed Silylation of (Hetero)aryl Chlorides with Et3SiBpin

(2020) Jia Jia et al.   ORGANIC LETTERS

C–O Bond Silylation Catalyzed by Iron: A General Method for the Construction of Csp2–Si Bonds

(2020) Juan Zhang et al.   ORGANIC LETTERS

Beyond Carbon: Enantioselective and Enantiospecific Reactions with Catalytically Generated Boryl- and Silylcopper Intermediates

(2020) Weichao Xue et al.   ACS Central Science

Enantioselective Synthesis of α-Chiral Propargylic Silanes by Copper-Catalyzed 1,4-Selective Addition of Silicon Nucleophiles to Enyne-Type α,β,γ,δ-Unsaturated Acceptors

(2020) Wenbin Mao et al.   ORGANIC LETTERS

Silylboranes as Powerful Tools in Organic Synthesis: Stereo- and Regioselective Reactions with 1,n-Enynes

(2020) Christina Moberg   SYNTHESIS-STUTTGART

Conjugated Polymers Inspired by Crystalline Silicon

(2019) Eric A. Marro et al.   CHEMISTRY OF MATERIALS

Recent Advances in Minisci-Type Reactions

(2019) Rupert S. J. Proctor et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pyridine‐Based Organocatalysts for Regioselective syn ‐1,2‐Silaboration of Terminal Alkynes and Allenes

(2019) Yohei Morimasa et al.   Asian Journal of Organic Chemistry

Copper-Catalyzed Carbon–Silicon Bond Formation

(2019) Jake R. Wilkinson et al.   ACS Catalysis

Hydride Transfer Enables the Nickel‐Catalyzed ipso ‐Borylation and Silylation of Aldehydes

(2019) Watchara Srimontree et al.   CHEMISTRY-A EUROPEAN JOURNAL

Photoredox Catalysis for Building C–C Bonds from C(sp2)–H Bonds

(2018) Chang-Sheng Wang et al.   CHEMICAL REVIEWS

Intermediacy of Ni–Ni Species in sp2 C–O Bond Cleavage of Aryl Esters: Relevance in Catalytic C–Si Bond Formation

(2018) Rosie J. Somerville et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Mediated Metal-Free Difunctionalization of Alkenes with CO2 and Silanes or C(sp3 )−H Alkanes

(2018) Jing Hou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible Light-Driven Radical trans-Hydrosilylation of Electron-Neutral and -Rich Alkenes with Tertiary and Secondary Hydrosilanes

(2018) Jing Zhu et al.   JOURNAL OF ORGANIC CHEMISTRY

Defluorosilylation of fluoroarenes and fluoroalkanes

(2018) Benqiang Cui et al.   Nature Communications

Quest for Novel Chemical Entities through Incorporation of Silicon in Drug Scaffolds

(2017) Remya Ramesh et al.   JOURNAL OF MEDICINAL CHEMISTRY

A Mild and Ligand-Free Ni-Catalyzed Silylation via C–OMe Cleavage

(2017) Cayetana Zarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Cα-heteroarylation of structurally diverse ethers via a mild N-hydroxysuccinimide mediated cross-dehydrogenative coupling reaction

(2017) Shihui Liu et al.   Chemical Science

Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes

(2016) Lin Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic silyl transfer from silylborane to nitroalkenes for the synthesis of β-silyl nitroalkanes and β-silyl amines

(2016) Chen-Ran Jiang et al.   CHEMICAL COMMUNICATIONS

Silicon-Containing Amino Acids: Synthetic Aspects, Conformational Studies, and Applications to Bioactive Peptides

(2016) Emmanuelle Rémond et al.   CHEMICAL REVIEWS

Organic Photoredox Catalysis

(2016) Nathan A. Romero et al.   CHEMICAL REVIEWS

Dual Catalysis Strategies in Photochemical Synthesis

(2016) Kazimer L. Skubi et al.   CHEMICAL REVIEWS

The chemistry of organo silanetriols

(2016) Rudolf Pietschnig et al.   COORDINATION CHEMISTRY REVIEWS

CHEM21 selection guide of classical- and less classical-solvents

(2016) Denis Prat et al.   GREEN CHEMISTRY

Intermolecular Three-Component Arylsilylation of Alkynes under Palladium/Copper Cooperative Catalysis

(2016) Ryo Shintani et al.   JOURNAL OF ORGANIC CHEMISTRY

Photoredox Catalysis in Organic Chemistry

(2016) Megan H. Shaw et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Cross-Coupling of Silicon Pronucleophiles with Unactivated Alkyl Electrophiles Coupled with Radical Cyclization

(2016) Weichao Xue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct α-heteroarylation of amides (α to nitrogen) and ethers through a benzaldehyde-mediated photoredox reaction

(2016) Yongqiang Zhang et al.   Chemical Science

Recent Advances in Transition-Metal-Catalyzed Synthetic Transformations of Organosilicon Reagents

(2016) Takeshi Komiyama et al.   ACS Catalysis

Suzuki-type cross coupling between aryl halides and silylboranes for the syntheses of aryl silanes

(2015) Huifang Guo et al.   CHEMICAL COMMUNICATIONS

Synthesis of Boron- and Silicon-Containing Amino Acids through Copper-Catalysed Conjugate Additions to Dehydroalanine Derivatives

(2015) Francesca Bartoccini et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Mechanism of NHC-Catalyzed Conjugate Additions of Diboron and Borosilane Reagents to α,β-Unsaturated Carbonyl Compounds

(2015) Hao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Insoluble Copper(II) Acetylacetonate–Chiral Bipyridine Complex that Catalyzes Asymmetric Silyl Conjugate Addition in Water

(2015) Taku Kitanosono et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis

(2015) Kazunori Nagao et al.   ORGANIC LETTERS

Why You Really Should Consider Using Palladium-Catalyzed Cross-Coupling of Silanols and Silanolates

(2015) Scott E. Denmark et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Aggregation-induced emission of siloles

(2015) Zujin Zhao et al.   Chemical Science

A Mild Ni/Cu-Catalyzed Silylation via C–O Cleavage

(2014) Cayetana Zarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Silyl-substituted 1,3-butadienes for Diels–Alder reaction, ene reaction and allylation reaction

(2011) Fei Zhao et al.   CHEMICAL COMMUNICATIONS

Metal-Free Catalytic C–Si Bond Formation in an Aqueous Medium. Enantioselective NHC-Catalyzed Silyl Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2011) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxetanes in Drug Discovery: Structural and Synthetic Insights

(2010) Georg Wuitschik et al.   JOURNAL OF MEDICINAL CHEMISTRY